The microwave absorption properties of polymer
composite PANI/PVA/NiFe2O3are investigated. The polymer composites of PANI/PVA and NiFe2O3 are prepared in two steps. NiFe2O3 is synthesized by
modified sol gel method and PANI by chemical polymerization method. Microwave
absorption parameters of polymer composite are measured at X-band. The
microwave absorption is found to be -28 dB
(99%) at 10.2 GHz.Different characterization techniques such as
SEM-EDX, FTIR and XRD are done. The SEM result shows flakes like structure for
PANI/PVA and crystalline structure for NiFe2O3. FTIR of
the composite reveals the interaction between the PANI/PVA and NiFe2O3.
References
[1]
Hermann, D.M. and Hossmann, K.A.J. (1997) Neurological Effects of Microwave Exposure Related to Mobile Communication. Neurological Sciences, 152, 1-14. https://doi.org/10.1016/S0022-510X(97)00140-8
[2]
Tiwari, D. C., Jain, R. and Sharma, S. (2008) Spectroscopic and Thermogravimetric Analysis of PANI/PPy Composite Polymer Electrode: Its Application to Electrochemical Investigation of Pharmaceutical Formulation. Journal of Applied Polymer Science, 110, 2328-2336.
[3]
Ghanbari, D. and Niasari, M.S. (2015) Synthesis of Urchin-Like CdS-Fe3O4 Nanocomposite and Its Application in Flame Retardancy of Magnetic Cellulose Acetate. Journal of Industrial and Engineering Chemistry, 24, 284-292. https://doi.org/10.1016/j.jiec.2014.09.043
[4]
Ghanbari, D., Niasari, M.S. and Kooch, M.G. (2014) A Sonochemical Method for Synthesis of Fe3O4 Nanoparticles and Thermal Stable PVA-Based Magnetic Nanocomposite. Journal of Industrial and Engineering Chemistry, 20, 3970-3974. https://doi.org/10.1016/j.jiec.2013.12.098
[5]
Sobhani, A. and Niasari, M.S. (2015) Synthesis and Characterization of FeSe2 Nanoparticles and FeSe2/FeO(OH) Nanocomposites by Hydrothermal Method. Journal of Alloys and Compounds, 625, 26-33. https://doi.org/10.1016/j.jallcom.2014.11.079
[6]
Hashim, M., Alimudin, Kumar, S., Shirsath, S.E., Mohamade, E.D. and Chung, H. (2012) Studies on the Activation Energy from the AC Conductivity Measurements of Rubber Ferrite Composites Containing Manganese Zinc Ferrite. Physica B, 407, 4097-4103. https://doi.org/10.1016/j.physb.2012.06.006
[7]
Ajabshir, S.Z., Morassaei, M.S. and Niasar, M.S. (2019) Eco-Friendly Synthesis of Nd2Sn2O7-Based Nanostructure Materials Using Grape Juice as Green Fuel as Photocatalyst for the Degradation of Erythrosine. Composites Part B: Engineering, 167, 643-653. https://doi.org/10.1016/j.compositesb.2019.03.045
[8]
Ajabshir, S.Z. and Niasari, M.S. (2019) Preparation of Magnetically Retrievable CoFe2O4@SiO2@Dy2Ce2O7 Nanocomposites as Novel Photocatalyst for Highly Efficient Degradation of Organic Contaminants. Composites Part B: Engineering, 174, Article ID: 106930. https://doi.org/10.1016/j.compositesb.2019.106930
[9]
Abbasi, A., Ghanbari, D., Niasari, M.S. and Hamadanian, M. (2016) Photo-Degradation of Methylene Blue: Photocatalyst and Magnetic Investigation of Fe2O3-TiO2 Nanoparticles and Nanocomposites. Journal of Materials Science: Materials in Electronics, 27, 4800-4809. https://doi.org/10.1007/s10854-016-4361-4
[10]
Ajabshir, S.Z., Morassaei, M.S. and Niasari, M.S. (2019) Facile Synthesis of Nd2Sn2O7-SnO2 Nanostructures by Novel and Environment-Friendly Approach for the Photodegradation and Removal of Organic Pollutants in Water. Journal of Environmental Management, 233, 107-119. https://doi.org/10.1016/j.jenvman.2018.12.011
[11]
Jin, Song, J., Deng, S. and Li, G. (2014) Synthesis and Microwave Absorbing Characteristics of Flake-Like Polypyrrole Filled Composites in X-Band. Polymer Composite, 37, 533-538. https://doi.org/10.1002/pc.23209
[12]
Tiwari, D.C., Patil, P.B., Sharma, R., Singh, D. and Singh, S.P. (2007) “Microwave”, in Proc. DAE 52th, Solid State Physics, 435-436.
