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甘油直接氢解合成1,3-丙二醇催化剂的研究与进展
Research and Progress on Catalysts for Direct Hydrogenolysis of Glycerol to 1,3-Propanediol

DOI: 10.12677/AMC.2020.82004, PP. 23-34

Keywords: 甘油，1,3-丙二醇，反应机理，催化剂
Glycerol, 1,3-Propanediol, Reaction Mechanism, Catalyst

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Abstract:

1,3-丙二醇作为聚酯(PTT)的合成单体之一，在许多领域有着宽阔的应用前景。甘油是合成1,3-丙二醇的原料之一。合成1,3-PDO的方法有很多，最近几年的研究热点是甘油直接氢解一步合成法，这种方法被学者们认同并广泛地研究。本文主要介绍了十余年来甘油氢解生成1,3-PDO的催化剂的研究，对催化剂的类型、载体的性质、催化剂的制备和催化反应条件进行了归纳总结。给出一些我们对催化剂的组分、制备方法的理解以及催化反应的机理。同时分析了今后的研究发展方向。
As one of the synthetic monomers of polyester (PTT), 1,3-propanediol has broad application pro-spects in many fields. Glycerol is one of the raw materials for the synthesis of 1,3-propanediol. There are many methods to synthesize 1,3-pdo. In recent years, cerium glycerin is one-step syn-thesis by direct hydrogenolysis. This method is recognized by scholars and studied extensively. In this paper, we mainly introduce the research of catalysts for the hydrogenolysis of glycerol to 1,3-pdo over the past ten years, and summarize the types of catalysts, types of supports, synthesis methods and process conditions of catalysts. Some of our understanding of the components of the catalyst, the preparation method and the mechanism of the catalytic reaction are given. At the same time, the future research direction is analyzed.

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