The utilization of UV excitation to verify the terahertz (THz) wave modulation of hexagonal-shaped metamaterial (MM) arrays coated with synthesized photoluminescent, down-shifting ZnO quantum dots (QDs) of two different radius sizes, namely, 3.00 nm (pH 10) and 2.12 nm (pH 12), respectively is reported. In order to characterize the behavior of the MM before and after deployment of the ZnO QDs, THz time domain spectroscopy in transmission mode was employed. Upon exposure to UV excitation, the collected amplitude modulation values were 9.21% for the pH 12 and 4.55% for the pH 10 ZnO QDs, respectively. It is anticipated that the ability to actively tune the performance of otherwise passive structures will promote the proliferation of THz signal modulation devices in the near future.
References
[1]
Hashemi, M.R., Cakmakyapan, S. and Jarrahi, M. (2017) Reconfigurable Metamaterials for Terahertz Wave Manipulation. Reports on Progress in Physics, 80, Article ID: 094501. https://doi.org/10.1088/1361-6633/aa77cb
[2]
Davies, A.G., Burnett, A.D., Fan, W., Linfield, E.H. and Cunningham, J.E. (2008) Terahertz spectroscopy of Explosives and Drugs. Materials Today, 11, 18-26.
https://doi.org/10.1016/S1369-7021(08)70016-6
[3]
Baaske, K., Salhi, M., Rutz, F., Hasek, T., Wilk, R., Richter, H., et al. (2006) Mail Inspection Using THz Imaging: A Comparison of Three Different Systems. Terahertz for Military and Security Applications IV, 6212, 62120U.
https://doi.org/10.1117/12.665238
[4]
Hernandez-Serrano, A.I., Corzo-Garcia, S.C., Garcia-Sanchez, E., Alfaro, M. and Castro-Camus, E. (2014) Quality Control of Leather by Terahertz Time-Domain Spectroscopy. Applied Optics, 53, 7872-7876.
https://doi.org/10.1364/AO.53.007872
[5]
Gowen, A.A., O’Sullivan, C. and O’Donnell, C.P. (2012) Terahertz Time Domain Spectroscopy and Imaging: Emerging Techniques for Food Process Monitoring and Quality Control. Trends in Food Science & Technology, 25, 40-46.
https://doi.org/10.1016/j.tifs.2011.12.006
[6]
Russe, I.S., Brock, D., Knop, K., Kleinebudde, P. and Zeitler, J.A. (2012) Validation of Terahertz Coating Thickness Measurements Using X-Ray Microtomography. Molecular Pharmaceutics, 9, 3551-3559. https://doi.org/10.1021/mp300383y
[7]
Ho, L., Müller, R., Romer, M., Gordon, K.C., Heinamaki, J., Kleinebudde, P., et al. (2007) Analysis of Sustained-Release Tablet Film Coats Using Terahertz Pulsed Imaging. Journal of Controlled Release, 119, 253-261.
https://doi.org/10.1016/j.jconrel.2007.03.011
[8]
Woodward, R.M., Cole, B.E., Wallace, V.P., Pye, R.J., Arnone, D.D., Linfield, E.H., et al. (2002) Terahertz Pulse Imaging in Reflection Geometry of Human Skin Cancer and Skin Tissue. Physics in Medicine and Biology, 47, 3853-3863.
https://doi.org/10.1088/0031-9155/47/21/325
[9]
Park, S.J. and Ahn, Y.H. (2015) Terahertz Metamaterials Application in Sensing Bacteria and Fungi. 2015 40th International Conference on Infrared, Millimeter, and Terahertz Waves (IRMMW-THz), Hong Kong, 23-28 August 2015, 1.
https://doi.org/10.1109/IRMMW-THz.2015.7327619
[10]
Sim, Y.C., Park, J.Y., Ahn, K.-M., Park, C. and Son, J.-H. (2013) Terahertz Imaging of Excised Oral Cancer at Frozen Temperature. Biomedical Optics Express, 4, 1413-1421. https://doi.org/10.1364/BOE.4.001413
[11]
Tao, H., Padilla, W.J., Zhang, X. and Averitt, R.D. (2011) Recent Progress in Electromagnetic Metamaterial Devices for Terahertz Applications. IEEE Journal on Selected Topics in Quantum Electronics, 17, 92-101.
https://doi.org/10.1109/JSTQE.2010.2047847
Bingham, C.M., Tao, H., Liu, X., Averitt, R.D., Zhang, X. and Padilla, W.J. (2008) Planar Wallpaper Group Metamaterials for Novel Terahertz Applications. Optics Express, 16, 18565-18575. https://doi.org/10.1364/OE.16.018565
[14]
Suslick, K.S. and Price, G.J. (1999) Applications of Ultrasound to Materials Chemistry. Annual Review of Material Science, 29, 295-326.
