%0 Journal Article
%T Merging Catalysis in Single Electron Steps with Photoredox Catalysis¡ªEfficient and Sustainable Radical Chemistry
%J -
%D 2019
%R https://doi.org/10.1021/acscatal.9b00787
%X We describe a combination of catalysts that allows the coupling of titanocene(III) catalysis with photoredox catalysis. Oxidation of radical intermediates by a photoredox catalyst opens novel catalytic mechanisms for reductive epoxide ring opening and redox-neutral epoxide radical arylation. In the former case, the requirement of metallic reductants and stoichiometric acidic additives is bypassed
%U https://pubs.acs.org/doi/10.1021/acscatal.9b00787