SELECTIVE LIGHT TRANSMISSION THROUGH 3D SKELETAL POLYMERIC COMPLEXES WITH CONTROLLABLE PORE SIZE
三维骨架聚合物的孔径调控及其滤光效应

A new method for synthesizing 3D skeletal polymers and coordinating polymer materials with controllable pore sizes is reported.The new method was based on a two-step phase separation,in the first step the curing reaction of epoxy resin in PEG medium was inhibited by using dodecylbenzenesulfonic acid to control the rate and extent of reaction induced phase separation;in the second step the obtained polymers in metastable state were treated with ZnSO_4 or CdSO_4 aqueous solutions to restart the phase separati...