%0 Journal Article
%T FUNCIONALIZACION DEL ANION BIS-(o-MERCAPTOBENZOATO)- CIS- DIOXOMOLIBDATO(VI), [MoO2(o-SC6H4COO)2]2-, CON ARILHIDRACINAS p-SUSTITUIDAS, R-p-C6H4NHNH2, R=H, Me, MeO, Cl, NO2: ESTRUCTURA DE RAYOS-X DE [Et3NH] 2[Mo(NNC6H4-p-Cl)2(o-SC6H4COO)2]
%A LI KAO
%A JULIA
%A CARRILLO
%A DAVID
%A VEGA
%A ANDRES
%A GARLAND
%A MARIA TERESA
%J Bolet¨ªn de la Sociedad Chilena de Qu¨ªmica
%D 2002
%I Scientific Electronic Library Online
%R 10.4067/S0366-16442002000100003
%X in acetonitrile, the cis-[moo2]2+ group present in the anionic complex [moo2(o-sc6h4coo)2]2-, can be functionalized under mild conditions by reaction with arylhydrazines, p-r-c6h4nhnh2. the resulting ionic complexes have been formulated as [et3nh]2[mo(nnc6h4-p-r)2(o-sc6h4coo)2], r=h, [et3nh]2[i]; me, [et3nh]2[ii]; meo, [et3nh]2[iii]; cl, [et3nh]2[iv]; no2, [et3nh]2[v], characterized by spectroscopic methods and, additionally, in the case of complex [et3nh]2[iv], by single crystal x-ray diffraction. the aryldiazenido ligands, occupying mutually cis positions, adopt the "singly bent" geometry
%K organodiazenido
%K aryldiazenido
%K diazenido
%K molybdenum complexes
%K o-mercaptobenzoate
%K molecular structure.
%U http://www.scielo.cl/scielo.php?script=sci_abstract&pid=S0366-16442002000100003&lng=en&nrm=iso&tlng=en