对高性能超级电容器不断增长的需求促进了无粘合剂电极材料的快速发展。静电纺纳米纤维由于具有良好的柔性、大比表面积、高孔隙率、容易制备等优点引起了研究者们的强烈关注。本文综述了静电纺纳米纤维基无粘合剂电极材料在超级电容器领域的研究进展，阐述了不同材料的设计制备过程和提升电化学性能的诸多方法，并指明了静电纺纳米纤维基超级电容器无粘合剂电极材料的发展机遇与挑战，为性能优异的无粘合剂超级电容器电极材料的进一步开发与应用拓宽了思路。
The increased demand for high-performance supercapacitors has fueled the development of electrode materials. As an important part of supercapacitors, the electrochemical performance of the supercapacitor is directly affected by the specific surface area, conductivity, electrochemical activity, and stability of electrode materials. In the traditional manufacturing method, a binder must be added to powdered electrode materials to enhance their combination with the current collector, which could lead to morphology damage, pore blockage, and reduced conductivity of active materials that will adversely affect their electrochemical behavior. Thus, research on binder-free electrode materials has attracted significant interest. Recently, electrospun nanofibers have been widely used as supercapacitor electrode materials because of their advantages such as large specific surface area, high porosity, and easy preparation. The attainable continuity and flexibility endow electrospun nanofiber membranes outstanding performance among large numbers of binder-free materials. This review considers recent studies on electrospun nanofiber-based binder-free electrode materials for supercapacitors, including carbon nanofibers, carbon-based composite nanofibers, conductive polymer-based composite nanofibers, and metal oxide nanofibers. These studies demonstrate that pore structure construction, activation treatment, and nitrogen doping can improve the specific surface area, electrochemical activity, wettability, and graphitization degree of carbon nanofibers to enhance their electrochemical properties. Moreover, combining carbon nanofibers with metal oxides, metal sulfides, metal carbides, and conductive polymers by methods such as blending, chemical deposition, electrochemical deposition, etc., can improve their capacitance, rate performance, and cycling stabilities, which complement the advantages of different materials and proves that the performance of multicomponent materials is better than that of single-component materials. In particular, conductive polymers based on composite nanofibers and metal oxide nanofibers can be used as binder-free materials by electrospinning technology, but their dependence on other substances as well as fragile fiber membrane limit their widespread application. Therefore, in order to ensure the continuity or flexibility of fiber