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Recycling and Disposal Methods for Polyurethane Wastes: A Review

DOI: 10.4236/ojpchem.2019.92004, PP. 39-51

Keywords: Recycling, Polyurethane, Foam, Sustainability, Waste Management

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Abstract:

Polyurethanes (PU) are a general class of polymers prepared by the polyaddition of isocyanates and hydroxyl group containing compounds. PU foams are formed via the reaction of poly-isocyanate and multi-functional hydroxyl compounds resulting in urethane linkages. The foams are formed in wide range of densities and maybe flexible, semi-flexible or rigid in structure. To control the foam structure, blowing agents are employed. These agents are introduced during foam formation through volatilization of low-boiling liquids or through the formation of gas due to chemical reaction. Additionally, surfactants, catalysts, etc. are used during the manufacturing of foams. PU, including PU foams, is one of the most important groups of materials today and hence, their recycling has been of great interest. Many methods of recycling PU are available and many more are being studied further. However, no method has seen large scale commercialization or is brought into regular practice. The objective of this review is to bring to light the various technologies available and their current status of development as well as newer upcoming methods that may be available in the future.

References

[1]  PlasticsEurope (2016) Plastics—The Facts 2016: An Analysis of European Plastics Production, Demand and Waste Data. Brussels, Belgium.
[2]  Agrawal, A., Kaur, R. and Walia, R.S. (2017) PU Foam Derived from Renewable Sources: Perspective on Properties Enhancement: An Overview. European Polymer Journal, 95, 255-274.
https://doi.org/10.1016/j.eurpolymj.2017.08.022
[3]  Brains, P.F. (1969) Polyurethanes Technology. John Wiley & Sons, Hoboken, NJ.
[4]  Hepburn, C. (1992) Polyurethane Elastomers. Elsevier Science, Barking, Essex.
https://doi.org/10.1007/978-94-011-2924-4
[5]  Zia, K.M., Bhatti, H.N. and Bhatti, I.A. (2007) Methods for Polyurethane and Polyurethane Composites, Recycling and Recovery: A Review. Reactive and Functional Polymers, 67, 675-692.
https://doi.org/10.1016/j.reactfunctpolym.2007.05.004
[6]  Yanga, W., Dongb, Q., Liu, S., Xie, H., Liu, L. and Li, J. (2012) Recycling and Disposal Methods for Polyurethane Foam Wastes. Procedia Environmental Sciences, 16, 167-175.
https://doi.org/10.1016/j.proenv.2012.10.023
[7]  Cregut, M., Bedas, M., Durand, M.-J. and Thouand, G. (2013) New Insights into Polyurethane Biodegradation and Realistic Prospects for the Development of a Sustainable Waste Recycling Process. Biotechnology Advances, 31, 1634-1647.
https://doi.org/10.1016/j.biotechadv.2013.08.011
[8]  Howard, G.T., Norton, W.N. and Burks, T. (2012) Growth of Acinetobacter generic P7 on Polyurethane and the Purification and Characterization of a Polyurethanase Enzyme. Biodegradation, 23, 561-573.
https://doi.org/10.1007/s10532-011-9533-6
[9]  Chevali, V. and Kandare, E. (2016) Rigid Biofoam Composites as Eco-Efficient Construction Materials. In: Pacheco-Torgal, F., Ivanov, V., Karak, N. and Jonkers, H., Eds., Biopolymers and Biotech Admixtures for Eco-Efficient Construction Materials, Woodhead Publishing Limited, Cambridge.
