Effects of gamma radiation and the polypropylene fibers on compressive properties of polymer concrete composites (PC) were studied. The PCs had a composition of 30?wt% of unsaturated polyester resin and 70?wt% of marble particles which have three different sizes (small, medium, and large). The PCs were submitted to 200, 250, and 300?kGy of radiation doses. The results show that the compressive properties depend on the combination of the polypropylene fiber concentration and the applied radiation dose. The compressive strength value is highest when using medium particle size, 0.1 vol% of polypropylene fibers and 250?kGy of dose; moreover, the compressive modulus decreases when increasing the particle size. 1. Introduction Polymer concrete (PC) is a composite material formed by combining mineral aggregates with a thermoset resin. In its elaboration several parameters must be taken into account, such as resin type, initiator, and accelerator concentrations. The unsaturated polyester resin (UPR) is the most widely used due to their balanced mechanical and chemical characteristics, its ease of handling, and low cost; for its polymerization, 2?wt% of methyl-ethyl-ketone peroxide (MEKP), as initiator, and 0.5?wt% of cobalt naphthenate as accelerator are normally used, with at least 40?wt% of styrene. The composition of polymer concrete is determined by its applications especially loading stress levels and ability to resist corrosive environment. PC is increasingly being used as an alternative to ordinary Portland cement concrete (PCC) in many applications, such as finishing work in cast-in-place applications, precast products, highway pavements, bridge decks, waste water pipes, and even decorative construction panels. In the last 40 years polymer concrete has made tremendous progress and continues to be very promising materials for a wide range of new and innovative applications. Moreover, the use of polymers should be well considered to guarantee better performance and improved sustainability [1–3]. Improvement on mechanical strength and chemical resistance is basic advantages of polymer concrete in comparison to ordinary Portland cement concrete (PCC). Three to five times on the compressive strength, high values for tensile strength (20?MPa), and flexural strength (50?MPa) are still an outstanding advantage of polymer concrete [3, 4]. Mechanical properties of polymer concrete depend on the type of resin and mineral aggregates. In the case of the last, higher specific surface means higher mechanical values, for example, (a) polymer concrete with clean sand
References
[1]
J. M. Laredo Dos Reis, “Mechanical characterization of fiber reinforced Polymer Concrete,” Materials Research, vol. 8, no. 3, pp. 357–360, 2005.
[2]
D. Van Gemert, L. Czarnecki, M. Maultzsch et al., “Cement concrete and concrete-polymer composites: two merging worlds: a report from 11th ICPIC Congress in Berlin, 2004,” Cement & Concrete Composites, vol. 27, no. 9-10, pp. 926–933, 2005.
[3]
L. Czarnecki, “Concrete-polymer composites: trends shaping and future,” International Journal of the Society of Materials Engineering for Resources, vol. 15, no. 1, pp. 1–5, 2007.
[4]
J. M. L. dos Reis, “Effect of textile waste on the mechanical properties of polymer concrete,” Materials Research, vol. 12, no. 1, pp. 63–67, 2009.
[5]
A. J. M. Ferreira, C. Tavares, and C. Ribeiro, “Flexural properties of polyester resin concretes,” Journal of Polymer Engineering, vol. 20, no. 6, pp. 459–468, 2000.
[6]
O. Gencel, W. Brostow, G. Martinez-Barrera, and M. S. Gok, “Mechanical properties of polymer concretes containing different amount of hematite or colemanite,” Polimery, vol. 57, no. 4, pp. 276–283, 2012.
[7]
O. Gencel, C. Ozel, F. Koksal, E. Erdogmus, G. Martínez-Barrera, and W. Brostow, “Properties of concrete paving blocks made with waste marble,” Journal of Cleaner Production, vol. 21, no. 1, pp. 62–70, 2012.
[8]
C. Vipulanandan and S. Mebarkia, “Flexural strength, toughness, and fracture properties of polyester composites,” Journal of Applied Polymer Science, vol. 50, no. 7, pp. 1159–1168, 1993.
