This paper is about the conversion of wet waste stream into valuable products via thermal processing. Hydrothermal carbonization of sewage sludge was carried out at 200°C and 2.1?MPa in a closed reactor for 1–6?h. Main products were in solid and liquid phases. The resulting hydrochar was shown to have H/C and O/C ratios moving towards natural lignite, improved energetic content, and adsorption property in terms of iodine number. The aqueous solution was found to contain high concentration of plant food nutrients, especially nitrogen and potassium. They may be desirable for subsequent fuel and chemical production as well as applications in agriculture. The study shows that valuable products can be generated successfully from sewage sludge using hydrothermal carbonization. 1. Introduction Sewage sludge is generated as an inevitable by-product of wastewater treatment activity. Their production is expected to rapidly increase with urbanization and industrial development. In Thailand, for example, about 4,000 tons per day of dry, treated sewage sludge solids is generated. Sewage sludge consists of mostly offensive and toxic substances. It must be disposed of or managed properly, otherwise, serious effects on humans and ecological systems will occur. Several methods can be adopted for the management of sewage sludge, such as landfill disposal, incineration, and utilization in agriculture, but each of these options has important limitations. Both incineration and landfill are troubled by their lowly public image. There are always concerns regarding associated costs and emissions. Application of sewage sludge to agricultural lands is restricted due to possible contamination of the soil and vegetation as well as hazardous consequences for animals and human. The decline of the traditional disposal routes for sewage sludge has created a strong demand for more cost effective and environmentally acceptable alternatives. This has motivated the research community to search for innovative and beneficial use of sewage sludge for years [1, 2]. A very appealing method is hydrothermal carbonization (HTC), also known as subcritical water or hot compressed water carbonization. It is ideal for high moisture content material such as sewage sludge. HTC can be described as a thermochemical process for converting an organic feedstock into value-added products, at moderate temperatures (180–350°C) and pressures (2–10?MPa) in the presence of liquid water. Hydrothermal degradation of organic matter and synthesis of basic chemicals and fuels have recently gained considerable
References
[1]
S. Krigstin and M. Sain, “Fractionation of dry recycled papermill sludge to higher value components,” Journal of Biobased Materials & Bioenergy, vol. 1, no. 3, pp. 315–322, 2007.
[2]
K. M. Smith, G. D. Fowler, S. Pullket, and N. J. D. Graham, “Sewage sludge-based adsorbents: a review of their production, properties and use in water treatment applications,” Water Research, vol. 43, no. 10, pp. 2569–2594, 2009.
[3]
M. Sevilla and A. B. Fuertes, “The production of carbon materials by hydrothermal carbonization of cellulose,” Carbon, vol. 47, no. 9, pp. 2281–2289, 2009.
[4]
M. M. Titirici and M. Antonietti, “Chemistry and materials options of sustainable carbon materials made by hydrothermal carbonization,” Chemical Society Reviews, vol. 39, pp. 103–116, 2010.
[5]
A. Funke and F. Ziegler, “Hydrothermal carbonization of biomass: a summary and discussion of chemical mechanisms for process engineering,” Biofuels, Bioproducts and Biorefining, vol. 4, no. 2, pp. 160–177, 2010.
[6]
H. A. Ruiz, R. M. Rodriguez-Jasso, B. D. Fernandes, A. A. Vicente, and J. A. Teixeira, “Hydrothermal processing as an alternative for upgrading agriculture residues and marine biomass according to the biorefinery concept: a review,” Renewable & Sustainable Energy Reviews, vol. 21, pp. 35–51, 2013.
[7]
Q. Wang, H. Li, L. Chen, and X. Huang, “Monodispersed hard carbon spherules with uniform nanopores,” Carbon, vol. 39, no. 14, pp. 2211–2214, 2001.
[8]
X. Cui, M. Antonietti, and S.-H. Yu, “Structural effects of iron oxide nanoparticles and iron ions on the hydrothermal carbonization of starch and rice carbohydrates,” Small, vol. 2, no. 6, pp. 756–759, 2006.
[9]
M.-M. Titirici, A. Thomas, and M. Antonietti, “Back in the black: hydrothermal carbonization of plant material as an efficient chemical process to treat the CO2 problem?” New Journal of Chemistry, vol. 31, no. 6, pp. 787–789, 2007.
[10]
M. M. Titirici, A. Thomas, S.-H. Yu, J.-O. Müller, and M. Antonietti, “A direct synthesis of mesoporous carbons with bicontinuous pore morphology from crude plant material by hydrothermal carbonization,” Chemistry of Materials, vol. 19, no. 17, pp. 4205–4212, 2007.
