%0 Journal Article
%T The Effect of the CO32- to Ca2+ Ion activity ratio on calcite precipitation kinetics and Sr2+ partitioning
%A Tsigabu A Gebrehiwet
%A George D Redden
%A Yoshiko Fujita
%A Mikala S Beig
%A Robert W Smith
%J Geochemical Transactions
%D 2012
%I BioMed Central
%R 10.1186/1467-4866-13-1
%X Calcite was the only phase observed, by XRD, at the end of the experiments. Precipitation rates increased from 41.3 ¡À 3.4 ¦̀mol m-2 min-1 at r = 0.0315 to a maximum rate of 74.5 ¡À 4.8 ¦̀mol m-2 min-1 at r = 0.306 followed by a decrease to 46.3 ¡À 9.6 ¦̀mol m-2 min-1 at r = 1.822. The trend was simulated using a simple mass transfer model for solute uptake at the calcite surface. However, precipitation rates at fixed saturation states also evolved with time. Precipitation rates accelerated for low r values but slowed for high r values. These trends may be related to changes in effective reactive surface area. The    a   C     O   3     2 -     /   a   C   a   2 +    ratios did not affect the distribution coefficient for Sr in calcite (DPSr2+), apart from the indirect effect associated with the established positive correlation between DPSr2+ and calcite precipitation rate.At a constant supersaturation state (¦¸ = 9.4), varying the ion activity ratio affects the calcite precipitation rate. This behavior is not predicted by affinity-based rate models. Furthermore, at the highest ion ratio tested, no precipitation was observed, while at the lowest ion ratio precipitation occurred immediately and valid rate measurements could not be made. The maximum measured precipitation rate was 2-fold greater than the minima, and occurred at a carbonate to calcium ion activity ratio of 0.306. These findings have implications for predicting the progress and cost of remediation operations involving enhanced calcite precipitation where mineral precipitation rates, and the spatial/temporal distribution of those rates, can have significant impacts on the mobility of contaminants.Engineering the precipitation of calcite in groundwater has been proposed as a means for remediation of the radionuclide strontium-90, a byproduct of uranium fission and a common contaminant at nuclear facilities in the U.S. and abroad [1-4]. Because of the relatively short half-life of 90Sr (29 yrs), and the compatibil
%U http://www.geochemicaltransactions.com/content/13/1/1