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有机化学 2015

苯炔对双键插入反应的研究进展有机化学

DOI: 10.6023/cjoc201411041, PP. 770-780

吴春蕊, 杨玉坡, 史峰

Keywords: 苯炔,邻亚甲基醌,活性中间体,周环反应,串联反应

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Abstract:

苯炔对双键的插入反应是近年来苯炔化学的一个热点领域.苯炔对双键插入将产生一个邻亚甲基醌型中间体,后者和苯炔一样是有机反应的重要活性中间体之一.综述了近年来苯炔对双键的插入反应及其在合成化学中的应用,并力图从反应机理的角度对这些插入反应及其生成的中间体进行结构上和反应活性上的阐释.

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