%0 Journal Article
%T First intercalibration of column-averaged methane from the Total Carbon Column Observing Network and the Network for the Detection of Atmospheric Composition Change
%A R. Sussmann
%A A. Ostler
%A F. Forster
%A M. Rettinger
%A N. M. Deutscher
%A D. W. T. Griffith
%A J. W. Hannigan
%A N. Jones
%A P. K. Patra
%J Atmospheric Measurement Techniques (AMT) & Discussions (AMTD)
%D 2013
%I Copernicus Publications
%X We present the first intercalibration of dry-air column-averaged mole fractions of methane (XCH4) retrieved from solar Fourier transform infrared (FTIR) measurements of the Network for the Detection of Atmospheric Composition Change (NDACC) in the mid-infrared (MIR) versus near-infrared (NIR) soundings from the Total Carbon Column Observing Network (TCCON). The study uses multi-annual quasi-coincident MIR and NIR measurements from the stations Garmisch, Germany (47.48¡ã N, 11.06¡ã E, 743 m a.s.l.), and Wollongong, Australia (34.41¡ã S, 150.88¡ã E, 30 m a.s.l.). Direct comparison of the retrieved MIR and NIR XCH4 time series for Garmisch shows a quasi-periodic seasonal bias leading to a standard deviation (stdv) of the difference time series (NIR¨CMIR) of 7.2 ppb. After reducing time-dependent a priori impact by using realistic site- and time-dependent ACTM-simulated profiles as a common prior, the seasonal bias is reduced (stdv = 5.2 ppb). A linear fit to the MIR/NIR scatter plot of monthly means based on same-day coincidences does not show a y-intercept that is statistically different from zero, and the MIR/NIR intercalibration factor is found to be close to ideal within 2-¦Ò uncertainty, i.e. 0.9996(8). The difference time series (NIR¨CMIR) do not show a significant trend. The same basic findings hold for Wollongong. In particular an overall MIR/NIR intercalibration factor close to the ideal 1 is found within 2-¦Ò uncertainty. At Wollongong the seasonal cycle of methane is less pronounced and corresponding smoothing errors are not as significant, enabling standard MIR and NIR retrievals to be used directly, without correction to a common a priori. Our results suggest that it is possible to set up a harmonized NDACC and TCCON XCH4 data set which can be exploited for joint trend studies, satellite validation, or the inverse modeling of sources and sinks.
%U http://www.atmos-meas-tech.net/6/397/2013/amt-6-397-2013.html