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Triphenylcyclopropenium hydroxytris(pentafluorophenyl)borate salt for solvent free epoxy curing

DOI: 10.5155/eurjchem.3.4.395-398.693

Keywords: Epoxy , Initiator , Plasticizer , Borate salts , Polymerization , Infrared spectroscopy

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Abstract:

A triphenylcyclopropenium salt paired with hydroxytris(pentafluorophenyl)borate counter ion was synthesized as an initiator for cationic polymerization and its activity was compared with triphenylcyclopropenium hexafluoroantimonate. Triphenylcyclopropenium hydroxytris (pentafluorophenyl)borate exhibits excellent activity as a room temperature thermal initiator for epoxide polymerization under solvent free conditions, due to excellent solubility in epoxy resins.

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