全部 标题 作者
关键词 摘要

OALib Journal期刊
ISSN: 2333-9721
费用:99美元

查看量下载量

相关文章

更多...
科学通报  2015 

低共熔溶剂在混合物分离中的应用

DOI: 10.1360/N972015-00385, PP. 2490-2499

Keywords: 低共熔溶剂,物化性质,混合物分离,过程特点,进展

Full-Text   Cite this paper   Add to My Lib

Abstract:

低共熔溶剂(DES)是一种新型的绿色溶剂,由于其独特的特性,如合成容易、成本低、环境友好、挥发性小、溶解能力强、可设计性等,在混合物分离方面得到广泛的应用.本文介绍了DES的物理化学性质,论述了DES在酸性气体(CO2,SO2和H2S)的分离、生物柴油中副产物的分离、燃料油脱硫、油中酚类化合物分离、油中芳烃的分离、苯羧酸同分异构体的分离、金属氧化物或者盐的分离、萃取天然产物、醇和酯混合物分离等方面的研究进展,分析了这些基于DES的分离过程的特点,探讨了DES在这些混合物分离过程中存在的问题,并提出了未来的发展建议.

References

[1]  1 Abbott A P, Capper G, Davies D L, et al.Novel solvent properties of choline chloride/urea mixtures.Chem Commun, 2003,(1):70-71
[2]  2 Smith E L, Abbott A P, Ryder K S.Deep eutectic solvents(DESs)and their applications.Chem Rev, 2014, 114:11060-11082
[3]  3 Zhang Y Y, Ji X Y, Lu X H.Application of choline-based deep eutectic solvents in CO2 capture and separation.CIESC J, 2014, 65:1721-1728 [张盈盈, 吉晓燕, 陆小华.胆碱类低共融溶剂在CO2捕集与分离中的应用.化工学报, 2014, 65:1721-
[4]  4 Abbott A P, Boothby D, Capper G, et al.Deep eutectic solvents formed between choline chloride and carboxylic acids:Versatile alternatives to ionic liquids.J Am Chem Soc, 2004, 126:9142-9147
[5]  5 Guo W J, Hou Y C, Ren S H, et al.Formation of deep eutectic solvents by phenols and choline chloride and their physical properties.J Chem Eng Data, 2013, 58:866-872
[6]  6 Maugeri Z, Domínguez de María P.Novel choline-chloride-based deep-eutectic-solvents with renewable hydrogen bond donors:Levulinic acid and sugar-based polyols.RSC Adv, 2012, 2:421-425
[7]  7 Hou Y W, Gu Y Y, Zhang S M, et al.Novel binary eutectic mixtures based on imidazole.J Mol Liq, 2008, 143:154-150
[8]  8 Kareem M A, Mjalli F S, Hashim M A, et al.Phosphonium-based ionic liquids analogues and their physical properties.J Chem Eng Data, 2010, 55:4632-4637
[9]  9 Abbott A P, Harris R C, Ryder K S, et al.Glycerol eutectics as sustainable solvent systems.Green Chem, 2011, 13:82-90
[10]  10 Hou Y W, Gu Y Y, Zhang S M, et al.Novel binary eutectic mixtures based on imidazole.J Mol Liq, 2008, 143:154-159
[11]  11 Shahbaz K, Mjalli F S, Hashim M A, et al.Prediction of the surface tension of deep eutectic solvents.Fluid Phase Equilibr, 2012, 319:48-54
[12]  12 Abbott A P, Cullis P M, Gibson M J, et al.Extraction of glycerol from biodiesel into a eutectic based ionic liquid.Green Chem, 2007, 9:868-872
[13]  13 Wu D, Wu B, Zhang Y M, et al.Density, viscosity, refractive index and conductivity of 1-allyl-3-methylimidazolium chloride + water mixture.J Chem Eng Data, 2010, 55:621-624
[14]  14 Leron R B, Li M H.Solubility of carbon dioxide in a eutectic mixture of choline chloride and glycerol at moderate pressures.J Chem Thermodyn, 2013, 57:131-136
[15]  15 Leron R B, Li M H.Solubility of carbon dioxide in a choline chloride-ethylene glycol based deep eutectic solvent.Thermochim Acta, 2013, 551:14-19
[16]  16 Lin C M, Leron R B, Caparanga A R, et al.Henry's constant of carbon dioxide-aqueous deep eutectic solvent(choline chloride/ethylene glycol, choline chloride/glycerol, choline chloride/malonic acid)systems.J Chem Thermodyn, 2014, 68:216-220
[17]  17 Leron R B, Caparanga A, Li M H.Carbon dioxide solubility in a deep eutectic solvent based on choline chloride and urea at T=303.15-343.15 K and moderate pressures.J Taiwan Inst Chem Eng, 2013, 44:879-885
[18]  18 Li X Y, Hou M Q, Han B X, et al.Solubility of CO2 in a choline chloride + urea eutectic mixture.J Chem Eng Data, 2008, 53:548-550
[19]  19 Francisco M, van den Bruinhorst A, Zubeir L F, et al.A new low transition temperature mixture(LTTM)formed by choline chloride plus lactic acid:Characterization as solvent for CO2 capture.Fluid Phase Equilibr, 2013, 340:77-84
[20]  20 Yang D Z, Hou M Q, Ning H, et al.Efficient SO2 absorption by renewable choline chloride-glycerol deep eutectic solvents.Green Chem, 2013, 15:2261-2265