https://doi.org/10.1146/annurev.matsci.29.1.295
[15]
Pandit, A.B. and Badnore, A.U. (2017) Effect of pH on Sonication Assisted Synthesis of ZnO Nanostructures: Process Details. Chemical Engineering and Processing: Process Intensification, 122, 235-244. https://doi.org/10.1016/j.cep.2017.09.013
[16]
Zazueta-Raynaud, A., Pelayo-Ceja, J.E., Lopez-Delgado, R. and Ayon, A. (2016) ZnO Photoluminescent Quantum Dots with Down-Shifting Effect Applied in Solar Cells. Journal of Physics: Conference Series, 773, Article ID: 012036.
https://doi.org/10.1088/1742-6596/773/1/012036
[17]
Caballero, A.C., Villegas, M., Moure, C. and Ferna, J.F. (2001) Controlled Precipitation Methods: Formation Mechanism of ZnO Nanoparticles. Journal of the European Ceramic Society, 21, 925-930. https://doi.org/10.1016/S0955-2219(00)00283-1
[18]
Alias, S.S., Ismail, A.B. and Mohamad, A.A. (2010) Effect of pH on ZnO Nanoparticle Properties Synthesized by Sol-Gel Centrifugation. Journal of Alloys and Compounds, 499, 231-237. https://doi.org/10.1016/j.jallcom.2010.03.174
[19]
Podzorov, A. and Gallot, G. (2010) Density of States and Vibrational Modes of PDMS Studied by Terahertz Time-Domain Spectroscopy. Chemical Physics Letters, 495, 46-49. https://doi.org/10.1016/j.cplett.2010.06.050
[20]
Alfihed, S., Bergen, M.H., Holzman, J.F. and Foulds, I.G. (2018) A Detailed Investigation on the Terahertz Absorption Characteristics of Polydimethylsiloxane (PDMS). Polymer, 153, 325-330. https://doi.org/10.1016/j.polymer.2018.08.025
[21]
Guzelian, A.A., Katari, J.E.B., Kadavanich, A. V., Banin, U., Hamad, K., Juban, E., et al. (1996) Synthesis of Size-Selected, Surface-Passivated InP Nanocrystals. The Journal of Physical Chemistry, 100, 7212-7219. https://doi.org/10.1021/jp953719f
[22]
Lin, K.F., Cheng, H.M., Hsu, H.C. and Hsieh, W.F. (2006) Bandgap Engineering and Spatial Confinement of Optical Phonon in ZnO Quantum Dots. 19th Annual Meeting of the IEEE Lasers and Electro-Optics Society, Montreal, 29 October-2 November 2006, 939-940. https://doi.org/10.1109/LEOS.2006.279156
[23]
Kar, S. and Chaudhuri, S. (2005) Synthesis and Optical Properties of Single and Bicrystalline ZnS Nanoribbons. Chemical Physics Letters, 414, 40-46.
https://doi.org/10.1016/j.cplett.2005.08.021
[24]
Brus, L. (1986) Electronic Wave Functions in Semiconductor Clusters: Experiment and Theory. The Journal of Physical Chemistry, 90, 2555-2560.
https://doi.org/10.1021/j100403a003
[25]
MenloSystems (2001) TeraSmart.
[26]
Withayachumnankul, W. and Naftaly, M. (2014) Fundamentals of Measurement in Terahertz Time-Domain Spectroscopy. Journal of Infrared, Millimeter, and Terahertz Waves, 35, 610-637. https://doi.org/10.1007/s10762-013-0042-z
[27]
Wang, F., Shan, J., Islam, M.A., Herman, I.P., Bonn, M. and Heinz, T.F. (2006) Exciton Polarizability in Semiconductor Nanocrystals. Nature Materials, 5, 861-864.
https://doi.org/10.1038/nmat1739
[28]
Zhao, X., Duan, G., Li, A., Chen, C. and Zhang, X. (2019) Integrating Microsystems with Metamaterials towards Metadevices. Microsystems and Nanoengineering, 5, 1-17. https://doi.org/10.1038/s41378-018-0042-1
[29]
Patra, M.K., Manoth, M., Singh, V.K., Siddaramana Gowd, G., Choudhry, V.S., Vadera, S.R., et al. (2009) Synthesis of Stable Dispersion of ZnO Quantum Dots in Aqueous Medium Showing Visible Emission from Bluish Green to Yellow. Journal of Luminescence, 129, 320-324. https://doi.org/10.1016/j.jlumin.2008.10.014