%0 Journal Article
%T A Rational Investigation of the Lewis Acid-Promoted Coupling of Carbon Dioxide with Cyclohexene Oxide: Towards CO2-Sourced Polycyclohexene Carbonate under Solvent- and Cocatalyst-Free Conditions
%J C ¡ª Journal of Carbon Research | An Open Access Journal from MDPI
%D 2019
%R https://doi.org/10.3390/c5030039
%X We report a rational investigation of the selective synthesis of poly(cyclohexene carbonate) from CO 2 and cyclohexene oxide by using commercially available Lewis acids with nontoxic metal centers. After a preliminary screening, we focused on the use of zinc salts, and the effect of the pressure, the temperature, the catalyst loading, and the presence of cocatalyst or a solvent on the reaction yields, selectivity, and molar masses was evaluated for selected catalytic platforms. Thus, we found that ZnTosylate in catalytic amounts under solvent- and cocatalyst-free conditions enables the selective synthesis of poly(cyclohexene carbonate) with a molecular weight of about 62.1 kg/mol with about 70% yields at 343 K and 4 MPa. To the best of our knowledge, this is a rare example of high molar mass polycyclohexene carbonates that are moreover obtained under solvent- and cocatalyst-free conditions. The high selectivity of ZnTos towards the formation of poly(cyclohexene carbonate) was interpreted, thanks to in situ FTIR spectroscopy and DFT calculations, as resulting from its ability to coactivate CO 2. View Full-Tex
%U https://www.mdpi.com/2311-5629/5/3/39