[21]  21 Guo B, Duan E H, Ren A, et al.Solubility of SO2 in caprolactam tetrabutyl ammonium bromide ionic liquids.J Chem Eng Data, 2010, 55:1398-1401
[22]  22 Guo B, Duan E, Zhong Y F, et al.Absorption and oxidation of H2S in caprolactam tetrabutyl ammonium bromide ionic liquid.Energ Fuel, 2011, 25:159-161
[23]  23 Jin M J, Hou Y C, Wu W Z, et al.Solubilities and thermodynamic properties of SO2 in ionic liquids.J Phys Chem B, 2011, 115:6585-6591
[24]  24 Hayyan M, Mjalli F S, Hashim M A, et al.A novel technique for separating glycerine from palm oil-based biodiesel using ionic liquids.Fuel Process Technol, 2010, 91:116-120
[25]  25 Shahbaz K, Mjalli F S, Hashim M A, et al.Using deep eutectic solvents based on methyl triphenyl phosphunium bromide for the removal of glycerol from palm-oil-based biodiesel.Energ Fuel, 2011, 25:2671-2678
[26]  26 Li C P, Li D, Zou S S, et al.Extraction desulfurization process of fuels with ammonium-based deep eutectic solvents.Green Chem, 2013, 15:2793-2799
[27]  27 Sun Z, Zhao D, Li F, et al.Optimization of oxidative desulfurization of dibenzothiophene using a coordinated ionic liquid as catalytic solvent.Pet Sci Technol, 2009, 27:1907-1918
[28]  28 Pang K, Hou Y C, Wu W Z, et al.Efficient separation of phenols from oils via forming deep eutectic solvents.Green Chem, 2012, 14:2398-2401
[29]  29 Guo W J, Hou Y C, Wu W Z, et al.Separation of phenol from model oils with quaternary ammonium salts via forming deep eutectic solvents.Green Chem, 2013, 15:226-229
[30]  30 Gonzalez E J, Calvar N, Gonzaalez B, et al.Liquid extraction of benzene from its mixtures using 1-ethyl-3-methylimidazolium ethylsulfate as a solvent.J Chem Eng Data, 2010, 55:4931-4936
[31]  31 Kareem M A, Mjalli F S, Hashim M A, et al.Liquid-liquid equilibria for the ternary system(phosphonium based deep eutectic solvent-benzene-hexane)at different temperatures:A new solvent introduced.Fluid Phase Equilibr, 2012, 314:52-59
[32]  32 Kareem M A, Mjalli F S, Hashim M A, et al.Phase equilibria of toluene/heptane with deep eutectic solvents based on ethyltriphenylphosphonium iodide for the potential use in the separation of aromatics from naphtha.J Chem Thermodyn, 2013, 65:138-149
[33]  33 Mulyono S, Hizaddin H F, Alnashef I M, et al.Separation of BTEX aromatics from n-octane using a(tetrabutylammonium bromide plus sulfolane)deep eutectic solvent-experiments and COSMO-RS prediction.RSC Adv, 2014, 4:17597-17606
[34]  34 Hou Y C, Li Z Y, Ren S H, et al.Separation of toluene from toluene/alkane mixtures with phosphonium salt based deep eutectic solvents.Fuel Process Technol, 2015, 135:99-104
[35]  35 Wang W H, Hou Y C, Wu W Z, et al.Simultaneous production of small-molecule fatty acids and benzene polycarboxylic acids from lignite by alkali-oxygen oxidation.Fuel Process Technol, 2013, 112:7-11
[36]  36 Hou Y C, Li J, Ren S H, et al.Separation of the isomers of benzene poly(carboxylic acid)s by quaternary ammonium salt via formation of deep eutectic solvents.J Phys Chem B, 2014, 118:13646-13650
[37]  37 Abbott A P, Frisch G, Hartley J, et al.Processing of metals and metal oxides using ionic liquids.Green Chem, 2013, 13:471-481
[38]  38 Abbott A P, Capper G, Davies D L, et al.Selective extraction of metals from mixed oxide matrixes using choline-based ionic liquids.Inorg Chem, 2005, 44:6497-6499
[39]  39 Dai Y T, Witkamp G J, Verpoorte R, et al.Natural deep eutectic solvents as a new extraction media for phenolic metabolites in carthamus tinctorius L.Anal Chem, 2013, 85:6272-6278
[40]  40 Maugeri Z, Leitner W, Dominguez de Maria P.Practical separation of alcohol-ester mixtures using deep-eutectic-solvents.Tetrahedr Lett, 2012, 53:6968-6971
[41]  41 Dai Y T, Spronsen J V, Witkamp G J, et al.Ionic liquids and deep eutectic solvents in natural products research:Mixtures of solids as extraction solvents.J Nat Prod, 2013, 76:2162-2173

Full-Text

Contact Us

[email protected]

QQ:3279437679

WhatsApp +8615387084133