%0 Journal Article
%T Determination of triacylglycerol oxidation mechanisms in canola oil using liquid chromatography¨Ctandem mass spectrometry
%A Fumiko Kimura
%A Junya Ito
%A Kiyotaka Nakagawa
%A Masayoshi Sakaino
%A Naoki Shimizu
%A Shunji Kato
%A Susumu Takekoshi
%A Takahiro Eitsuka
%A Takashi Sano
%A Teruo Miyazawa
%A Yasuhiko Hanzawa
%A Yurika Otoki
%J Archive of "NPJ Science of Food".
%D 2018
%R 10.1038/s41538-017-0009-x
%X Triacylglycerol (TG) oxidation mechanisms and the structures of triacylglycerol hydroperoxide isomers (a). Dioleoyl-linoleoyl glycerol (I) is oxidized to dioleoyl-(hydroperoxy octadecadienoyl) glycerol (OO-HpODE-TG, II¨CVII) by radical and/or singlet-oxygen oxidation. Hydroperoxide positions and geometrical structures depend on the TG peroxidation mechanisms. Schemes for the reference preparation of OO-HpODE-TG isomers (b). The references were synthesized from dioleoyl glycerol and HpODE isomer
%K Industry
%K Technology
%U https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6550225/