%0 Journal Article
%T ELECTROCHEMICAL COPOLYMERIZATION OF CROSS-LINKABLE POLYTHIOPHENE AND CARBAZOLE
%A GAO
%A CHUANG
%A PEI
%A MEISHAN
%A PAN
%A QIWEI
%J Journal of the Chilean Chemical Society
%D 2012
%I Scientific Electronic Library Online
%R 10.4067/S0717-97072012000200019
%X the copolymerization of carbazole(c) and poly3-ethyl-3-({[6-(3-thienyl)hexyl]oxy}-methyl)oxetane(pto) was successfully achieved electrochemically in ch2cl2 containing 25% boron trifluoride diethyl etherate bfee(by volume) as supporting electrolyte by direct anodic oxidation of the monomer mixtures on platinum or an optically transparent ito electrode. as-formed copolymer own the advantages of pto, such as good electrochemical behaviors, excellent ambient stability. the structure of the copolymer were investigated by uv-vis, fluorescence spectra and thermal analysis, respectively. the fluorescence spectra indicate that pptoc films are yellow-light emitters. thermal analysis studies confirmed pptoc has a good thermal stability.
%K polythiophene
%K electrochemical polymerization
%K carbazole
%K copolymerization
%K boron trifluoride diethyl etherate.
%U http://www.scielo.cl/scielo.php?script=sci_abstract&pid=S0717-97072012000200019&lng=en&nrm=iso&tlng=en