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过渡金属基电催化剂在全解水反应中的动力学调控策略
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Abstract:
过渡金属(TM)基催化剂因其在水分解中的独特优势而被广泛研究。尽管目前国内外取得了重大进展，但TM基材料在电催化中的有效动力学调控策略仍处于初始阶段。通过在TM基催化剂中引入异质成分，形成特定的界面，有利于调整催化剂界面环境和化学吸附行为，从而加速动力学过程。在这篇综述中，我们全面总结了TM基电催化剂的动力学调控策略，包括界面工程、缺陷工程、掺杂工程和晶面工程，并且在全文最后概述了这一新兴领域当前面临的机遇与挑战。
Transition Metal (TM)-based catalysts are widely studied for their unique advantages in water splitting. Despite sig-nificant progress, efficient kinetic regulation strategies for TM-based materials in electrocatalysis and real-time monitoring of the dynamic evolution of reaction processes are still in the initial stages. By introducing heterogeneous components into the TM-based catalyst and forming a specific inter-face, it is beneficial to adjust the catalyst interface environment and chemical adsorption behavior, thereby accelerating the kinetic process. In this review, the kinetic regulation strategies of TM-based electrocatalysts are timely and comprehensively summarized, including interface engi-neering, defect engineering, doping engineering and crystal face engineering. Finally, we outline the current challenges and identify the opportunities facing this emerging area.
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