https://doi.org/10.1016/B978-0-08-100214-8.00013-0
[10]  Oprea, S. (2010) Synthesis and Properties of Polyurethane Elastomers with Castor Oil as Crosslinker. Journal of the American Oil Chemists’ Society, 87, 313-320.
https://doi.org/10.1007/s11746-009-1501-5
[11]  Molero, C., de Lucas, A., Romero, F. and Rodríguez, J.F. (2008) Influence of the Use of Recycled Polyols Obtained by Glycolysis on the Preparation and Physical Properties of Flexible Polyurethane. Journal of Applied Polymer Science, 109, 617-626.
https://doi.org/10.1002/app.28136
[12]  Molero, C., Mitova, V., Troev, K. and Rodríguez, J.F. (2010) Kinetics and Mechanism of the Chemical Degradation of Flexible Polyurethane Foam Wastes with Dimethyl H-Phosphonate with Different Catalysts. Journal of Macromolecular Science, Part A: Pure and Applied Chemistry, 47, 983-990.
https://doi.org/10.1080/10601325.2010.506408
[13]  Gutiérrez-González, S., Gadea, J., Rodríguez, A., Junco, C. and Calderón, V. (2012) Lightweight Plaster Materials with Enhanced Thermal Properties Made with Polyurethane Foam Wastes. Construction and Building Materials, 28, 653-658.
https://doi.org/10.1016/j.conbuildmat.2011.10.055
[14]  Alameda, L., Calderón, V., Junco, C., Rodríguez, A., Gadea, J. and Gutiérrez-González, S. (2016) Characterization of Gypsum Plasterboard with Polyurethane Foam Waste Reinforced with Polypropylene Fibers. Materiales de Construcción, 66, 100.
https://doi.org/10.3989/mc.2016.06015
[15]  Junco, C., Gadea, J., Rodríguez, A., Gutiérrez-González, S. and Calderón, V. (2012) Durability of Lightweight Masonry Mortars Made with White Recycled Polyurethane Foam. Cement and Concrete Composites, 34, 1174-1179.
https://doi.org/10.1016/j.cemconcomp.2012.07.006
[16]  Poulikakos, L.D., Papadaskalopoulou, C., Hofko, B., Gschosser, F., Cannone Falchetto, A., Bueno, M., et al. (2017) Harvesting the Unexplored Potential of European Waste Materials for Road Construction. Resources, Conservation and Recycling, 116, 32-44.
https://doi.org/10.1016/j.resconrec.2016.09.008
[17]  Huang, Y., Bird, R.N. and Heidrich, O. (2007) A Review of the Use of Recycled Solid Waste Materials in Asphalt Pavements. Resources, Conservation and Recycling, 52, 58-73.
https://doi.org/10.1016/j.resconrec.2007.02.002
[18]  Yildirim, Y. (2007) Polymer Modified Asphalt Binders. Construction and Building Materials, 21, 66-72.
https://doi.org/10.1016/j.conbuildmat.2005.07.007
[19]  Bukowski, A. and Gretkiewicz, J. (1982) Polyurethane Synthesis Reactions in Asphalts. Journal of Applied Polymer Science, 27, 1197-1204.
https://doi.org/10.1002/app.1982.070270409
[20]  Carrera, V., Cuadri, A.A., García-Morales, M. and Partal, P. (2014) Influence of the Prepolymer Weight and Free Isocyanate Content on the Rheology of Polyurethane Modified Bitumens. European Polymer Journal, 57, 151-159.
https://doi.org/10.1016/j.eurpolymj.2014.05.013
[21]  Izquierdo, M.A., Navarro, F.J., Martínez-Boza, F.J. and Gallegos, C. (2012) Bituminous Polyurethane Foams for Building Applications: Influence of Bitumen Hardness. Construction and Building Materials, 30, 706-713.
https://doi.org/10.1016/j.conbuildmat.2011.12.088
