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OALib Journal期刊
ISSN: 2333-9721
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Synthesis and EPR Characterization of a Novel Functional Biradical
一种新型功能化双自由基的合成及EPR表征

Keywords: 电子顺磁共振(EPR),双自由基,三苯甲基自由基,氮氧自由基,氧化还原态,氧气

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Abstract:

A biradical TN3 was synthesized, which is composed of a fully substituted triphenylmethyl radical and a nitroxide. EPR spectrum of TN3 at room temperature consists of an asymmetric quartet broad lines, suggesting its typical biradical structure. Using- ascorbate as a model compound, we proved that TN3 can be used to evaluate redox status and oxygen level simultaneously.

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