全部 标题 作者
关键词 摘要

OALib Journal期刊
ISSN: 2333-9721
费用:99美元

查看量下载量

相关文章

更多...

Influence of Diisocyanate on Polyurethane Elastomers Which Crosslinked by β-Cyclodextrin

DOI: 10.4236/ojopm.2016.63010, PP. 99-111

Keywords: Cyclodextrin, Polyurethane Elastomer, Microphase Separation, Cross-Linker

Full-Text   Cite this paper   Add to My Lib

Abstract:

A series of polyurethane elastomers (PUEs) were synthesized by using β-cyclodextrin (β-CD) as cross-linker from aliphatic, alicyclic, aromatic diisocyanates, and polyol. The PUEs were characterized by Fourier Transform Infrared Spectroscopy (FTIR), Scanning Electron Microscopy (SEM), Differential Scanning Calorimetry (DSC), Dynamic Mechanical Analysis (DMA), swelling test, hardness test and tensile test. The influence of diisocyanate on microphase separation and properties of PUEs was evaluated.

References

[1]  Oertel, F. (1985) Polyurethane Handbook. Macmillan Publishing Co., New York.
[2]  Szycher, M. (1999) Szycher’s Handbook of Polyurethanes. CRC Press, Boca Raton, Florida.
[3]  Randall, D. and Lee, S. (2003) The Polyurethanes Book.
[4]  Prisacariu, C. (2011) Polyurethane Elastomers. From Morphology to Mechanical Aspects. Springer Vienna.
http://dx.doi.org/10.1007/978-3-7091-0514-6
[5]  Gao, N., Zhang, Z. and Dong, Q.Z. (2013) Preparation and Properties of Two-Component and Double-Crosslinking Waterborne Polyurethane-Acrylic Dispersions. Open Journal of Organic Polymer Materials, 3, 27-33.
http://dx.doi.org/10.4236/ojopm.2013.32005
[6]  Lan, Z.Y., Daga, R., Whitehouse, R., McCarthy, S. and Schmidt, D. (2014) Structure-Properties Relations in Flexible Polyurethane Foams Containing a Novel Bio-Based Crosslinker. Polymer, 55, 2635-2644.
http://dx.doi.org/10.1016/j.polymer.2014.03.061
[7]  Jena, K.K. and Raju, K.V.S.N. (2008) Synthesis and Characterization of Hyperbranched Polyurethane Hybrids Using Tetraethoxysilane (TEOS) As Cross-Linker. Industrial & Engineering Chemistry Research, 47, 9214-9224.
http://dx.doi.org/10.1021/ie800884y
[8]  Oprea, S. (2010) Synthesis and Properties of Polyurethane Elastomers with Castor Oil as Crosslinker. Journal of the American Oil Chemists’ Society, 87, 313-320.
http://dx.doi.org/10.1007/s11746-009-1501-5
[9]  Schmidta, B.V.K.J., Hetzerc, M., Ritterc, H. and Barner-Kowollik, C. (2014) Complex Macromolecular Architecture Design via Cyclodextrin Host/Guest Complexes. Progress in Polymer Science, 39, 235-249.
http://dx.doi.org/10.1016/j.progpolymsci.2013.09.006
[10]  Karoyo, A.H., Borisov, A.S., Wilson, L.D. and Hazendonk, P. (2011) Formation of Host-Guest Complexes of β-Cyclodextrin and Perfluorooctanoic Acid. The Journal of Physical Chemistry B, 115, 9511-9527.
http://dx.doi.org/10.1021/jp110806k
[11]  Wickstrom, L., He, P., Gallicchio, E. and Levy, R.M. (2013) Large Scale Affinity Calculations of Cyclodextrin Host-Guest Complexes: Understanding the Role of Reorganization in the Molecular Recognition Process. Journal of Chemical Theory and Computation, 9, 3136-3150.
http://dx.doi.org/10.1021/ct400003r
[12]  Bortolus, P., Grabner, G., Kohler, G. and Monti, S. (1993) Photochemistry of Cyclodextrin Host-Guest Complexes. Coordination Chemistry Reviews, 125, 261-268.
http://dx.doi.org/10.1016/0010-8545(93)85023-W
[13]  Salipira, K.L., Krause, R.W., Mamba, B.B., Malefetse, T.J., Cele, L.M. and Durbach, S.H. (2008) Cyclodextrin Polyurethanes Polymerized with Multi-Walled Carbon Nanotubes: Synthesis and Characterization. Materials Chemistry and Physics, 111, 218-224.
http://dx.doi.org/10.1016/j.matchemphys.2008.03.026
[14]  Young, S.K., Vajda, P.L., Napadensky, E., Crawford, D.M., Sloan, J.M. and Trevino, S.F. (2002) Structure-Scavenging Abilities of Cyclodextrin-Based Polyurethanes. Army Research Laboratory, ARL-TR-2776.
[15]  Biswas, A., Appell, M., Liu, Z. and Cheng, H.N. (2015) Microwave-Assisted Synthesis of Cyclodextrin Polyurethanes. Carbohydrate Polymers, 133, 74-79.
http://dx.doi.org/10.1016/j.carbpol.2015.06.044
[16]  Kiasat, A.R. and Nazaria, S. (2012) β-Cyclodextrin Based Polyurethane as Eco-Friendly Polymeric Phase Transfer Catalyst in Nucleophilic Substitution Reactions of Benzyl Halides in Water: An Efficient Route to Synthesis of Benzyl Thiocyanates and Acetates. Catalysis Science & Technology, 5, 1056-1058.
http://dx.doi.org/10.1039/c2cy00375a
[17]  Pu, X., Dudal, Y., Corvini, P.F.X., Pieles, U. and Shahgaldian, P. (2013) Cyclodextrin-Based Polyurethanes Act as Selective Molecular Recognition Materials of Active Pharmaceutical Ingredients (APIs). Polymer Chemistry, 2, 1264-1266.
[18]  Abouzahr, S. and Wilkes, G.L. (2012) Structure-Property Behaviour of Segmented Polyether-MDI-Butanediol Based Urethanes: Effect of Composition ratio. Polymer, 23, 1077-1086.
http://dx.doi.org/10.1016/0032-3861(82)90411-6
[19]  Yilgor, I. and Yilgor, E. (2007) Structure-Morphology-Property Behavior of Segmented Thermoplastic Polyurethanes and Polyureas Prepared without Chain Extenders. Polymer Reviews, 47, 487-510.
http://dx.doi.org/10.1080/15583720701638260
[20]  Versteegen, R.M., Kleppinger, R., Sijbesma, R.P. and Meijer, E.J. (2005) Properties and Morphology of Segmented Copoly(Ether Urea)s with Uniform Hard Segments. Macromolecules, 38, 3176-3184.
http://dx.doi.org/10.1021/ma0478207

Full-Text

comments powered by Disqus

Contact Us

service@oalib.com

QQ:3279437679

WhatsApp +8615387084133