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Factor Affecting Gel Time/Process-Ability of Urea Formaldehyde Resin Based Wood Adhesives

DOI: 10.4236/ojpchem.2017.72003, PP. 33-42

Keywords: Urea Formaldehyde Resins, Catalysts, Gel Time, Wood, pH, Polyvinyl Acetate, Composite

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Abstract:

Urea-formaldehyde (UF) resin presents the most utilized adhesive system in the manufacture of plywood, particleboard and fiberboard. At the temperatures above 100°C in the presence of hardener, this resin undergoes cross-linking reaction and the formation of three dimensional cross linked structures takes place and bonding of wood particles in a hot press [1]. UF powder resins show high reactivity and good performance in the production and by their low price; however they lack in water resistance of the hardened resin [2]. Urea-formaldehyde (UF) resins are the most important type of adhesive resins for the production of wood based panels but process-ability and curing behavior of urea formaldehyde resin depended on various factors related to resin properties, types of wood and their properties, amount & type of catalyst, types and amount of polymers addition and environmental conditions [3]. This factor decides the process-ability of UF resin based composite during manufacturing of plywood, particle board and fiberboard. In this review paper, various factors affecting gel time and process-ability of UF resin based wood composite are reviewed.

References

[1]  Gao, Z., Wang, X.M., Wan, H. and Liu, Y. (2007) Curing Characteristics of Urea-Formaldehyde Resin in the Presence of Various Amounts of Wood Extracts and Catalyst. Journal of Applied Polymer Science, 107, 1555-1562.
https://doi.org/10.1002/app.27205
[2]  Dunky, M. (1998) Urea-Formaldehyde (UF) Adhesive Resins for Wood. International Journal of Adhesion and Adhesives, 18, 95-107.
[3]  Xing, C., Zhang, S.Y., Deng, J. and Wang, S. (2006) Urea-Formaldehyde-Resin Gel Time as Affected by the pH Value, Solid Content, and Catalyst. Journal of Applied Polymer Science, 103, 1566-1569.
https://doi.org/10.1002/app.25343
[4]  Whitfield, R.M., Brown, F.C. and Low, R. (2007) Socio-Economic Benefits of Formaldehyde to the European Union (EU25) and Norway. Global Insight, Lexington.
[5]  Conner, A.H. (1996) Urea-Formaldehyde Adhesive Resins. Polymeric Materials Encyclopedia, 128, 8496-8501.
[6]  Hse, C.Y., Xia, Z.Y. and Tomita, B. (1994) Effects of Reaction pH on Properties and Performance of Urea-Formaldehyde Resins. Holzforschung, 48, 527-532.
https://doi.org/10.1515/hfsg.1994.48.6.527
[7]  Stuligross, J. and Koutsky, J.A. (1985) A Morphological Study of Urea-Formalde-hyde Resins. Journal of Adhesion, 18, 281-299.
https://doi.org/10.1080/00218468508080464
[8]  Xing, C., Riedl, B., Cloutier, A. and Shaler, S.M. (2005) Characterization of Urea-Formaldehyde Resin Penetration into Medium Density Fiberboard Fibers. Wood Science and Technology, 39, 374-384.
https://doi.org/10.1007/s00226-005-0294-4
[9]  Myers, G.E. (1981) Investigation of Urea-Formaldehyde Polymer Cure by Infrared. Journal of Applied Polymer Science, 26, 747-764.
https://doi.org/10.1002/app.1981.070260301
[10]  Troughton, G.E. (1969) Accelerated Aging of Glue-Wood Bonds. Journal of Wood Science, 1, 172-176.
[11]  Myers, G.E. (1982) Hydrolytic Stability of Cured Urea-Formaldehyde Resins. Journal of Wood Science, 15, 127-138.
[12]  Albritton, R.O. and Short, P.H. (1979) Effects of Extractives from Pressure-Refined Hardwood Fiber on the Gel Time of Urea-Formaldehyde Resin. Forest Products Journal, 29, 40-41.
[13]  Guo, A.L., Zhang, H.S., Feng, L.Q., Gao, X.X. and Zhang, G.L. (1998) pH Value and Buffering Capacity of 6 Shrub Species and Relevant Effect on Curing Time of UF Resin. China Wood Industry, 12, 18-20.
[14]  Johns, W.E. and Niazi, K.A. (1980) Effect of pH and Buffering Capacity of Wood on the Gelation Time of Urea-Formaldehyde Resin. Wood and Fiber Science, 12, 255-263.
