%0 Journal Article %T On the Galvanic Modification of Seawater %A Alexander Shimkevich %J World Journal of Condensed Matter Physics %P 112-121 %@ 2160-6927 %D 2019 %I Scientific Research Publishing %R 10.4236/wjcmp.2019.94009 %X Chemical properties of seawater are studied at forced shifting of Fermi level ¦Å_F in the band gap of liquid water due to deviation of its composition H₂O_1−z ( | z£ü< 10^−13 ) from the stoichiometric one ( z = 0 ). It is shown that the hypo-stoichiometric state ( z > 0 ) of seawater emerges when Fermi level is shifted to the local electron level ¦ÅH₃O of hydroxonium H₃O⁺ in galvanic cell with the strongly polarized anode and the quasi-equilibrium cathode. Then, each ¦ÅH₃O is occupied by electron and hydroxonium radicals [H₃O] together with hydroxide anions [OH^−] form in seawater hydrated electrons [(H₂O)₂^−] . The opposite hyper-stoichiometric state ( z < 0 ) of seawater is gotten in galvanic cell with the strongly polarized cathode and the quasi-equilibrium anode. Then, Fermi level is shifted to the local energy level ¦ÅOH for removing electron from each hydroxide ion OH^− and forming hydroxyl radicals [OH] as strong oxidizers. It turned out that the ions of sodium and chlorine are connected into hydrates of sodium hypochlorite NaClO in this case. %K Non-Stoichiometric Seawater %K Band Gap %K Fermi Level %K Galvanic Cell %K Electron Donor %K Sodium Hypochlorite %U http://www.scirp.org/journal/PaperInformation.aspx?PaperID=96093