[22]  Ghosh, B., Gogoi, S., Thakur, S. and Karak, N. (2016) Biobased Waterborne Polyurethane/Carbon Dot Nanocomposite as a Surface Coating Material. Progress in Organic Coatings, 90, 324-330.
https://doi.org/10.1016/j.porgcoat.2015.10.025
[23]  Howard, G.T. (2002) Biodegredation of Polyurethane: A Review. International Biodeterioration & Biodegradation, 49, 245-252.
https://doi.org/10.1016/S0964-8305(02)00051-3
[24]  Zia, K.M., Bhatti, H.N. and Bhatti, J.A. (2007) Methods for Polyurethane and Polyurethane Composites, Recycling and Recovery: A Review. Reactive and Functional Polymers, 67, 675-692.
https://doi.org/10.1016/j.reactfunctpolym.2007.05.004
[25]  Yang, W., Dong, Q., et al. (2012) Recycling and Disposal Methods for Polyurethane Foam Wastes. Procedia Environmental Sciences, 16, 167-175.
https://doi.org/10.1016/j.proenv.2012.10.023
[26]  Campbell, G.A. and Meluch, W.C. (1977) Polyurethane Waste Disposal Development: Amine Recovery. Journal of Applied Polymer Science, 21, 581-584.
https://doi.org/10.1002/app.1977.070210224
[27]  Scheirs, J. (1998) Polymer Recycling. Wiley, New York.
[28]  Braslaw, J. and Gerlock, J.L. (1984) Polyurethane Waste Recycling. 2. Polyol Recovery and Purification. Industrial & Engineering Chemistry Process Design and Development, 23, 552-557.
https://doi.org/10.1021/i200026a024
[29]  Zhu, P., Cao, Z.-B., Chen, Y., Zhang, X.-J., Qian, G.-R., Chu, Y.-L., et al. (2014) Glycolysis Recycling of Rigid Waste Polyurethane Foam from Refrigerators. Environmental Technology, 35, 2676-2684.
https://doi.org/10.1080/09593330.2014.918180
[30]  Gadhave, R., Srivastava, S., Mahanwar, P. and Gadekar, P. (2019) Lignin: Renewable Raw Material for Adhesive. Open Journal of Polymer Chemistry, 9, 27-38.
https://doi.org/10.4236/ojpchem.2019.92003
[31]  Gadhave, R., Mahanwar, P. and Gadekar, P. (2018) Lignin-Polyurethane Based Biodegradable Foam. Open Journal of Polymer Chemistry, 8, 1-10.
https://doi.org/10.4236/ojpchem.2018.81001
[32]  Ulrich, H., Odinak, A., Tucker, B. and Sayigh, A.A.R. (1978) Recycling of Polyurethane and Polyisocyanurate Foam. Polymer Engineering & Science, 18, 844-888.
https://doi.org/10.1002/pen.760181103
[33]  Nikje, M.M.A., Garmarudi, A.B. and Azni, B. (2011) Polyurethane Waste Reduction and Recycling: From Bench to Pilot Scales. Designed Monomers and Polymers, 14, 395-421.
https://doi.org/10.1163/138577211X587618
[34]  John, L., Gerlock, J.B. and Albright, J. (1982) Process for Polyol Recovery from Polyurethane Foam Comprising Alcohol and Steam Hydrolysis. US Patent No. 4316992.
[35]  Kondo, O., Hashimoto, T. and Hasegawa, H.U.S. (1993) Patent 4014809, 197722.
[36]  Benes, H., Hajek, M., Horak, Z. and Krulis, Z. (2010) Method of Recycling Waste Polyurethane Foams. US Patent No. EP2183311A2.
[37]  Asahi, N., Sakai, K., Kumagai, N., Nakanishi, T., Hata, K., Katoh, S. and Moriyoshi, T. (2004) Methanolysis Investigation of Commercially Available Polyurethane Foam. Polymer Degradation and Stability, 86, 147-151.
https://doi.org/10.1016/j.polymdegradstab.2004.04.002
[38]  Le Gac, P.Y., Choqueuse, D. and Melot, D. (2013) Description and Modeling of Polyurethane Hydrolysis Used as Thermal Insulation in Oil Offshore Conditions. Polymer Testing, 32, 1588-1593.
https://doi.org/10.1016/j.polymertesting.2013.10.009

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