|
OALib Journal期刊
ISSN: 2333-9721
费用：99美元
|
|
|
|
铝离子在beta沸石晶化过程中对多形体A富集的影响
DOI: 10.1016/S1872-2067(14)60300-4, PP. 889-896
Keywords: beta沸石,手性,A形体,富集
Abstract:
？以四乙基氢氧化铵为有机结构导向剂,采用超浓水热方法,从氟离子体系合成出手性多形体A(简称A形体)富集的全硅beta沸石.在同样的初始混合物中引入铝源后,所合成的beta沸石中A形体含量明显降低,产物为普通的硅铝beta沸石.用粉末X射线衍射、元素分析、热重-差热分析、氮气吸附、扫描电子显微镜和固体魔角自旋核磁共振等表征手段对全硅beta沸石和硅铝beta沸石进行了详细的表征,并研究了其晶化过程.结果表明,铝源的引入可以加速beta沸石的晶化,得到的硅铝beta沸石晶体粒径明显减小.在硅铝beta沸石的晶化过程中生成了五配位铝物种,五配位铝物种可能是导致产物中A形体含量降低的原因.
| [1] | Wadlinger R L, Kerr G T, Rosinski E J. US Patent 3 308 069. 1967
|
| [2] | Newsam J M, Treacy M M J, Koetsier W T, De Gruyter C B. Proc R Soc Lond A, 1988, 420: 375
|
| [3] | Higgins J B, LaPierre R B, Schlenker J L, Rohrman A C, Wood J D, Kerr G T, Rohrbaugh W J. Zeolites, 1988, 8: 446
|
| [4] | Davis M E, Lobo R F. Chem Mater, 1992, 4: 756
|
| [5] | Camblor M A, Corma A, Valencia S. Chem Commun, 1996: 2365
|
| [6] | Xia Q H, Shen S C, Song J, Kawi S, Hidajat K. J Catal, 2003, 219: 74
|
| [7] | Takagi Y, Komatsu T, Kitabata Y. Microporous Mesoporous Mater, 2008, 109: 567
|
| [8] | Taborda F, Willhammar T, Wang Z Y, Montes C, Zou X D. Microporous Mesoporous Mater, 2011, 143: 196
|
| [9] | Tong M Q, Yan W F, Yu J H, Xu R R. Chem J Chin Univ (童明全, 闫文付, 于吉红, 徐如人. 高等学校化学学报), 2013, 34: 494
|
| [10] | Guo W, Yan W F, Xu R R, Wang Y R, Mu X H. Chem J Chin Univ (郭文, 闫文付, 徐如人, 王永睿, 慕旭宏. 高等学校化学学报), 2014, 35: 1363
|
| [11] | Camblor M A, Corma A, Martinez A, Perez-Pariente J. J Chem Soc, Chem Commun, 1992: 589
|
| [12] | Corma A, Nemeth L T, Renz M, Valencia S. Nature, 2001, 412: 423
|
| [13] | Jin J J, Ye X X, Li Y S, Wang Y Q, Li L, Gu J L, Zhao W R, Shi J L. Dalton Trans, 2014, 43: 8196
|
| [14] | Li Y J, Armor J N. Chem Commun, 1997: 2013
|
| [15] | Santi D, Holl T, Calemma V, Weitkamp J. Appl Catal A, 2013, 455: 46
|
| [16] | Zhu Y Z, Chuah G, Jaenicke S. J Catal, 2004, 227: 1
|
| [17] | Hazm J E, Caullet P, Paillaud J L, Soulard M, Delmotte L. Microporous Mesoporous Mater, 2001, 43: 11
|
| [18] | Bourgeat-Lami E, Di Renzo F, Fajula F, Mutin P H, Des Courieres T. J Phys Chem, 1992, 96: 3807
|
| [19] | Camblor M A, Corma A, Valencia S. Microporous Mesoporous Mater, 1998, 25: 59
|
| [20] | Serrano D P, Van Grieken R, Sanchez P, Sanz R, Rodriguez L. Microporous Mesoporous Mater, 2001, 46: 35
|
| [21] | Camblor M A, Corma A, Valencia S. J Mater Chem, 1998, 8: 2137
|
| [22] | Hartmeyer G, Marichal C, Lebeau B, Caullet P, Hernandez J. J Phys Chem C, 2007, 111: 6634
|
| [23] | Harris R K, Newman R H. J Chem Soc, Faraday Trans 2, 1977, 73: 1204
|
Full-Text
|
|
Contact Us
[email protected] QQ:3279437679 
WhatsApp +8615387084133
|
|
