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-  2019 

Electrostatic Forces in Field-Perturbed Equilibria: Nanopore Analysis of Cage Complexes

DOI: https://doi.org/10.1016/j.chempr.2019.03.004

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Abstract:

? Cage-nanopore association kinetics were dominated by the applied electric field ? Local electrostatic interactions more strongly influenced dissociation kinetics ? External voltages could be used to selectively bind specific cages from a mixture ? Higher potentials drove enantio-inversion, nanopore capture, or disassembly of cage

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