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OALib Journal期刊
ISSN: 2333-9721
费用：99美元
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可聚合乳化剂合成醋酸乙烯酯-叔碳酸乙烯酯共聚乳液
Keywords: 反应性乳化剂,醋酸乙烯酯,叔碳酸乙烯酯,力学性能,稳定性
Abstract:
？以1-烯丙氧基-3-（4-壬基苯氧基）-2-丙醇聚氧乙烯（10）醚单磷酸（anpeo10-p1）为可聚合乳化剂合成了醋酸乙烯酯（vac）-叔碳酸乙烯酯（veova-10）共聚乳液，考察了anpeo10-p1用量对乳液的聚合稳定性、离子稳定性及胶膜耐水性的影响，并利用热重分析和拉伸试验等方法对胶膜进行了表征。结果表明：当anpeo10-p1用量为单体质量的5％时，合成的乳液聚合稳定性较好，单体转化率达到96.59％；与常规复合乳化体系（sds/op-10）相比，采用反应性乳化剂anpeo10-p1制备的乳液离子稳定性好，乳胶膜耐水性增强，膜的力学性能提高。热重分析表明：乳胶膜的分解温度为285～510℃，与膨胀型阻燃体系的分解温度匹配性较好，乳液可用于膨胀型防火涂料。
| [1] | naghashhj,abilib.synthesisofasiliconecontainingallylicmonomeranditsusesinthewaterbornepolyurethanevinylacetate-acrylichybridemulsioncopolymers[j].progressinorganiccoatings,2010,69（4）:486-494.
|
| [2] | jahanzadf.somecomparativeaspectsofparticleformationandrateofreactioninemulsionpolymerizationofvinylacetateandbutylacrylate[j].journalofappliedpolymerscience,2010,117（1）:84-90.
|
| [3] | zhongl,zhouc,cher,etal.preparationandadhesionpropertyofalowtemperaturecross-linkablevinylacetate-acrylatecopolymerlatex[j].polymer-plasticstechnologyandengineering,2010,49（15）:1515-1520.
|
| [4] | 彭陆雷,陈海松,沈国鹏.叔碳酸乙烯酯改性醋丙乳液的制备与性能研究[j].粘接,2011,32（8）:56-60.
|
| [5] | farwahar,desousagomesl.vinylacetate-versaticacidvinylestercopolymerformasonrycoatings[j].jctcoatingstech,2010,7（1）:36-38.
|
| [6] | abadc,delacaljc,asuajm.emulsioncopolymerizationincontinuousloopreactors[j].chemicalengineeringscience,1994,49（24）:5025-5037.
|
| [7] | araujophh,delacaljc,asuajm,etal.modelingparticlesizedistribution（psd）inemulsioncopolymerizationreactionsinacontinuousloopreactor[j].macromoleculartheoryandsimulations,2001,10（8）:769-779.
|
| [8] | luhs,lizx,fengyg,etal.preparationandpropertiesofanionicpolymeremulsioninthepresenceofareactivesurfactant[j].appliedmechanicsandmaterials,2013,262:430-434.
|
| [9] | xugl,dengll,wenxf,etal.synthesisandcharacterizationoffluorine-containingpoly-styrene-acrylatelatexwithcore-shellstructureusingareactivesurfactant[j].journalofcoatingstechnologyandresearch,2011,8（3）:401-407.
|
| [10] | ovando-medinavm,pia-garcaps,corona-riverama,etal.semicontinuousheterophasepolymerizationofmethylmethacrylateinthepresenceofreactivesurfactanthitenolbc10[j].polymerbulletin,2012,68（9）:2313-2322.
|
| [11] | urquiolamb,dimonievl,sudoled,etal.emulsionpolymerizationofvinylacetateusingapolymerizablesurfactant.ii.polymerizationmechanism[j].journalofpolymerscienceparta:polymerchemistry,1992,30（12）:2631-2644.
|
| [12] | schoonbroodhas,asuajm.reactivesurfactantsinheterophasepolymerization.9.optimumsurfmerbehaviorinemulsionpolymerization[j].macromolecules,1997,30（20）:6034-6041.
|
| [13] | erkald,senkalbf,saraca.emulsionpolymerizationofstyreneandvinylacetatewithcationicsurfactant[c]macromolecularsymposia.wiley-vchverlag,2007,254（1）:141-145.
|
| [14] | 曹翠,乔卫红.一种丙烯酸酯型可聚合乳化剂的合成与应用[j].精细与专用化学品,2009,17（15）:22-25.
|
| [15] | hollandb.thethermaldegradationofpoly（vinylacetate）measuredbythermalanalysis-fouriertransforminfraredspectroscopy[j].polymer,2002,43（8）:2207-2211.
|
| [16] | wangzy,haneh,kew.effectofacrylicpolymerandnanocompositewithnano-sio2onthermaldegradationandfireresistanceofapp-dper-melcoating[j].polymerdegradationandstability,2006,91（9）:1937-1947.
|
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