[15]  Park, B.D., Kim, Y.S. and Riedl, B. (2001) Effect of Wood-Fiber Characteristics on Medium Density Fiberboard (MDF) Performance. Journal of the Korean Wood Science and Technology, 29, 27-35.
[16]  Peng, H.Y. and Li, J. (1983) Effect of pH and the Buffering Capacity of Economic Wood Species Growing in Northeast on the Gel Time of Urea-Formaldehyde Resin. J. North East for Ins China, 11, 100-105.
[17]  Sithole, B. (2005) New Method of Measuring the pH of Wood Chips. 59th APPITA Annual Conference and Exhibition: Incorporating the 13th ISWFPC, Auckland, 16-19 May 2005, 391-396.
[18]  Xing, C., Riedl, B. and Cloutier, A. (2004) Measurement of Urea-Formaldehyde Resin Distribution as a Function of MDF Fiber Size by Laser Scanning Microscopy. Wood Science and Technology, 37, 495-507.
https://doi.org/10.1007/s00226-003-0195-3
[19]  Slay, J.R., Short, P.H. and Wright, D.C. (1980) Catalytic Effect of Extractives from Pressure-Refined Hardwood Fiber on the Gel Time of Urea—Formaldehyde Resin. Forest Products Journal, 30, 22-23.
[20]  Pizzi, A., Mtsweni, B. and Parsons, W.J. (1994) Wood-Induced Catalystic Activation of PF Adhesives Auto Polymerization vs. PF/Wood Covalent Bonding. Journal of Applied Polymer Science, 52, 1847-1856.
https://doi.org/10.1002/app.1994.070521302
[21]  Xing, C., Deng, J., Zhang, S.Y., Riedl, B. and Cloutier, A. (2005) DSC Characterization of UF Resin Curing Behavior as Affected by Less Desirable Wood Material and Catalyst Content. Journal of Applied Polymer Science, 98, 2027-2032.
https://doi.org/10.1002/app.22118
[22]  Mao, A., Hassan, E.B. and Kim, M.G. (2013) Investigation of Low Mole Ratio UF and UMF Resins Aimed at Lowering the Formaldehyde Emission Potential of Wood Composite Boards. Bioresources, 8, 2453-2469.
https://doi.org/10.15376/biores.8.2.2453-2469
[23]  Balaban, M. and Ucar, G. (2001) The Correlation of Wood Acidity to Its Solubility by Hot Water and Alkali. Holz als Roh-und Werkstoff, 59, 67-70.
https://doi.org/10.1007/s001070050476
[24]  Gu, J.Y., Wei, S.Y. and Zhu, L.B. (2004) Study on Curing Agents Systems of Urea-Formaldehyde Resin. China Adhesives, 13, 4-8.
[25]  Poblete, H.W. and Pinto, A.S. (1993) Advances on the Effect of the Catalyst in the Curing of Urea Formaldehyde in Tepa Boards. Forest v., 14, 55-61.
[26]  Myers, G.E. (1990) Formaldehyde Liberation and Cure Behavior of Urea-Formal-dehyde Resins. Holzforschung, 44, 117-126.
https://doi.org/10.1515/hfsg.1990.44.2.117
[27]  Park, B.D. and Causin, V. (2013) Crystallinity and Domain Size of Cured Urea-Formaldehyde Resin Adhesives with Different Formaldehyde/Urea Mole Ratios. European Polymer Journal, 49, 532-537.
[28]  Lee, T.W., Roffael, E., Dix, B. and Mitertzsch, H. (1994) Influence of Different Catalyst Systems on the Hydrolytic Stability of Particleboards Bonded with Unmodified and Modified UF-Resins. Holzforschung, 48, 101-106.
https://doi.org/10.1515/hfsg.1994.48.s1.101
[29]  Hse, C.Y., Fu, F. and Pan, H. (2008) Melamine-Modified Urea Formaldehyde Resin for Bonding Particleboards. Forest Products Journal, 58, 56-61.
[30]  Robitschek, P. and Christensen, R.L. (1976) Degradation Phenomena in Urea Formaldehyde Resin-Bonded Particleboard. Forest Products Journal, 12, 43-46.
[31]  Xing, C., Deng, J., Zhang, S.Y., Riedl, B. and Cloutier, A. (2005) Differential Scanning Calorimetry Characterization of Urea Formaldehyde Resin Curing Behavior as Affected by Less Desirable Wood Material and Catalyst Content. Journal of Applied Polymer Science, 98, 2027-2032.
https://doi.org/10.1002/app.22118
[32]  Dimas, B.J., Osemeahon, S.A., Maitera, O.N. and Hotton, A.J. (2013) Influence of Starch Addition on Properties of Urea Formaldehyde/Starch Copolymer Blends for Application as a Binder in the Coating Industry. Journal of Environmental Chemistry and Ecotoxicology, 5, 181-189.
[33]  Xu, Z., Hua, S. and Tu, Y. (2013) Esterified-Starch Modified Urea Formaldehyde Adhesive. CN 102898987 A 12, Jan 30, 2013.
[34]  Liu, R. (2013) Modified Urea-Formaldehyde Resin. CN 103360559 A 13, Oct 23, 2013.
[35]  Zhu, L. (2014) Preparation Method for High-Strength Water-Resistant Starch Adhesive for Corrugated Paperboards. CN 104119816 A 14, 29 Oct, 2014.
