The
science that underpins our knowledge and understanding of Isotope-Based Hydrograph separation (IHS) has
gained grounds, over the last few decades, in the identification of streamflow
sources. However, challenges still exist in identifying appropriate tracers and
the right combination of end-members for the IHS process. In a two-component IHS analysis, the application of the dual isotopes tracers, δ18O and (or) δ2H,
is regarded as the simplest method. We
undertook an IHS study within a nested system of eight Prairie watersheds
located in South central Manitoba, Canada. The work evaluated about 17,000
results emanating from the application of a combination of two potential
tracers (δ18O and δ2H)
and eight each of potential “old” and “new” water end-members in a
two-component IHS process. The outcome showed occurrences of many
mathematically possible but hydrologically unacceptable IHS results. The
observation was particularly predominant within relatively larger perennial
sub-catchments of the watershed. It is also shown that inter-site sub-catchment
isotopic end-member transferability is possible within watersheds of similar
physio-hydrographic characteristics. We suggest that a careful evaluation of
the physio-hydrographic characteristics of catchments be considered in IHS
studies in addition to the recommended guidelines in the selection of tracers
and end-members.
References
[1]
Mohamoud, Y.M. (2008) Prediction of Daily Flow Duration Curves and Streamflow for Ungauged Catchments Using Regional Flow Duration Curves. Hydrological Sciences Journal, 53, 706-724. https://doi.org/10.1623/hysj.53.4.706
[2]
Kneis, D., Burger, G. and Bronstert, A. (2012) Evaluation of Medium-Range Runoff Forecasts for a 50 km2 Watershed. Journal of Hydrology, 415, 341-353.
https://doi.org/10.1016/j.jhydrol.2011.11.005
[3]
Day, C.A. (2009) Modelling Impacts of Climate Change on Snowmelt Runoff Generation and Streamflow across Western U.S. Mountain Basins: A Review of Techniques and Applications for Water Resource Management. Progress in Physical Geography, 33, 614-633. https://doi.org/10.1177/0309133309343131
[4]
Ye, S., Yaeger, M., Coopersmith, E., Cheng, L. and Sivapalan, M. (2012) Exploring the Physical Controls of Regional Patterns of Flow Duration Curves Part 2: Role of Seasonality, the Regime Curve, and Associated Process Controls. Hydrology and Earth System Sciences, 16, 4447-4465. https://doi.org/10.5194/hess-16-4447-2012
[5]
Hugenschmidt, C., Ingwersen, J., Sangchan, W., Sukvanachaikul, Y., Duffner A., Uhlenbrook, S. and Streck, T. (2014) A Three-Component Hydrograph Separation Based on Geochemical Tracers in a Tropical Mountainous Headwater Catchment in Northern Thailand. Hydrology and Earth System Sciences, 18, 525-537.
https://doi.org/10.5194/hess-18-525-2014
[6]
Sklash, M.G. and Farvolden, R.N. (1979) Role of Groundwater in Storm Runoff. Journal of Hydrology, 43, 45-65. https://doi.org/10.1016/0022-1694(79)90164-1
[7]
Buttle, J.M. (2005) Isotope Hydrograph Separation of Runoff Sources. In: Anderson, M.G., Ed., Encyclopedia of Hydrological Sciences, John Wiley & Sons Ltd., Chichester, 10, 116.
[8]
Buttle, J.M. (1994) Isotope Hydrograph Separations and Rapid Delivery of Preevent water from Drainage Basins. Progress in Physical Geography, 18, 16-41.
https://doi.org/10.1177/030913339401800102
[9]
Bansah, S. and Ali, G. (2017) Evaluating the Effects of Tracer Choice and End-Member Definitions on Hydrograph Separation Results across Nested Seasonally Cold Watersheds. Water Resources Research, 53, 8851-8871.
https://doi.org/10.1002/2016WR020252
[10]
Tiessen, K.H.D., Elliott, J.A., Yarotski, J., Lobb, D.A., Flaten, D.N. and Glozier, N.E. (2010) Conventional and Conservation Tillage: Influence on Seasonal Runoff, Sediment, and Nutrient Losses in the Canadian Prairies. Journal of Environmental Quality, 39, 964-980. https://doi.org/10.2134/jeq2009.0219
[11]
Bamburak, J.D. and Christopher, J.E. (2004) Mesozoic Stratigraphy of the Manitoba Escarpment. WCSB/TGI II, Fieldtrip Guidebook, 87 p.
[12]
Pinder, G.F. and Jones, J.F. (1969) Determination of Ground-Water Component of Peak Discharge from Chemistry of Total Runoff. Water Resources Research, 5, 438-445. https://doi.org/10.1029/WR005i002p00438
[13]
Hooper, P.R. and Shoemaker, C.A. (1986) A Comparison of Chemical and Isotopic Hydrograph Separation. Water Resources Research, 22, 1444-1454.
https://doi.org/10.1029/WR022i010p01444
[14]
Metcalfe, R.A. and Buttle, J.M. (2001) Soil Partitioning and Surface Store Controls on Spring Runoff from a Boreal Forest Peatland Basin in North-Central Manitoba, Canada. Hydrological Processes, 15, 2305-2324. https://doi.org/10.1002/hyp.262
[15]
Liu, Y.H., Fan, N.J., An, S.Q., Bai, X.H., Liu, F.D., Xu, Z., Wang, Z.S. and Liu, S.R. (2008) Characteristics of Water Isotopes and Hydrograph Separation during the Wet Season in the Heishui River, China. Journal of Hydrology, 353, 314-321.
https://doi.org/10.1016/j.jhydrol.2008.02.017
[16]
Fang, X., Minke, A., Pomeroy, J., Brown, T., Westbrook, C., Guo, X. and Guangul, S. (2007) A Review of Canadian Prairie Hydrology: Principles, Modelling and Response to Land Use and Drainage Change (Vol. 2). Centre for Hydrology, Saskatoon.
[17]
Genereux, D. (1998) Quantifying Uncertainty in Tracer-Based Hydrograph Separations. Water Resources Research, 34, 915-919. https://doi.org/10.1029/98WR00010
[18]
Craig, H. (1961) Standard for Reporting Concentrations of Deuterium and Oxygen-18 in Natural Waters. Science, 133, 1833-1841.
https://doi.org/10.1126/science.133.3467.1833