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波谱学杂志 2010
Synthesis and EPR Characterization of a Novel Functional Biradical
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Abstract:
A biradical TN3 was synthesized, which is composed of a fully substituted triphenylmethyl radical and a nitroxide. EPR spectrum of TN3 at room temperature consists of an asymmetric quartet broad lines, suggesting its typical biradical structure. Using- ascorbate as a model compound, we proved that TN3 can be used to evaluate redox status and oxygen level simultaneously.