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-  2020 

Electrocoagulation (Ec) of Styrene Butadiene Rubber from Aqueous Solution using different Electrodes

DOI: 10.25141/2474-8811-2016-2.0037

Keywords: Styrene Butadiene Rubber, Electrocoagulation, Water Treatment, Electrode, Adsorption, Kinetics. %E =[ (A0 - A) / A0 ]?? 100 (5) Effect of current density on the efficiency of Styrene butadiene rubber adsoprtion using iron (a), stainless steel (b) and aluminum (c) electrodes respectively Effect of current density, pH, type of electrolyte, concentration electrolyte, rubber concentration, and temperature on the efficiency of COD removal for Styrene butadiene rubber using iron (a), stainless steel (b) and aluminum (c) electrodes respectively. Effect of pH on the efficiency of Styrene butadiene rubber adsoprtion using iron (a), stainless steel (b) and aluminum (c) electrodes respectively . Effect of electrolyte concentration on the efficiency of Styrene butadiene rubber adsoprtion using iron (a), stainless steel (b) and aluminum (c) electrodes respectively. Effect of initial concentration on the efficiency of Styrene butadiene rubber adsorption using iron (a), stainless steel (b) and aluminum (c) electrodes respectively Effect of temperature on the efficiency of Styrene butadiene rubber adsoprtion using iron (a), stainless steel (b) and aluminum (c) electrodes respectively. Effect of type of electrolyte on the efficiency of Styrene butadiene rubber adsoprtion using iron (a), stainless steel (b) and aluminum (c) electrodes respectively . Relation between Ln At against the time for Styrene butadiene rubber adsoprtion using iron (a), stainless steel (b) and aluminum (c) electrodes respectively . Langmuir plot (Ce/qe) vs. (Ce) for Styrene butadiene rubber adsoprtion using S.S electrodes. Freundlich plot (log qe vs. log Ce). for Styrene butadiene rubber adsoprtion using S.S electrodes. .

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Abstract:

The removal of Styrene Butadiene Rubber (SBR) from aqueous solution by electrocoagulation using different electrodes was investigated. The main objectives of the experiments were to investigate the effects of the various operating parameters on the SBR and chemical oxygen demand (COD) removal efficiency from aqueous solution. The optimal operating condition for removal of (SBR) were : initial pH of 7.1, an initial polymer concentration of 200 mg/L, temperature of 30 oC, current density (25 mA/cm2) and salt concentration of (1.5 g/L) by using iron (Fe), stainless steel (SS) and aluminum (Al) electrodes. The results showed that the removal percentage for SBR and COD were (99.2% and 91.2 %), (99.4% and 93.5%) and (98.9 % and 90.2%) by using (Fe), (SS) and (Al) electrodes at 15 min respectively. The adsorption equilibriums were analyzed by Langmuir and Freundlich isotherm models. It was found that the data fitted to Freundlich (R?2 = 0.954) better than Langmuir (R?2 = 0.777) model. The removal of SBR exhibited a pseudo first order reaction with rate constant (0.191, 0.245 and 0.142 min-1) for Fe, SS and Al electrodes respectivel

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