The synthesis for glasses series xFe2O3-(45-x)PbO-55P2O5, (with 0≤x≤20; mol%) carried out in a temperature (1050±10)°C, leads to obtaining transparent glasses, brown in color and with a non-hygroscopic appearance. The study of glasses dissolution rate, immersed in distilled water at 90°C for 24 days, indicates a considerable chemical durability. The increase in the Fe2O3 content in the vitreous network to the detriment of PbO is a favorable factor for the chemical durability improvement. Different techniques have been used such as X-ray diffraction, infrared spectroscopy, DSC, SEM and density for the study of these glasses. These techniques have led to establish correlations between chemical and structural properties. Thus the results obtained confirmed the creation of P-O-M bonds (M= Pb, Fe) with a strongly covalent nature to the detriment of the hydrated P-O-P bonds and led to the formation, mainly, of pyrophosphate groups. The low melting point of Pb-O makes it possible to play an important role, at the same time, on the viscosity, on the equilibrium between the vitreous bath and the crystallites formed. The
References
[1]
Beloued, N., Chabbou, Z. and Aqdim, S. (2016) Correlation between Chemical Durability Behaviour and Structural Approach of the Vitreous Part of the System 55P2O5-2Cr2O3-(43-x)Na2O-xPbO. Advances in Materials Physics and Chemistry, 6, 149-156. https://doi.org/10.4236/ampc.2016.66016
[2]
Jakhati, S., Nadavalumane, N. and Ashwajeet, J. (2022) Studies of Anomalies in Mixed Conduction of Na2O and V2O5 Doped Boro-Phosphate Glasses. New Journal of Glass and Ceramics, 12, 1-18.
[3]
Yu, X., Day, D.E., Long, G.J. and Brow, R.K. (1997) Properties and Structure of Sodium-Iron Phosphate Glasses. Journal of Non-Crystalline Solids, 215, 21-31.
https://doi.org/10.1016/S0022-3093(97)00022-7
[4]
Kiani, A., Hanna, J.V., King, S.P., Rees, G.J., Smith, M.E., Roohpour, N. and Knowles, J.C. (2012) Structural Characterization and Physical Properties of P2O5-CaO-Na2O- TiO2 Glasses by Fourier Transform Infrared, Raman and Solid-State Magic Angle Spinning Nuclear Magnetic Resonance Spectroscopies. Acta Biomaterialia, 8, 333-340.
https://doi.org/10.1016/j.actbio.2011.08.025
[5]
Colak, S.C. and Aral, E. (2011) Optical and Thermal Properties of P2O5-Na2O-CaO- Al2O3: CoO Glasses Doped with Transition Metals. Journal of Alloys and Compounds, 509, 4935-4939. https://doi.org/10.1016/j.jallcom.2011.01.172
[6]
Videau, J.J. and Gilles, F. (2010) Les verres phosphates de la spécificité de l’atome de phosphore à la formation, la structure et la durabilité chimique de phosphates vitreux. Institut de Chimie de la Matière Condensée de Bordeaux, CNRS, Université de Bordeaux, Bordeaux.
[7]
Santic, A., Skoko, Z., Gajovic, A., Reis, S.T., Day, D.E. and Mogus-Milankovic, A. (2011) Physical Properties of Lead Iron Phosphate Glasses Containing Cr2O3. Journal of Non-Crystalline Solids, 357, 3578-3584.
https://doi.org/10.1016/j.jnoncrysol.2011.07.011
[8]
Makhkhas, Y., Aqdim, S. and Sayouty, E.H. (2013) Study of Sodium-Chromium- Iron-Phosphate Glass by XRD, IR, Chemical Durability and SEM. Journal of Materials Science and Chemical Engineering, 1, 1-6.
https://doi.org/10.4236/msce.2013.13001
[9]
Aqdim, S., Errouissi, Y., Cherif, A. and Makhlouk, R. (2017) Elaboration and Characterization of Glasses and Ceramic-Glasses within the Ternary Diagram Li2O- Cr2O3-P2O5. Advances in Materials Physics and Chemistry, 7, 123-137.
https://doi.org/10.4236/ampc.2017.74011
[10]
El-Egili, K., Doweidar, H., Moustafa, Y.M. and Abbas, I. (2008) Structure and Some Properties of PbO-P2O5 Glasses. Physica B, 339, 237-245.
https://doi.org/10.1016/j.physb.2003.07.005
[11]
Brow, R.K. (2000) Review: The Structure of Simple Phosphate Glasses. Journal of Non-Crystalline Solids, 263-264, 1-28.
https://doi.org/10.1016/S0022-3093(99)00620-1
[12]
Er-Rouissi, Y., et al. (2020) Chemical Durability, Structure Properties and Bioactivity of Glasses 48P2O5-30CaO-(22-x)Na2O-xTiO2 (With 0< x ≤ 3; mol%). Advances in Materials Physics and Chemistry, 10, 305-318.
https://doi.org/10.4236/ampc.2020.1012024
[13]
Errouissi, Y., Chabbou, Z., Beloued, N., Aqdim, S. and Aqdim, S. (2017) Chemical Durability and Structural Properties of Al2O3-CaO-Na2O-P2O5 Glasses Studied by IR Spectroscopy, XRD and SEM. Advances in Materials Physics and Chemistry, 7, 353-363. https://doi.org/10.4236/ampc.2017.710028
[14]
Aqdim, S. (2007) Investigation des phases vitreuses des systèmes (Li, Na)2O-(Fe, Al)2O3-P2O5 par Spectroscopies Infrarouge et Mossbauer-Structures et Durabilité chimique. These, Faculté des Sciences de Casablanca Ain Chock, Casablanca.