[11]
D. Cao, Y. Sun, and G. Wang, “Direct carbon fuel cell: fundamentals and recent developments,” Journal of Power Sources, vol. 167, no. 2, pp. 250–257, 2007.
[12]
R. Demir-Cakan, N. Baccile, M. Antonietti, and M.-M. Titirici, “Carboxylate-rich carbonaceous materials via one-step hydrothermal carbonization of glucose in the presence of acrylic acid,” Chemistry of Materials, vol. 21, no. 3, pp. 484–490, 2009.
[13]
J. P. Paraknowitseh, A. Thomas, and M. Antonietti, “Carbon colloids prepared by hydrothermal carbonization as efficient fuel for indirect carbon fuel cells,” Chemistry of Materials, vol. 21, no. 7, pp. 1170–1172, 2009.
[14]
M. Sevilla and A. B. Fuertes, “Chemical and structural properties of carbonaceous products obtained by hydrothermal carbonization of saccharides,” Chemistry, vol. 15, no. 16, pp. 4195–4203, 2009.
[15]
B. Hu, K. Wang, L. Wu, S.-H. Yu, M. Antonietti, and M.-M. Titirici, “Engineering carbon materials from the hydrothermal carbonization process of biomass,” Advanced Materials, vol. 22, no. 7, pp. 813–828, 2010.
[16]
M. C. Rillig, M. Wagner, M. Salem et al., “Material derived from hydrothermal carbonization: effects on plant growth and arbuscular mycorrhiza,” Applied Soil Ecology, vol. 45, no. 3, pp. 238–242, 2010.
[17]
M. Sevilla, A. B. Fuertes, and R. Mokaya, “High density hydrogen storage in superactivated carbons from hydrothermally carbonized renewable organic materials,” Energy and Environmental Science, vol. 4, no. 4, pp. 1400–1410, 2011.
[18]
J. A. Libra, K. S. Ro, C. Kammann et al., “Hydrothermal carbonization of biomass residuals: a comparative review of the chemistry, processes and applications of wet and dry pyrolysis,” Biofuels, vol. 2, no. 1, pp. 71–106, 2011.
[19]
N. D. Berge, K. S. Ro, J. Mao, J. R. V. Flora, M. A. Chappell, and S. Bae, “Hydrothermal carbonization of municipal waste streams,” Environmental Science and Technology, vol. 45, no. 13, pp. 5696–5703, 2011.
[20]
I.-H. Hwang, H. Aoyama, T. Matsuto, T. Nakagishi, and T. Matsuo, “Recovery of solid fuel from municipal solid waste by hydrothermal treatment using subcritical water,” Waste Management, vol. 32, no. 3, pp. 410–416, 2012.
[21]
A. Shanableh, “Production of useful organic matter from sludge using hydrothermal treatment,” Water Research, vol. 34, no. 3, pp. 945–951, 2000.
[22]
J. Mumme, L. Eckervogt, J. Pielert, M. Diakité, F. Rupp, and J. Kern, “Hydrothermal carbonization of anaerobically digested maize silage,” Bioresource Technology, vol. 102, no. 19, pp. 9255–9260, 2011.
[23]
M. Escala, T. Zumbuhl, Ch. Koller, R. Junge, and R. Krebs, “Hydrothermal carbonization as an energy efficient alternative to established drying technologies for sewage sludge: a feasibility study on a laboratory scale,” Energy & Fuels, vol. 27, pp. 454–460, 2013.
[24]
S. M. Heilmann, H. T. Davis, L. R. Jader et al., “Hydrothermal carbonization of microalgae,” Biomass and Bioenergy, vol. 34, no. 6, pp. 875–882, 2010.
[25]
S. M. Heilmann, L. R. Jader, M. J. Sadowsky, F. J. Schendel, M. G. von Keitz, and K. J. Valentas, “Hydrothermal carbonization of distiller's grains,” Biomass and Bioenergy, vol. 35, no. 7, pp. 2526–2533, 2011.
[26]
X. Lu, B. Jordan, and N. D. Berge, “Thermal conversion of municipal solid waste via hydrothermal carbonization: comparison of carbonization products to products from current waste management techniques,” Waste Management, vol. 32, no. 7, pp. 1353–1365, 2012.
[27]
G. K. Parshetti, S. K. Hoekman, and R. Balasubramanian, “Chemical, structural and combustion characteristics of carbonaceous products obtained by hydrothermal carbonization of palm empty fruit bunches,” Bioresource Technology, vol. 135, pp. 683–689, 2012.