%0 Journal Article
%T Synthesis and Crystal Structures of Two Metal-Radical Complexes
%A Youjuan Zhang
%A Caiwen Zhang
%A Jing Chen
%J Open Journal of Inorganic Chemistry
%P 85-94
%@ 2161-7414
%D 2021
%I Scientific Research Publishing
%R 10.4236/ojic.2021.113006
%X Two new M(II)-radical complexes [M(hfac)<sub>2</sub>(IM-<span style=\"font-size:10.0pt;font-family:;\" \"=\"\"><i></i></span><i>o<span style=\"font-size:10.0pt;font-family:;\" \"=\"\"></span></i>-QN)] (M = Ni(<strong>1</strong>), Zn(<strong>2</strong>); IM-<span style=\"white-space:normal;font-size:10pt;font-family:;\" \"=\"\"><i></i></span><i><span style=\"white-space:normal;\">o</span><span style=\"white-space:normal;font-size:10pt;font-family:;\" \"=\"\"></span></i>-QN = 4'-quinoxalinyl-substituted imino nitroxide; <span style=\"font-family:\" font-size:13.3333px;white-space:normal;\"=\"\"><i></i></span><i>hfac<span style=\"font-family:\" font-size:13.3333px;white-space:normal;\"=\"\"></span></i> = hexafluoroa-cetylacetonate) have been synthesized and characterized by X-ray diffraction analysis, element analyses, IR and UV-Visible spectroscopy. X-ray analysis reveal that the structures of both complexes are similar configuration and differently spatial symmetries. The complex <strong>1</strong> crystallizes in the triclinic <span style=\"font-family:\" font-size:13.3333px;white-space:normal;\"=\"\"><i></i></span><i>P<span style=\"font-family:\" font-size:13.3333px;white-space:normal;\"=\"\"></span></i>ий space group with the respective cell parameters: <span style=\"font-family:\" font-size:13.3333px;white-space:normal;\"=\"\"><i></i></span><i>a<span style=\"font-family:\" font-size:13.3333px;white-space:normal;\"=\"\"></span></i> = 9.1189(18)&nbsp;<span style=\"color:#4F4F4F;font-family:-apple-system, \" font-size:16px;white-space:normal;background-color:#f7f7f7;\"=\"\"><span style=\"color:#4F4F4F;font-family:-apple-system, &quot;font-size:16px;white-space:normal;background-color:#F7F7F7;\">&amp;#197</span></span>, <span style=\"font-family:\" font-size:13.3333px;white-space:normal;\"=\"\"><i></i></span><i>b<span style=\"font-family:\" font-size:13.3333px;white-space:normal;\"=\"\"></span></i> = 9.836(2) <span style=\"color:#4F4F4F;font-family:-apple-system, \" font-size:16px;white-space:normal;background-color:#f7f7f7;\"=\"\"><span style=\"color:#4F4F4F;font-family:-apple-system, &quot;font-size:16px;white-space:normal;background-color:#F7F7F7;\">&amp;#197</span></span>, <span style=\"font-family:\" font-size:13.3333px;white-space:normal;\"=\"\"><i></i></span><i>c<span style=\"font-family:\" font-size:13.3333px;white-space:normal;\"=\"\"></span></i> = 18.537(4) <span style=\"color:#4F4F4F;font-family:-apple-system, \" font-size:16px;white-space:normal;background-color:#f7f7f7;\"=\"\"><span style=\"color:#4F4F4F;font-family:-apple-system,
%K M(II)-Radical Complex
%K Quinoxalinyl-Substituted Imino Nitroxide
%K Synthesized
%K Characterized
%U http://www.scirp.org/journal/PaperInformation.aspx?PaperID=110511