%0 Journal Article
%T PREPARATION, SPECTROSCOPIC CHARACTERIZATION OF A NEW Cd(II) COMPLEX CONTAINING TRIDENTATE NNO SCHIFF BASE DERIVED AND X-RAY CRYSTALLOGRAPHIC STRUCTURAL STUDY OF 3,4,5-TRIHYDROXYBENZOIC ACID[1-(PYRIDYL)-ETHYLIDENE]HYDRAZONE
%A ALHADI
%A ABEER A
%A SHAKER
%A SHAYMA A
%A SULEIMAN G
%A NURA
%A YEHYE
%A WAGEE A
%A MOHD ALI
%A HAPIPAH
%J Journal of the Chilean Chemical Society
%D 2012
%I Scientific Electronic Library Online
%R 10.4067/S0717-97072012000300018
%X a new cd(ii) complex with a tridentate schiff base derivative which was obtained from condensation of gallic hydrazid with 2-acetylpyridine has been prepared. the structure of the ligand 3,4,5-trihydroxybenzoic acid[1-(pyridyl)-ethylidene]hydrazone (gapy) was confirmed using the x-ray structure analysis. the elemental analysis, ftir, uv-vis, 1h nmr spectral and thermal analysis indicates that the schiff base ligand gapy is a tridentate ligand which is coordinated with the cd(ii) complex through n,n and o atoms. thus, the acetate ion is a bidentate ligand that is coordinated with the metal ion through two o atoms.
%K schiff base derivatives
%K cd(ii) complexes
%K hydrazone derivatives complexes
%K spectroscopic characterization.
%U http://www.scielo.cl/scielo.php?script=sci_abstract&pid=S0717-97072012000300018&lng=en&nrm=iso&tlng=en