[13]
Tiwari, D.C., Dipak, P., Dwevide, S.K., Shami, T.C. and Dwevide, P. (2018) PPy/TiO2(np)/CNT Polymer Nanocomposite Material for Microwave Absorption. Journal of Materials Science: Materials in Electronics, 29, 1643-1650.
[14]
Tiwari, D.C., Dipak, P., Dwevide, S.K., Shami, T.C. and Dwivide, P. (2018) Synthesis and Characterization Polymer Nanocomposite of PANI/TiO2(np)-Fe+3 for Microwave Application. Journal of Materials Science: Materials in Electronics, 29, 6439-6445. https://doi.org/10.1007/s10854-018-8625-z
[15]
Hu, Z.A., et al. (2006) The Preparation and Characterization of Quadrate NiFe2O4/Polyaniline Nanocomposites. Journal of Materials Science: Materials in Electronics, 17, 859-863. https://doi.org/10.1007/s10854-006-0042-z
[16]
Chauhan, L., Shukla, A.K. and Sreenivas, K. (2015) Dielectric and Magnetic Properties of Nickel Ferrite Ceramics Using Crystalline Powders Derived from DL Alanine Fuel in Sol-Gel Auto-Combustion. Ceramics International, 41, 8341-8351. https://doi.org/10.1016/j.ceramint.2015.03.014
[17]
Ma, F., Qin, Y. and Li, Y.Z. (2010) Enhanced Microwave Performance of Cobalt Nanoflakes with Strong Shape Anisotropy. Applied Physics Letters, 96, Article ID: 202507. https://doi.org/10.1063/1.3432441
[18]
Zhang, S.Y., Cao, Q.X., Xue, Y.R. and Zhau, Y.X. (2015) Microwave Absorption Performance of the Absorber Based on Epsilon-Fe3N/Epoxy and Carbonyl Iron/Epoxy Composites. Journal of Magnetism and Magnetic Materials, 374, 755-761. https://doi.org/10.1016/j.jmmm.2014.08.073
[19]
Zhang, X.J., Wang, G.S., Wei, Y.Z., Guo, L. and Cao, M.S. (2013) Polymer-Composite with High Dielectric Constant and Enhanced Absorption Properties Based on Graphene-CuS Nanocomposites and Polyvinylidene Fluoride. Journal of Materials Chemistry A, 1, 12115-12122. https://doi.org/10.1039/c3ta12451g
[20]
Huang, L., Liu, X., Chuai, D., Chen, Y. and Yu, R. (2016) Flaky FeSiAl Alloy-Carbon Nanotube Composite with Tunable Electromagnetic Properties for Microwave Absorption. Scientific Reports, 6, Article No. 35377. https://doi.org/10.1038/srep35377
[21]
Ge, C., Zhang, X., Liu, J., Jin, F., Liu, J. and Bi, H. (2016) Hollow-Spherical Composites of Polyaniline/Cobalt Sulfide/Carbon Nanodots with Enhanced Magnetocapacitance and Electromagnetic Wave Absorption Capabilities. Applied Surface Science, 378, 49-56. https://doi.org/10.1016/j.apsusc.2016.03.210
[22]
Matsumoto, M. and Miyata, Y. (1997) Thin Electromagnetic Wave Absorber for Quasi-Microwave Band Containing Aligned Thin Magnetic Metal Particles. IEEE Transactions on Magnetics, 33, 4459-4464. https://doi.org/10.1109/20.649882
[23]
Zhang, S.G., Zhu, H.X., Tian, J.J., Pan, D.A., Liu, B. and Kang, Y.T. (2013) Electromagnetic and Microwave Absorbing Properties of FeCoB Powder Composites. Rare Metals, 32, 402-407. https://doi.org/10.1007/s12598-013-0115-0
[24]
Azadmanjiri, A., Talemi, P.H., Simon, G.P., Suzuki, K. and Selomulya, C. (2011) Polymer Engineering & Science, 248-253.
[25]
Zhou, W., Hu, X., Sun, C., Yan, J., Zhou, S. and Chen, P. (2014) Polymers for Advanced Technologies, 25, 83-88.
[26]
D. Yuping, Z. Yahong, W. Tongmin, G. Shuchao, L. Xin, L. Xingjun, (2014) Evolution Study of Microstructure and Electromagnetic Behaviors of Fe-Co-Ni Alloy with Mechanical Alloying. Materials Science and Engineering: B, 185, 86-93. https://doi.org/10.1016/j.mseb.2014.02.014