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OALib Journal期刊
ISSN: 2333-9721
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-  2019 

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DOI: https://doi.org/10.1016/j.chempr.2019.04.018

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Abstract:

Polariton chemistry is a new class of chemistry that occurs in strongly confined environments, such as optical cavities, where light-matter interactions are modified by the strong coupling limit. In this issue of Chem, Du et al. show a theoretical example where a catalyst is capable of inducing a reaction without touching the reactant when both are confined in a quantum-based optical device. Thanks to the strong coupling of two adjacent optical cavities, the study demonstrates that it would be possible to drive the cis → trans conformational isomerization of nitrous acid, contained in one cavity, by increasing the photoexcitation of glyoxylic acid in another cavity

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