|
|
微波催化化学反应理论研究及催化新概念探索
|
Abstract:
微波在日常生活中获得了广泛应用。本文研究了微波催化化学反应的相关理论及探讨了某些催化领域的新概念。催化方法技术的三次飞跃，以及物理催化、组合催化、接力催化、同时催化、惰性催化、溶剂催化和精准催化控制等这些新概念的运用，必将引起催化化学领域的革命性变化和发展。多种组合催化方法的推广应用，无论其机理是否得到深刻的阐明，将在化学及其相关领域产生广泛而又深远的影响。
Macrowave finds wide application in our daily life. In this paper, the theory of microwave catalytic chemical reaction and some new concepts in the field of catalysis are discussed. Three leaps of catalytic technology, application of new concepts such as physical catalysis, combined catalysis, relay catalysis, simultaneous catalysis, inert catalysis, solvent catalysis and precise catalytic control will cause revolutionary changes and development in the field of catalytic chemistry. The popularization and application of various combined catalytic methods, whether or not its mecha-nism has been profoundly clarified, will have a wide and far-reaching influence in chemistry and related fields.
| [1] | 胡曌玺, 王存文, 闵清, 尤进茂, 马密霞, 胡文祥. 微波化学研究进展——京东祥鹄微波化学联合实验室微波化学领域相关研究成果目录及部分论文集[M]. 武汉: 汉斯出版社, 2019. |
| [2] | 秦宁, 闵清, 阮新志, 吴云韬, 杨萱平, 胡文祥. 书评: 《微波化学研究进展》[J]. 微波化学, 2019, 3(3): 29-35. |
| [3] | 郝静远, 王存文, 胡文祥. 书评: 《微波化学》[J]. 微波化学, 2019, 3(2): 15-27. |
| [4] | Hu, W.X. (2018) Catalytic Synthesis and Substituent Effect. Hans Publishers, Wuhan. |
| [5] | 李明, 郭维斯, 王书文, 等. 有机化学实验第二版[M]. 北京: 科学出版社, 2019. |
| [6] | 陆模文, 胡文祥, 恽榴红. 有机微波化学研究进展[J]. 有机化学, 1995, 15(6): 561-566. |
| [7] | 胡文祥, 胡文辉, 王建营, 丁景范, 恽榴红. 微波催化药物合成研究进展[J]. 中国药物化学杂志, 1999, 9(1): 70-78. |
| [8] | 胡文祥, 刘明, 弓亚玲. 微波催化有机药物反应机理及其应用研究[J]. 压电与声光, 2008, 30(2s): 9-11. |
| [9] | 韩谢, 吴元欣, 邵开元, 胡文祥. 微波萃取技术在天然产物提取中的应用[J]. 微波化学, 2017, 1(1): 3-7. |
| [10] | 马密霞, 秦宁, 闵清, 胡文祥. 微波超声波联用萃取花生芽中白藜芦醇及其含量HPLC测定[J]. 化工学报, 2019, 70(s1): 124-129. |
| [11] | 胡文祥, 王建营. 协同组合化学[M]. 北京: 科学出版社, 2003. |
| [12] | 付梦蕾, 曲有乐, 马密霞, 韩谢. 书评: 《协同组合化学》[J]. 比较化学, 2018, 2(1): 11-15. |
| [13] | 王陆瑶, 胡文祥. “分子温度”与微波的非热效应[C]//中国化学会全国微波化学学术研讨会论文摘要集. 咸宁: 湖北祥鹄, 2005: 156. |
| [14] | 《千桥飞梦》编写组. 千桥飞梦——胡文祥哲学宇宙学社会科学相关思考录[M]. 第三卷, 武汉: 汉斯出版社, 2019. |
| [15] | 胡文祥. 反恐药物战. In: 肖军华, 盛任农, 主编, 李方, 胡文祥, 李文君, 单大国, 聂福德, 副主编, 公关安全中的化学问题研究进展[M]. 第四卷. 北京: 中国人民公安大学出版社, 2015: 515. |
| [16] | 胡文祥. 微波催化化学反应热力学与动力学[C]//第三届全国公共安全化学会议邀请报告. 北京: 中国人民公安大学出版社, 2011: 769-792. |
| [17] | Song, S., et al. (2019) DMSO-Catalysed Late-Stage Chlorination of (Hetero)arenes. Nature Catalysis, 3, 107-115.
https://doi.org/10.1038/s41929-019-0398-0 |
| [18] | Duan, H.H., et al. (2019) Molecular Nitrogen Promotes Catalytic Hydrodeoxygenation. Nature Catalysis, 2, 1078-1087.
https://doi.org/10.1038/s41929-019-0368-6 |
| [19] | Li, G.H., Zhou, W., Li, X.X., Bi, Q.W., Wang, Z., Zhao, Z.G., Hu, W.X. and Chen, Z.L. (2013) Gold Catalyzed Enantioselective Intermolecular [3+2] Dipolar Cycloaddition of N-allenyl Amides with Nitrones. Chemical Communication, 49, 4770-4772. https://doi.org/10.1039/c3cc41769g |
| [20] | 魏国强, 徐高, 胡文祥. 金催化化学概况及新进展[J]. 化学通报, 2011, 74(2): 99-105. |
| [21] | Liu, M. and Hu, W.X. (2013) Recent Progress of Microwave Irradiation in Synthesis and Diagnosis Treatment. Advanced Material Research, 616-618, 1711-1716. https://doi.org/10.4028/www.scientific.net/AMR.616-618.1711 |
| [22] | 胡文祥, 何林涛, 等. 反恐技术方略[M]. 北京: 化学工业出版社, 2013. |
| [23] | 胡文祥, 刘明. 阿片受体分子药学[M]. 北京: 化学工业出版社, 2014. |
| [24] | 秦宁, 闵清, 邵开元, 胡文祥. 间甲基苯甲脒盐酸盐的合成研究[J]. 化工学报, 2019, 70(s1): 242-247. |
| [25] | Liu, Z.Z., Deng, B.Q., Li, S.L. and Zou, Z.R. (2018) Optimization of Solvent-Free Microwave Assisted Extraction of Essential Oil from Cinnamomum camphora Leaves. Industrial Crops & Products, 124, 353-362.
https://doi.org/10.1016/j.indcrop.2018.08.016 |
| [26] | Yang, B.W., An, Q.F., Zhao, Z.G., Shao, K.Y. and Hu, W.X. (2019) Research on Chemical Reactivity of Nitrotriazolam in Its Process of Preparation. Chemical Research in Chinese University, 35, 680-685.
https://doi.org/10.1007/s40242-019-8339-7 |
| [27] | Shen, X.Z., He, H.J., Yang, B., Zhao, Z.G., Shao, K.Y. and Hu, W.X. (2017) Studies on the Activities of Electrophilic Sites on Benzene Ring of 4-Substituted Anilines and Their Acyl Compounds with Multiphilicity Descriptor. Chemical Research in Chinese University, 33, 773-778. https://doi.org/10.1007/s40242-017-7112-z |
| [28] | 胡曌玺, 喻长远, 陈禹宝, 许立达, 李博, 马密霞, 胡红兵, 杨博文. 交叉科学研究进展——胡文祥交叉科学相关研究部分论文集[M]. 武汉: 汉斯出版社, 2020. |
