%0 Journal Article
%T 高岭土接枝流滴剂/聚乙烯复合材料的制备及性能
Preparation and properties of kaolin grafted alkyl amine type dripping agent/polyethylene composites
%A 朱丹彤
%A 吴倩
%A 李文斐
%A 姚占海
%J 复合材料学报
%D 2020
%R 10.13801/j.cnki.fhclxb.20190416.002
%X 通过表面接枝技术将流滴剂十八烷基二乙醇胺丙烯酸单酯(AAM)接枝到高岭土(Ka)表面,制得Ka与AAM接枝物(Ka-g-AAM);将Ka-g-AAM与线性低密度聚乙烯(LLDPE)熔融挤出,制备了Ka-g-AAM/LLDPE复合材料;利用FTIR、SEM、DSC和加速流滴仪等对Ka-g-AAM/LLDPE复合材料的结构和性能进行了表征。结果表明,与AAM/LLDPE和Ka-AAM/LLDPE复合材料相比,Ka-g-AAM/LLDPE复合材料中LLDPE的熔融温度、结晶温度和力学性能变化不大;Ka-g-AAM/LLDPE复合材料薄膜在60℃加速流滴期达23天,比AAM/LLDPE复合材料延长了4天。 The eighteen alkyl diethanolamine acrylic monoester dripping agent (AAM) was grafted onto kaolin (Ka) by surface grafting, the grafting of AAM and Ka (Ka-g-AAM) was prepared. Then Ka-g-AAM/linear low density polyethylene (LLDPE) composites were prepared by melt extrusion. The structure and properties of Ka-g-AAM/LLDPE were investigated by FTIR, SEM, DSC and acceleration dripping testing etc. The results indicate that AAM is grafted onto the surface of Ka. Compared with AAM/LLDPE and Ka-AAM/LLDPE composite, Ka-g-AAM/LLDPE composites have inconspicuous changes on the melting temperature, the crystallization temperature and mechanical properties. The acceleration dripping duration of Ka-g-AAM/LLDPE composite films is 23 days at 60℃, which is 4 days longer than that of AAM/LLDPE composite. 十三五国家重点研发计划(2016YFB0302401
%K 接枝
%K 高岭土
%K 复合材料
%K 流滴剂
%K 聚乙烯
graft
%K kaolin
%K composites
%K dripping agent
%K polyethylene
%U http://fhclxb.buaa.edu.cn/CN/abstract/abstract14672.shtml