%0 Journal Article
%T New Method of Generation of Carbon Molecules and Clusters
%A Alexey Kharlamov
%A Ganna Kharlamova
%A Marina Bondarenko
%A Veniamin Fomenko
%J Open Journal of Synthesis Theory and Applications
%P 38-45
%@ 2168-1252
%D 2013
%I Scientific Research Publishing
%R 10.4236/ojsta.2013.21004
%X <p align=\"justify\">
	<span style=\"font-family:Verdana;\">Firstly the method of joint synthesis of carbon molecules and their hydrides is developed. The stage of high-temperature sublimation of carbon in a new method of generation of carbon molecules is completely excluded. By mass spectro</span><span><span style=\"font-family:Verdana;\">metric method the condensation products of new method of pyrolysis (NMP) benzene are studied. Firstly clusters (C</span><sub><span style=\"font-family:Verdana;\">3</span></sub><span style=\"font-family:Verdana;\">-C</span><sub><span style=\"font-family:Verdana;\">17</span></sub><span style=\"font-family:Verdana;\">), typical for carbon vapour, in substances obtained under pyrolysis of hydrocarbons were detected. Fullerene C</span><sub><span style=\"font-family:Verdana;\">60</span></sub><span style=\"font-family:Verdana;\"> and its hydrides, quasi-fullerenes C</span><sub><span style=\"font-family:Verdana;\">48</span></sub><span style=\"font-family:Verdana;\"> and C</span><sub><span style=\"font-family:Verdana;\">33</span></sub><span style=\"font-family:Verdana;\"> inproducts of benzene pyrolysis are detected also. Firstly it is shown what clusters C</span><sub><span style=\"font-family:Verdana;\">3</span></sub><span style=\"font-family:Verdana;\">-C</span><sub><span style=\"font-family:Verdana;\">5</span></sub><span style=\"font-family:Verdana;\"> can be generated at so low (100?C-200?C) temperatures of decomposition of substance. Obtained experimental results firstly demonstrate that the small carbon molecules can be generated in reactionary conditions ex</span></span><span><span style=\"font-family:Verdana;\">cluding evaporation of carbon. Dehydrogenation and destruction of hydrocarbon molecules is the first stage on a route of the transformation of benzene to carbon molecules</span><span style=\"font-family:Verdana;\">.</span></span> 
</p>
%K Pyrolysis
%K Benzene
%K Fullerene
%K Quasi-Fullerene
%K Small Molecules
%K Mass Spectra
%K Carbon Clusters
%U http://www.scirp.org/journal/PaperInformation.aspx?PaperID=27200