%0 Journal Article %T Simultaneous determination of molybdenum and tin by standard addition-dual wavelength spectrophotometry with trimethoxyphenylfluorone
三甲氧基苯基荧光酮标准加入双波长分光光度法同时测定钼和锡 %A SHAO Qian %A ZENG Yan %A GE Sheng-song %A
邵谦 %A 曾艳 %A 葛圣松 %J 冶金分析 %D 2012 %I %X The experimental conditions for the simultaneous determination of molybdenum and tin by standard addition-dual wavelength spectrophotometry with trimethoxyphenylfluorone were studied.Meanwhile,the synthetic sample of molybdenum and tin and aluminum alloy samples were determined.In the presence of sulfuric acid medium and surfactant OP-10,the determination wavelength and reference wavelength for spectrophotometric determination of molybdenum and tin with trimethoxyphenylfluorone are 524 nm and 503 nm,respectively.The ranges obeying Beer’s law were 0-20 μg/25 mL and 0-15 μg/25 mL,respectively.This method was applied to the simultaneous determination of molybdenum and tin in synthetic sample of molybdenum and tin and aluminum alloy actual samples.The recoveries were 97 %-106 %,and the relative standard deviations(RSD) were less than 3 %. %K trimethoxyphenylfluorone %K standard additions-dual wavelength spectrophotometry %K molybdenum %K tin
三甲氧基苯基荧光酮 %K 标准加入双波长分光光度法 %K 钼 %K 锡 %U http://www.alljournals.cn/get_abstract_url.aspx?pcid=5B3AB970F71A803DEACDC0559115BFCF0A068CD97DD29835&cid=2D0EECBAB3CF5455&jid=801503686266675EACDCAD01FB961264&aid=09A83131469FC5D48F74BC29A69DD555&yid=99E9153A83D4CB11&vid=9971A5E270697F23&iid=CA4FD0336C81A37A&sid=BFE7933E5EEA150D&eid=E84BBBDDD74F497C&journal_id=1000-7571&journal_name=冶金分析&referenced_num=0&reference_num=0