过渡金属化合物为高效催化剂有氧氧化生物质衍生5-羟甲基糠醛生成2,5-二甲酰基呋喃的研究
Transition Metal Compounds as Efficient Catalysts in Aerobic Oxidation of Biomass-Derived 5-Hydroxymethylfurfural to 2,5-Diformylfuran

DOI: 10.12677/SSC.2014.22005, PP. 41-49

Keywords: 催化氧化，5-羟甲基糠醛，2,5-二甲酰基呋喃，生物质，化学品
Catalytic Oxidation, 5-Hydroxymethylfurfural, 2,5-Diformylfuran, Biomass, Chemicals

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Abstract:

2,5-二甲酰基呋喃(DFF)是一种由5-羟甲基糠醛或其他生物基碳水化合物衍生的重要平台分子，它在有机合成工业的众多领域中具有许多潜在用途。鉴于其目前较高的价格以及合成技术的不成熟性，对该化合物的研究近年来已然成为研究热点。为了将来能够实现DFF工业化生产，已开发了一些技术用于该产品的高效生产。在本研究中，一些过渡金属化合物以及镧系化合物被用作有氧催化氧化生物质模型化合物5-羟甲基糠醛(5-HMF)获取高附加值DFF

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