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Material Sciences 2011
BiFeO3微晶的水热制备工艺及其磁性研究
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Abstract:
采用Bi(NO3)3·5H2O和Fe(C5H7O2)3为原料，乙醇胺为碱性沉淀剂，用改进的水热法制备了BiFeO3微晶。研究了前驱体沉淀的量，矿化剂浓度以及反应温度对产物形貌，尺度以及结构的影响。采用0.005 M的前驱物溶液在180℃的反应温度下能够制备得到均匀的球形纳米颗粒。BiFeO3的尺度随反应前驱物的量增加而减小，随反应温度增加而增加。XRD研究表明在200℃的反应温度下，当前驱物的浓度低于0.005 M时都能够获得纯的BiFeO3。而TEM结构分析表明BiFeO3纳米颗粒具有完整的单畴结构；磁性分析表明纳米的BiFeO3颗粒具有弱的铁磁有序。
An improved hydrothermal method was adopted to prepare BiFeO3 using Bi(NO3)3·5H2O, Fe(C5H7O2)3 as raw materials and 2-Aminoethanol as alkaline precipitant. The effects of the quantity of pre-cursor precipitate, the concentration of mineralizer, and the reaction temperature on the morphology of prod-ucts, size and structure were studied. The results showed that the size decreases with quantity of precursor precipitate, and increases with reaction temperature. XRD results indicated that pure BiFeO3 can be obtained by the precursor with a concentration lower that 0.005 M reacting under 200°C. TEM results indicated that the BiFeO3 nanoparticles present prefect mono-domain structure. Analyzing on magnetism showed that the BiFeO3 nanoparticles present weak antiferromagnetic order.
| [1] | J. Wang, J. B. Neaton, H. Zheng, et al. Epitaxial BiFeO3 multiferroic thin film heterostructures. Science, 2003, 299(5613): 1719-1722. |
| [2] | T. Choi, S. Lee, Y. J. Choi, V. Kiryukhin and S. W. Cheong, Switchable ferroelectric diode and photovoltaic effect in BiFeO3. Science, 2009, 324(5923): 63-66. |
| [3] | W. Eerenstein, N. D. Mathur and J. F. Scott. Multiferroic and magnetoelectric materials. Nature, 2006, 442 (7104): 759-765. |
| [4] | G. L. Don, G. K. Min, R. G. San, et al. Epitaxially grown Lamodified BiFeO3 magnetoferroelectric thin films. Applied Physics Letters, 2005, 86(22): 1-3. |
| [5] | Y. Wang, G. Xu, Z. Ren, X. Wei, W. Weng, P. Du, G. Shen and G. Han. Mineralizer-assisted hydrothermal synthesis and characterization of BiFeO3 nanoparticles. Journal of the American Ceramic Society, 2007, 90(8): 2615-2617. |
| [6] | C. Chen, J. Cheng, S. Yu, L. Che and Z. Meng, Hydrothermal synthesis of perovskite bismuth ferrite crystallites. Journal of Crystal Growth, 2006, 291(1): 135-139. |
| [7] | Y. Wang, G. Xu, L. Yang, Z. Ren, X. Wei, W. Weng, P. Du, G. Shen and G. Han. Alkali metal Ions-assisted controllable synthesis of bismuth ferrites by a hydrothermal method. Journal of the American Ceramic Society, 2007, 90 (11): 3673-3675. |
| [8] | C. M. Cho, J. H. Noh, I. S. Cho, J. S. An, K. S. Hong and J. Y. Kim. Low-temperature hydrothermal synthesis of pure BiFeO3 nanopowders using triethanolamine and their applications as visible-light photocatalysts. Journal of the American Ceramic Society, 2008, 91(11): 3753-3755. |
| [9] | 谈国强, 博海洋, 苗鸿雁, 夏傲, 贺中亮. 共沉淀法制备BiFeO3粉末[J]. 人工晶体学报, 2010, 39: 154-157. |
| [10] | N. Das, R. Majumdar, A. Sen and H. S. Maiti. Nanosized bismuth ferrite powder prepared through sonochemical and microemulsion techniques. Materials Letters, 2007, 61(10): 2100-2104. |
| [11] | S. Ghosh, S. Dasgupta, A. Sen and H. S. Maiti. Low-temperature synthesis of nanosized bismuth ferrite by soft chemical route. Journal of the American Ceramic Society, 2005, 88(5): 1349-1352. |
| [12] | J. K. Kim, S. S. Kim and W. J. Kim. Sol–Gel synthesis and properties of multiferroic BiFeO3. Materials Letters, 2005, 59(29-30): 4006-4009. |
| [13] | 苗鸿雁, 李佳, 谈国强, 梁云鹤, 张卫霞. 掺镧BiFeO3粉体的水热合成及性能研究[J]. 压电与声光, 2009, 31(3): 389-391. |
| [14] | J. T. Han, Y. H. Huang, X. J. Wu, C. L. Wu, W. Wei, B. Peng,W. Huang and J. B. Goodenough. Tunable synthesis of bismuth ferrites with various morphologies. Advanced Materials, 2006, 18(16): 2145-2158. |
| [15] | H. Zhang, K. Kajiyoshi. Hydrothermal synthesis and size-dep- endent properties of multiferroic bismuth ferrite crystallites. Journal of the American Ceramic Society, 2010, 93(11): 3842-3849. |
| [16] | M. Hojamberdiev, Y. Xu, F. Wang, W. Liu and J. Wang. La-Modi- fication of multiferroic BiFeO3 by hydrothermal method at low temperature. Inorganic Materials, 2009, 45(10): 1183-1187. |
