The aim of this research study was to evaluate the influence of utilising natural polymers as a form of soil stabilization, in order to assess their potential for use in building applications. Mixtures were stabilized with a natural polymer (alginate) and reinforced with wool fibres in order to improve the overall compressive and flexural strength of a series of composite materials. Ultrasonic pulse velocity (UPV) and mechanical strength testing techniques were then used to measure the porous properties of the manufactured natural polymer-soil composites, which were formed into earth blocks. Mechanical tests were carried out for three different clays which showed that the polymer increased the mechanical resistance of the samples to varying degrees, depending on the plasticity index of each soil. Variation in soil grain size distributions and Atterberg limits were assessed and chemical compositions were studied and compared. X-ray diffraction (XRD), X-ray fluorescence spectroscopy (XRF), and energy dispersive X-ray fluorescence (EDXRF) techniques were all used in conjunction with qualitative identification of the aggregates. Ultrasonic wave propagation was found to be a useful technique for assisting in the determination of soil shrinkage characteristics and fibre-soil adherence capacity and UPV results correlated well with the measured mechanical properties. 1. Introduction The development of building systems has been inextricably linked throughout history with the evolution of construction materials and the technological advancements related to harvesting and exploiting our planet’s natural resources [1]. In recent years, the construction sector has been under increasing pressure to reduce its CO2 emissions and the volume of natural resources which it is responsible for consuming. Environmental concerns relating to the specification of contemporary materials which often involve energy-intensive and oil-dependent processes have become increasingly recognised [2] and with buildings, cities, and their associated infrastructure playing such a significant role in depleting our global resources, it is vital that material utilisation within buildings is specified with care in order to reduce the impact on our planet’s resources and delicate ecosystems. The purpose of this research was to explore the potential for developing a low embodied energy construction materials obtained where possible from natural, renewable resources. The main barrier to the use of natural materials at present, particularly in developed countries, is their perceived poor mechanical
References
[1]
J. M. Saiter, L. Dobircau, and N. Leblanc, “Are 100% green composites and green thermoplastics the new materials for the future?” International Journal of Polymer Science, vol. 2012, Article ID 280181, 7 pages, 2012.
[2]
M. F. Ashby, Materials and the Environment: Eco-Informed Material Choice, Elsevier, Oxford, UK, 2009.
[3]
P. McHenry, Adobe and Rammed Earth Construction. Adobe, Build It Yourself, 1994.
[4]
A. Debnath, S. V. Singh, and Y. P. Singh, “Comparative assessment of energy requirements for different types of residential buildings in India,” Energy and Buildings, vol. 23, no. 2, pp. 141–146, 1995.
[5]
J. O. Arumala and T. Gondal, Compressed Earth Building Blocks for Affordable Housing, RICS, COBRA, London, UK, 2007.
[6]
A. Heath, D. Maskell, P. Walker, M. Lawrence, and C. Fourie, “Modern earth masonry: structural properties and structural design,” Structural Engineering, vol. 90, no. 4, pp. 38–44, 2012.
[7]
E. A. Adam and P. J. Jones, “Thermophysical properties of stabilised soil building blocks,” Building and Environment, vol. 30, no. 2, pp. 245–253, 1995.
[8]
D. A. Adesanya, “Evaluation of blended cement mortar, concrete and stabilized earth made from ordinary Portland cement and corn cob ash,” Construction and Building Materials, vol. 10, no. 6, pp. 451–456, 1996.
[9]
L. K. Aggarwal, “Bagasse-reinforced cement composites,” Cement and Concrete Composites, vol. 17, no. 2, pp. 107–112, 1995.
[10]
V. Agopyan, H. Savastano Jr., V. M. John, and M. A. Cincotto, “Developments on vegetable fibre-cement based materials in S?o Paulo, Brazil: an overview,” Cement and Concrete Composites, vol. 27, no. 5, pp. 527–536, 2005.
[11]
E. A. Basha, R. Hashim, H. B. Mahmud, and A. S. Muntohar, “Stabilization of residual soil with rice husk ash and cement,” Construction and Building Materials, vol. 19, no. 6, pp. 448–453, 2005.
[12]
P. R. Blankenhorn, B. D. Blankenhorn, M. R. Silsbee, and M. DiCola, “Effects of fiber surface treatments on mechanical properties of wood fiber-cement composites,” Cement and Concrete Research, vol. 31, no. 7, pp. 1049–1055, 2001.
[13]
R. S. P. Coutts, “Fibre-matrix interface in air-cured wood-pulp fibre-cement composites,” Journal of Materials Science Letters, vol. 6, no. 2, pp. 140–142, 1987.
[14]
R. Bahar, M. Benazzoug, and S. Kenai, “Performance of compacted cement-stabilised soil,” Cement and Concrete Composites, vol. 26, no. 7, pp. 811–820, 2004.
