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MOFs衍生多孔材料的研究进展
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Abstract:
金属有机骨架(MOFs)材料是由金属离子或团簇与有机配体构成晶态多孔材料，常被用作前驱体来衍生具有高比表面积、高孔隙率、孔径可调、高导电性和稳定性等优异性能的衍生多孔材料。本文论述了直接热解、共裂解、复合材料热解和溶液掺入后热处理四种不同制备MOFs衍生材料的策略以及MOFs衍生材料在有机催化、光催化和电催化中的潜在应用。
Metal organic framework (MOFs) materials are crystalline porous materials composed of metal ions or clusters and organic ligands, which are often used as precursors to derive derived-porous materials with high specific surface area, high porosity, adjustable pore size, high electrical conductivity and stability. In this paper, four different strategies for the preparation of MOFs derived materials, including direct pyrolysis, co-pyrolysis, composite pyrolysis and solution infiltration method followed by heat treatment, and the potential applications of MOFs derived materials in organic catalysis, photocatalysis and electrocatalysis are discussed.
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