全部 标题 作者
关键词 摘要

OALib Journal期刊
ISSN: 2333-9721
费用:99美元

查看量下载量

相关文章

更多...

含蒽环的钳状氮杂环卡宾前体及银卡宾的合成
Synthesis of Pincer-Type N-Heterocylic Carbene Predecessors Based on Anthracene Moity and Its Silver Carbene

DOI: 10.12677/SSC.2015.32004, PP. 24-27

Keywords: 氮杂环卡宾,蒽,钳状
N-Heterocylic Carbene
, Anthracene, Pincer

Full-Text   Cite this paper   Add to My Lib

Abstract:

钳状氮杂环卡宾广泛用于阴离子识别和金属卡宾络合物制备。本文合成了四种含蒽环的钳状氮杂环卡宾前体和一种银氮杂环卡宾络合物,并对其结构进行了表征。
Pincer-type N-heterocylic Carbene (NHC) predecessor have been widely applied in anion recognition and preparation of meal NHCs. Herein, four pincer-type NHC predecessors and one of its silver complex containing anthracene ring were synthesized and characterized by NMR spectra.

References

[1]  Arduengo, A.J. Harlow, R.L. and Kline, M. (1991) A stable crystalline carbene. Journal of the American Chemical Society, 113, 361-363.
http://dx.doi.org /10.1021/ja00001a054
[2]  Lin, J.C.Y., Huang, R.T.W., Lee, C.S., et al. (2009) Coinage metal-N-heterocyclic carbene complexes. Chemical Reviews, 109, 3561-3598.
http://dx.doi.org /10.1021/cr8005153
[3]  Lin, I.J.B. and Vasam, C.S. (2007) Preparation and application of N-heterocyclic carbene complexes of Ag(I). Coordination Chemistry Reviews, 251, 642-670.
http://dx.doi.org /10.1016/j.ccr.2006.09.004
[4]  Garrison, J.C. and Youngs, W.J. (2005) Ag(I) N-heterocyclic carbene complexes: Synthesis, structure, and application. Chemical Reviews, 105, 3978-4008.
http://dx.doi.org /10.1021/cr050004s
[5]  Kantche,E.A.B., OBrien, C.J. and Organ, M.J. (2007) Palladium complexes of N-heterocyclic carbenes as catalysts for cross-coupling reactions—A synthetic chemists perspective. Angewandte Chemie International Edition, 46, 2768-2813.
http://dx.doi.org /10.1002/anie.200601663
[6]  Nebioglu, A.K., Panzne, M.J., Tessier, C.A., et al. (2007) N-Heterocyclic carbine-silver complexes: A new class of antibiotics. Coordination Chemistry Reviews, 252, 884-89.
http://dx.doi.org /10.1016/j.ccr.2006.08.019
[7]  Qin, D., Zeng, X.S., Li, Q.S., et al. (2007) Silver(I) N-heterocyclic carbene-bridged calix-[4] arene analogues as efficient [60]fullerene receptor. Chemical Communications, 38, 147-149.
http://dx.doi.org /10.1039/B612421F
[8]  Liu, Q.X., Yao, Z.Q., Zhao, X.J., et al. (2011) Two N-heterocyclic carbene silver(I) cyclophanes: Synthesis, structural studies, and recognition for p-phenylenediamine. Organometallics, 30, 3732-3739.
http://dx.doi.org /10.1021/om1012117
[9]  Kim, S.K., Seo, E., Han, S.J., et al. (2008) A new imidazolium acridine derivative as ?uorescent chemosensor for pyrophosphate and dihydrogen phosphate. Tetrahedron, 64, 6402-6405.
http://dx.doi.org /10.1016/j.tet.2008.04.085
[10]  Lee, H.N., Singh, N.J., Kim, S.K., et al. (2007) New imidazolium systems bearing two pyrene groups as ?uorescent chemosensors for anions and anion induced logicgates. Tetrahedron Letters, 48, 169-172.
http://dx.doi.org /10.1016/j.tetlet.2006.10.161
[11]  Ghosh, K., Saha, I. and Patra, A. (2009) Design and synthesis of an ortho-phenylenediamine-based open cleft: A selective fluorescent chemosensor for dihydrogen phosphate. Tetrahedron Letters, 50, 2392-2397.
http://dx.doi.org /10.1016/j.tetlet.2009.02.215
[12]  Kim, S.K., Singh, N,J., Kwon, J., et al. ( 2006) Fluorescent imidazolium receptors for the recognition of pyrophosphate. Tetrahedron, 62, 6065-6072.
http://dx.doi.org /10.1016/j.tet.2006.03.107
[13]  Shi, Z.W., Li, Y. and Lu, G.Y. (2005) Synthes is of 1,8-D ihydroxy-9,10-dihydroan thracene. Chemical Journal of Chinese Universities, 26, 667-670.
[14]  Casnati, A., Pochini, A., Ungaro, R., et al. (1995) Synthesis, complexation, and membrane transport studies of 1,3-alternate calix[4] arene-crown-6 conformers: A new class of cesium selective ionophores. Journal of the American Chemical Society, 117, 2767-2777.
http://dx.doi.org /10.1021/ja00115a012

Full-Text

comments powered by Disqus

Contact Us

service@oalib.com

QQ:3279437679

WhatsApp +8615387084133

WeChat 1538708413