[15]
J.-C. Morel, A. Pkla, and P. Walker, “Compressive strength testing of compressed earth blocks,” Construction and Building Materials, vol. 21, no. 2, pp. 303–309, 2007.
[16]
J. R. Prusinski and S. Bhattacharja, “Effectiveness of portland cement and lime in stabilizing clay soils,” Transportation Research Record, vol. 1, no. 1652, pp. 215–227, 1999.
[17]
M. Villamizar, V. Araque, C. Reyes, and R. Silva, “Effect of the addition of coal-ash and cassave peels on the engineering properties of compressed earth blocks,” Construction and Building Materials, vol. 36, pp. 276–286, 2012.
[18]
C. Galán-Marín, C. Rivera-Gómez, and J. Petric-Gray, “Effect of animal fibres reinforcement on stabilized earth mechanical properties,” Journal of Biobased Materials and Bioenergy, vol. 4, no. 2, pp. 121–128, 2010.
[19]
S. P. Raut, R. V. Ralegaonkar, and S. A. Mandavgane, “Development of sustainable construction material using industrial and agricultural solid waste: a review of waste-create bricks,” Construction and Building Materials, vol. 25, no. 10, pp. 4037–4042, 2011.
[20]
R. F. Craig, Craig’s Soil Mechanics, Spon Press, New York, NY, USA, 7th edition, 2004.
[21]
I. D. Hay, Z. U. Rehman, and B. H. Rehm, “Membrane topology of outer membrane protein AlgE which is required for alginate production in pseudomonas aeruginosa. Identification of two aflatrem biosynthesis gene loci in aspergillus flavus and metabolic engineering of penicillium paxilli to elucidate their function,” The American Society For Microbiology, vol. 76, no. 6, pp. 1806–1812, 2010.
[22]
I. L. Andresen, O. Skipnes, O. Smidsrod, K. Ostgaard, and P. C. Hemmer, “Some biological functions of matrix components in benthic algae in relation to their chemistry and the composition of seawater,” ACS Symposium Series of the American Chemical Society, vol. 48, pp. 361–381, 1977.
[23]
I. Donati and S. Paoletti, “Materials properties of alginates,” in Alginates: Biology and Applications, B. H. A. Rehm, Ed., pp. 1–54, Springer, Berlin, Germany, 2009.
[24]
G. L. Schneider, “Method of stabilizing soils,” USA Patent 4, 002, 633, 1977.
[25]
K. Friedemann, F. Stallmach, and J. K?rger, “NMR diffusion and relaxation studies during cement hydration-A non-destructive approach for clarification of the mechanism of internal post curing of cementitious materials,” Cement and Concrete Research, vol. 36, no. 5, pp. 817–826, 2006.
[26]
C. Galán-Marín, C. Rivera-Gómez, and J. Petric, “Clay-based composite stabilized with natural polymer and fibre,” Construction and Building Materials, vol. 24, no. 8, pp. 1462–1468, 2010.
[27]
C. Galán-Marín and G. Rivera-Gómez, “Method for stabilising clay soils with natural organic polymers reinforced with animal fibre,” Patent WO2012/101299, 2012.
[28]
N. Uddin and R. R. Kalyankar, “Manufacturing and structural feasibility of natural fiber reinforced polymeric structural insulated panels for panelized construction,” International Journal of Polymer Science, vol. 2011, Article ID 963549, 7 pages, 2011.
[29]
G. Design and M. F. Ashby, CES Edupak: Material Selector, 2012.
[30]
S. Lima, H. Varim, A. Sales, and V. Neto, “Analysis of the mechanical properties of compressed earth block masonry utilizing the sugarcane bagash ash,” Construction and Building Materials, vol. 35, pp. 829–837, 2012.
[31]
A. L. Martínez-Hernández, C. Velasco-Santos, M. de-Icaza, and V. M. Casta?o, “Dynamical-mechanical and thermal analysis of polymeric composites reinforced with keratin biofibres from chicken feathers,” Composites B, vol. 38, pp. 405–410, 2007.
[32]
“UNE-EN 583-1/A1. Non-destructive testing. Ultrasonic examination. Part 1: general principles,” AENOR, European Committee for Standardization, 2004.
[33]
“UNE-EN, 1015-11:2000/A1. Methods of test for mortar for masonry. Part 11: determination of flexural and compressive strength of hardened mortar,” AENOR, European Committee for Standardization, 2000.
[34]
reparation Protocol System PNT 07LRX0044, CITIUS, “Centro de Investigación, Tecnología e Innovación” (Research Center for Technology and Innovation) of the University of Seville, 2011.
[35]
C. Galán-Marín, C. Rivera-Gómez, and F. Bradley, “The mechanical properties and molecular bonding characteristics of clay-based natural composites reinforced with animal fibres,” Journal of Biobased Materials and Bioenergy, vol. 7, pp. 143–151, 2013.