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Spectrophotometric Characterization of the Complex Generated in Solution for the Reaction of H[Ru(III)Cl2(H2EDTA)] Complex with AETS Modifier Agent

DOI: 10.4236/ojsta.2014.34006, PP. 37-43

Keywords: [3-(2-Aminoethyl)aminopropyl]trimethoxysilane, H[Ru(III)Cl2(H2EDTA)] Complex, Spectrophotometric Method, Molar Absorptivity

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Abstract:

Spectrophotometric method was used to evaluate the kinetic of the complex formation from the reaction between H[Ru(III)Cl2(H2EDTA)] and the modifier agent [3-(2-aminoethyl)aminopropyl] trimethoxysilane (AEATS) (μ = 0.50 mol.dm-3 with NaCF3COO, 298.15 K), in pseudo-first order conditions. These studies showed that the reactions are successives producing several species influenced by the concentrations ratio. The electronics spectrum of all solutions showed a band in 457 nm with variable molar absorptivity (ε).

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