%0 Journal Article
%T Co(Salphen)线型聚合物用于催化2,3,6-三甲基苯酚氧化<br>Co(Salphen) Linear Polymer for Catalyzing the Oxidation Of 2,3,6-Trimethylphenol
%A 张合
%A 潘春跃
%J Studies in Synthetic Chemistry
%P 11-17
%@ 2332-7960
%D 2019
%I Hans Publishing
%R 10.12677/SSC.2019.72003
%X 以含溴的Co(Salphen) (双水杨醛缩邻苯二胺合钴)和1,4-苯二硼酸通过Suzuki偶联合成了一种含有Co(Salphen)的线型聚合物，其分子量通过凝胶渗透色谱测定，该聚合物用于催化2,3,6-三甲基苯酚氧化，24 h 2,3,6-三甲基苯酚的转化率可以达到99%，且该催化剂可以循环使用3次无明显的转化率和选择性下降。<br />
A linear polymer containing Co(Salphen) was synthesized by Suzuki coupling with bromine-containing Co(Salphen) and 1,4-benzenediboronic acid. The molecular weight was determined by gel permeation chromatography. The polymer was used to catalyze the oxidation of 2,3,6-trimethylphenol, the conversion of 2,3,6-trimethylphenol could reach 99% at 24 h and the catalyst could be recycled for 3 times without significant reduction in conversion.
%K Suzuki偶联，Co(Salphen)，线型聚合物，2
%K 3
%K 6-三甲基苯酚<br>Suzuki Coupling
%K Co(Salphen)
%K Linear Polymer
%K 2
%K 3
%K 6-Trimethylphenol
%U http://www.hanspub.org/journal/PaperInformation.aspx?PaperID=30702