%0 Journal Article
%T Synthesis, characterisation and reactions of cationic complexes of Arylantimony (III) chlorides ArnSbCl3-n with perchlorate and tetrafluoroborate anions
%A Ram Nath Prasad Yadav
%J International Journal of Applied Sciences and Biotechnology
%D 2013
%I SEM-Biotech Publishing
%R 10.3126/ijasbt.v1i2.8204
%X Several hitherto unreported cationic complexes of the general formula [Ar2SbL][Y] and [ArSbL2][Y]2 [ Where, Ar = C6H5, L = кв-Picoline, Pyridine, Ph3AsO, hexamethyl phosphoramide (HMPA), thiourea (TU) and Y = ClO4- BF4-] have been synthesized and characterized by solid state IR, 1H NMR, elemental analysis, conductance and molecular weight measurements. The physico- chemical data, cations [Ar2SbL]+1 and[ArSbL2]+2 are assigned a pyramidal structure.
%K arylantimony
%K cationic complex
%K chloride
%K elemental analysis
%K iii
%K ir spectra
%K molecular weight measurement
%K perchlorate
%K tetrafluoroborate
%U http://ijasbt.org/vol_1/yadav_IJASBT_1(2).pdf