%0 Journal Article
%T Ion-Liquid Based Supercapacitors with Inner Gate Diode-Like Separators
%A Haim Grebel
%A Tazima S. Chowdhury
%J ChemEngineering | An Open Access Journal from MDPI
%D 2019
%R https://doi.org/10.3390/chemengineering3020039
%X In order to minimize unintentional discharge, supercapacitors are interfaced with a membrane that separates the anode from the cathode¡ªthis membrane is called the separator. We focus here on separators, which are structured as electronic diode-like. We call an electrically structured separator ¡°the gate¡±. Through experiments, it was demonstrated that ionic liquid-filled supercapacitors, which were interfaced with gated separators exhibited a substantial capacitance (C) increase and reduction in the equivalent series resistance (ESR) compared to cells with ordinary separators. These two attributes help to increase the energy, which is stored in a cell, since for a given cell¡¯s voltage, the dissipated energy on the cell, U R = V 2/4(ESR) and the stored energy, U C = CV 2/2, would increase. These were indeed ionic diodes since the order of the diode layout mattered¡ªthe diode-like structures exhibited maximum capacitance when their p-side faced the auxiliary electrode. View Full-Tex
%U https://www.mdpi.com/2305-7084/3/2/39