[9]
J. M. L. Reis and A. J. M. Ferreira, “A contribution to the study of the fracture energy of polymer concrete and fibre reinforced polymer concrete,” Polymer Testing, vol. 23, no. 4, pp. 437–440, 2004.
[10]
N. Dharmarajan and C. Vipulanandan, “Fracture toughness of particle filled fiber reinforced polyester composites,” Journal of Applied Polymer Science, vol. 42, no. 3, pp. 601–607, 1991.
[11]
O. Gencel, C. Ozel, W. Brostow, and G. Martínez-Barrera, “Mechanical properties of self-compacting concrete reinforced with polypropylene fibres,” Materials Research Innovations, vol. 15, no. 3, pp. 216–225, 2011.
[12]
Z. Ajji, “Preparation of polyester/gypsum/composite using gamma radiation, and its radiation stability,” Radiation Physics and Chemistry, vol. 73, no. 3, pp. 183–187, 2005.
[13]
T. Jurkin and I. Puci?, “Post-irradiation crosslinking of partially cured unsaturated polyester resin,” Radiation Physics and Chemistry, vol. 75, no. 9, pp. 1060–1068, 2006.
[14]
G. Martínez-Barrera and W. Brostow, “Fiber-reinforced polymer concrete: property improvement by gamma irradiation,” in Gamma Radiation Effects on Polymeric Materials and Its Applications, C. Barrera-Díaz and G. Martínez-Barrera, Eds., pp. 27–44, Research Signpost, Kerala, India, 2009.
[15]
G. Martínez-Barrera, C. Menchaca Campos, and F. Ure?a-Nu?ez, “Gamma radiation as a novel technology for development of new generation concrete,” in Gamma Radiation, F. Adrovic, Ed., pp. 91–114, InTech, Rijeka, Croatia, 2012.
[16]
M. Levitt, D. J. McGahan, and P. R. Hills, “Comparision of concrete polymer composites produced by high energy radiation,” Journal of the Precast/Prestressed Concrete Institute, vol. 18, no. 3, pp. 35–41, 1973.
[17]
G. Martínez-Barrera, U. Texcalpa-Villarruel, E. Vigueras-Santiago, S. Hernández-López, and W. Brostow, “Compressive strength of Gamma-irradiated polymer concrete,” Polymer Composites, vol. 29, pp. 1210–1217, 2008.
[18]
G. Martínez-Barrera, M. E. Espinosa-Pesqueira, and W. Brostow, “Concrete + polyester + CaCO3: mechanics and morphology after gamma irradiation,” e-Polymers, Article ID 083, 2007.
[19]
E. A. Bobadilla-Sánchez, G. Martínez-Barrera, W. Brostow, and T. Datashvili, “Effects of polyester fibers and gamma irradiation on mechanical properties of polymer concrete containing CaCO3 and silica sand,” Express Polymer Letters, vol. 3, no. 10, pp. 615–620, 2009.
[20]
T. Nishiura, S. Nishijima, and T. Okada, “Creep behavior of epoxy resin during irradiation at cryogenic temperature,” Radiation Physics and Chemistry, vol. 56, no. 5-6, pp. 605–609, 1999.
[21]
I. Puci? and F. Ranogajec, “Phase separation during radiation crosslinking of unsaturated polyester resin,” Radiation Physics and Chemistry, vol. 67, no. 3-4, pp. 415–419, 2003.
[22]
G. Martínez-Barrera, L. F. Giraldo, B. L. López, and W. Brostow, “Effects of y radiation on fiber-reinforced polymer concrete,” Polymer Composites, vol. 29, no. 11, pp. 1244–1251, 2008.
[23]
G. Martínez-Barrera, A. L. Martínez-Hernández, C. Velasco-Santos, and W. Brostow, “Polymer concretes improved by fiber reinforcement and gamma irradiation,” e-Polymers, vol. 103, pp. 1–14, 2009.