[36]  Ni, K. (2014) Oxidized Starch Modified Urea-Formaldehyde Resin Adhesive. CN 103911103 A 15, 09 July 2014.
[37]  Chen, Y. (2014) Method for Producing Urea-Formaldehyde Resin Adhesive. CN 104178070 A 16, 03 Dec., 2014.
[38]  Li, J., Shen, K., Cai, J., Lai, Q. and Zheng, X. (2010) Environmentally-Friendly Starch Adhesive. CN 101735741 A 17, 16 Jun 2010.
[39]  Park, B.D., Kang, E.C. and Park, J.Y. (2006) Effects of Formaldehyde to Urea Mole Ratio on Thermal Curing Behavior of Urea-Formaldehyde Resin and Properties of Particleboard. Journal of Applied Polymer Science 101,1787-1792.
https://doi.org/10.1002/app.23538
[40]  Yu, S. and Zhang, H. (2008) Starch Adhesive for Producing Highly Intensified Water-Proof Corrugated Paper. CN 101134881 A, 5 Mar 2008.
[41]  Liu, Y., Zhang, Y. and Li, Q. (2014) Environmental Moisture MDF with Urea-Formaldehyde Resin Adhesive and Composite Additives and Production Methods. CN 102408855 B, 18 Jun, 2014.
[42]  Lv, Z., Duan, X.L., Xu, S., Deng, Z., Zhou, Y. and Jiang, Z. (2014) Manufacturing Method of Low-Formaldehyde-Release-Amount Plywood. CN 103484046 B, 31 Dec., 2014.
[43]  Wieland, S., Pizzi, A., Grigsby, W., Warnes, J. and Pichelin, F. (2007) Microcrystallinity and Colloidal Peculiarities of UF/Isocyanate Hybrid Resins. Journal of Applied Polymer Science, 104, 2633-2636.
https://doi.org/10.1002/app.24757
[44]  Gu, J.Y., Zuo, Y.F., Zhang, Y., Tan, H.Y., Zhu, L.B. and Shen, J. (2010) Preparation of Plywood Using Starch Adhesives Modified with Isocyanate. Applied Mechanics and Materials, 26, 1065-1068.
https://doi.org/10.4028/www.scientific.net/AMM.26-28.1065
[45]  Li, L.H., Liu, G.J. and Zhang, G.X. (2008) The Latest Progress in Study on Starch-Based Adhesives. Chemistry and Adhesive, 30, 50-53.
[46]  Liu, Y.H., Ruan, R.S. and Zhang, J.S. (2005) Research Situation of Starch Based Wood Adhesives. Chemistry and Adhesive, 27, 358-361.
[47]  Zhang, Y.H., Gu, J.Y. and Tan, H.Y. (2009) Preparation of the Plywood Using UF Resin Modified with Blocked Isocyanates as Bonding Agent. China Forest Products Industy, 36, 17-19.
[48]  Huang, Y.B. and Huo, Q.Y. (2006) The Application of Isocyanates Adhesive in Timber Industry. Journal of Heilongjiang Ecological Engineering Vocational College, No. 6, 34-35.
[49]  Qiao, Z., Gu, J., Lv, S., Cao, J., Tan, H. and Zhang, V. (2015) Preparation and Properties of Isocyanate Prepolymer/Corn Starch Adhesive. Journal of Adhesion Science and Technology, 29.
[50]  Shi, J. (2007) Starch Based Wood Adhesive API and Curing and Aging Mechanism. Journal of Northeast Forestry University, 90-123.
[51]  Shi, J.Y. and Tang, Y.Y. (2010) Study on the Rice Straw Particleboard by Starch-Based API Adhesive. Advanced Materials Research, 113, 1017-1020.
https://doi.org/10.4028/www.scientific.net/AMR.113-116.1017
[52]  Du, S. and Zhang, C. (2003) Study on Modified Starch of Non-Formaldehyde Adhesive. Journal of Chinese Adhesive, 10, 11-13.
[53]  Imam, S.H., Mao, L.J., Chen, L. and Greene, R.V. (1999) Wood Adhesive from Crosslinked Poly (Vinyl Alcohol) and Partially Gelatinized Starch: Preparation and Properties. Starch-Starke, 51, 225-229.
https://doi.org/10.1002/(SICI)1521-379X(199906)51:6<225::AID-STAR225>3.0.CO;2-F
[54]  Mizumachi, H. (1973) Activation Energy of the Curing Reaction of Urea Resin in the Presence of Wood. Wood Science and Technology, 6, 14-18.
[55]  Yang, I., Kuo, M. and Myers, D. (2006) Bond Quality of Soy-Based Phenolic Adhesives in Southern Pine Plywood. JAOCS, 83, 231-237.
https://doi.org/10.1007/s11746-006-1198-7
[56]  Papadopoulos, A.N., Hill, C.A.S., Traboulay, E. and Hague, J.R.B. (2002) Isocyanate Resins for Particleboard: PMDI vs. EMDI. Holz als Roh-und Werkstoff, 81-83.
https://doi.org/10.1007/s00107-001-0275-8
[57]  Ballerini, A., Despres, A. and Pizzi, A. (2005) Non-Toxic, Zero Emission Tannin-Glyoxal Adhesives for Wood Panels. Holz als Roh-und Werkstoff, 477-478.
https://doi.org/10.1007/s00107-005-0048-x

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