Chalcogenide glasses are very important in the modern technology especially selenium-based. These
glasses are sensitive to electromagnetic radiation useful in the infrared optics. The study investigated
the effect of substrate temperature on the as-deposited selenium-bismuth thin films in addition
to bismuth content. The films were deposited by flash evaporation method. Thickness of the
films was measured on a surface profiler and confirmed through calculation based on the Swanepoel
method. The spectral range of study was between 200 - 3000 nm. It is found that the effect of
increasing bismuth content on the as-deposited films led to increased absorption coefficient, reflectance,
refractive index and extinction coefficient while transmittance and optical band gap
energy decreased. On the other hand, reflectance, absorption coefficient, extinction coefficient, refractive
index, real and imaginary parts of dielectric constant increased with increase in substrate
temperature but transmittance and optical band gap energy decreased.
References
[1]
Mohd, N. and Zulfequar, M. (2012) DC Conductivity and Dielectric Behavior of Glassy Se100-xZnx Alloy. Journal of Inorganic Non-Metallic Materials, 2, 11-17. http://dx.doi.org/10.4236/ojinm.2012.22002
[2]
Elliot, S.R. (1991) Chalcogenide Glasses. In: Zarzycki, J., Ed., Materials Science and Technology, VCH, New York, 375-454.
[3]
Hafiz, M.M., El-Shazly, O. and Kinawy, N. (2001) Reversible Phase in BixSe100-x Chalcogenide Thin Films for Use as Optical Recording Medium. Applied Surface Science, 171, 231-241. http://dx.doi.org/10.1016/S0169-4332(00)00709-1
[4]
Popescu, M. (2006) Self-Organization in Amorphous Semiconductors and Chalcogenide Glasses. Journal of Advanced Materials, 8, 2164-2168.
[5]
Soltan, A.S., Abu El-Oyoun, M., Abu-Sehly, A.A. and Abdel-Latief, A.Y. (2003) Thermal Annealing Dependence of the Structural, Optical and Electrical Properties of Selenium-Tellurium Films. Materials Chemistry and Physics, 82, 101-106. http://dx.doi.org/10.1016/S0254-0584(03)00184-6
[6]
Elliot, S.R. and Steel, A.T. (1987) A Model for the Chemical Modification of Electrical Properties of Chalcogenide Glasses by Bismuth. Journal of Physics C: Solid State Physics, 20, 4335-4357. http://dx.doi.org/10.1088/0022-3719/20/27/012
[7]
Schottmiller, J., Tabak, M., Lucovsky, G. and Ward, A. (1970) The Effect of Valency on Transport Properties of in Vitreous Binary Alloys of Selenium. Journal of Non-Crystalline Solids, 4, 80-96. http://dx.doi.org/10.1016/0022-3093(70)90024-4
[8]
Minaev, V., Timoshenko, S. and Kalugin, V. (2005) Structural and Phase Transformations in Condensed Selenium. Journal of Optoelectronics and Advanced Materials, 7, 1717-1741.
[9]
Ohring, M. (2001) The Material Science of Thin Films. 5th Edition, Academic Press, London.
[10]
Born, M. and Wolf, E. (1999) Principles of Optics. 7th Edition, Cambridge University Press, London. http://dx.doi.org/10.1017/CBO9781139644181
[11]
Swanepoel, R. (1983) Determination of the Thickness and Optical Constants of Amorphous Silicon. Journal of Physics E: Scientific Instruments, 16, 1214-1218. http://dx.doi.org/10.1088/0022-3735/16/12/023
[12]
Barman, J., Sharma, K.C., Sarma, M. and Sarma, K. (2008) Structural and Optical Studies of Chemically Prepared CdS Nanocrystalline Thin Films. Indian Journal of Pure and Applied Physics, 46, 339-343.
[13]
Goswami, A. (2005) Thin Film Fundamentals. 5th Edition, New Age International, New Delhi.
[14]
Alwan, T.J. (2011) The Influence of Substrate Temperature on Density of States and Optical Properties of Ge0.2Te0.8 Thin Films. Lebanese Science Journal, 12, 91-100.
[15]
Tauc, J. (1974) Amorphous and Liquid Semiconductors. Plenum Press, London & New York. http://dx.doi.org/10.1007/978-1-4615-8705-7
[16]
Shaaban, E.R., Yahia, I.S. and El-Metwally, E.G. (2012) Validity of Swanepoel’s Method for Calculating the Optical Constants of Thick Films. Acta Physica Polonica A, 121, 628-635.
[17]
Majeed Khan, M.A., Zulfequar, M. and Husain, M. (2003) Optical Investigation of a-Se100-xBix Alloys. Optical Materials, 22, 21-29. http://dx.doi.org/10.1016/S0925-3467(02)00234-3
[18]
Chauhan, R., Tripathi A., Srivastava, A.K. and Srivastava, K.K. (2013) Effect of Swift Heavy Ion Irradiation on Optical and Structural Properties of Amorphous Ge-As-Se Thin Films. Chalcogenide Letters, 10, 63-71.
[19]
Ambika and Barman, P.B. (2012) Effect of Bi Addition on the Optical Band Gap of Se85Te15 Chalcogenide Thin Films. Journal of Non-Oxide Glasses, 3, 19-24.
[20]
Mulama, A.A., Mwabora, J.M., Oduor, A.O. and Muiva, C.M. (2014) Optical Properties and Raman Studies of Amor- phous Se-Bi Thin Films. The African Review of Physics, 9, 33-37.
[21]
Kumar, A., Heera, P., Barman, P.B. and Sharma, R. (2012) Optical Properties of Bi Doped Se-Te Thin Films. Journal of Ovonic Research, 8, 135-146.
[22]
Elliot, S.R. (2000) The Physics and Chemistry of Solids. John Wiley & Sons, Chichester.
[23]
Mulama, A.A., Mwabora, J.M., Oduor, A.O., Muiva, C.M. and Muthoka, B. (2014) Investigation of the Effect of Film Thickness on the Optical Properties of Amorphous Se85-xTe15Sbx Thin Films. African Journal of Physical Sciences, 1, 38-42.
[24]
Mansour, B.A., Shaban, H., Gad, S.A., El-Gendy, Y.A. and Salem, A.M. (2010) Effect of Film Thickness, Annealing and Substrate Temperature on the Optical and Electrical Properties of CuGa0.25In0.75Se2 Amorphous Thin Films. Journal of Ovonic Research, 6, 13-22.
[25]
Muiva, C.M., Sathiaraj, T.S. and Mwabora, J.M. (2012) Chemical Bond Approach to Optical Properties of Some Flash Evaporated Se100-xSbx Chalcogenide Alloys. The European Physical Journal of Applied Physics, 59, P1-P7. http://dx.doi.org/10.1051/epjap/2012120082