[15]
Aqdim, S., Elouadi, B. and Grenech, J.M. (2012) Chemical Durability and Structural Approach of the Glass Series (40-y)Na2O-yFe2O3-5Al2O3-55P2O5by IR, X-Ray Diffraction and Mossbauer Spectroscopy. Material Sciences and Engineering, 27, Article ID: 012003. https://doi.org/10.1088/1757-899X/28/1/012003
[16]
Chabbou, Z. and Aqdim, S. (2014) Chemical Durability and Structural Proprieties of the Vitreous Part of the System xCaO-(40-x)ZnO-15Na2O-45P2O5. Advances in Materials Physics and Chemistry, 4, 179-180.
https://doi.org/10.4236/ampc.2014.410021
[17]
Ouchetto, M. (1993) Thèse de Doctorat d’Etat es Sciences. Faculty of Sciences Rabat, Rabat.
[18]
Aqdim, S. and Albizane, A. (2015) Structural Feature and Chemical Durability of Sodium Aluminium Iron Phosphate Glasses. Journal of Environmental Science, Computer Science and Engineering & Technology, 4, 509-521.
[19]
Santic, A., Mogus-Milankovic, A., Furic, K., Bermanec, V., Kim, D.W. and Daye, D.E. (2007) Structural Properties of Cr2O3-Fe2O3-P2O5 Glasses, Part I. Journal of Non-Crystalline Solids, 353, 1070-1077.
https://doi.org/10.1016/j.jnoncrysol.2006.12.104
[20]
Ingram, M.D., Imre, C.T. and Konidakis, I. (2006) Activation Volumes and Site Relaxation in Mixed Alkali Glasses. Journal of Non-Crystalline Solids, 352, 3200-3209.
https://doi.org/10.1016/j.jnoncrysol.2006.05.009
[21]
Imre, A., Divinski, S.V., Voss, S., Berkmeier, F. and Mehrer, H. (2006) A Revised View on the Mixed-Alkali Effect in Alkali Borate Glasses. Journal of Non-Crystalline Solids, 352, 783-788. https://doi.org/10.1016/j.jnoncrysol.2006.02.008
[22]
Aqdim, S., Sayouty, E.H. and Elouadi, B. (2008) Structural and Durability Investigation of the Vitreous Part of the System (35-z)Na2O-zFe2O3-5Al2O3-60P2O5. Eurasian Chemico-Technological Journal, 10, 9-17.
[23]
Bevilacqua, A.M., et al. (1996) Immobilization of Simulated High-Level Liquid Wastes in Sintered Borosilicate, Aluminosilicate and Aluminoborosilicate Glasses. Journal of Nuclear Materials, 229, 187-193. https://doi.org/10.1016/0022-3115(95)00229-4
[24]
Aqdim, S. and Ouchetto, M. (2013) Elaboration and Structural Investigation of Iron (III) Phosphate Glasses. Advances in Materials Physics and Chemistry, 3, 332-339.
https://doi.org/10.4236/ampc.2013.38046
[25]
Mogus-Milankovic, A., Santic, A., Reis, S.T., Furic, F. and Day, D.E. (2005) Studies of Lead-Iron Phosphate Glasses by Raman, Mossbauer and Impedance Spectroscopy. Journal of Non-Crystalline Solids, 351, 3246-3258.
https://doi.org/10.1016/j.jnoncrysol.2005.08.006
[26]
Bachachir, B., Er-Rouissi, Y., Makhlouk, R., Harrati, H., El Bouari, A. and Aqdim, S. (2021) Structural Features and Properties of the Vitreous Part of the System 50P2O5- 25CaO-(25-x)Na2O-xCoO (with 0 ≤ x ≤ 25; mol%). Advances in Materials Physics and Chemistry, 11, 254-266. https://doi.org/10.4236/ampc.2021.1112021
[27]
Doweidar, H., Moustafa, Y.M., El-Egili, K. and Abbas, I. (2005) Infrared Spectra of Fe2O3-PbO-P2O5 Glasses. Vibrational Spectroscopy, 37, 91-96.
https://doi.org/10.1016/j.vibspec.2004.07.002
[28]
Reis, S.T., Karabulut, M. and Day, D.E. (2001) Chemical Durability and Structure of Zinc-Iron Phosphate Glasses. Journal of Non-Crystalline Solids, 292, 150-157.
https://doi.org/10.1016/S0022-3093(01)00880-8
[29]
Srinivasa Reddy, M., Naga Raju, G., Nagarjuna, G. and Veeraiah, N. (2007) Structural Influence of Aluminium, Gallium and Indium Metal Oxides by Means of Dielectric and Spectroscopic Properties of CaO-Sb2O3-B2O3 Glass System. Journal of Alloys and Compounds, 438, 41-51. https://doi.org/10.1016/j.jallcom.2006.08.054
[30]
Beloued, N., Makhlouk, R., Er-Rouissi, Y., Taibi, M., Sajieddine, M. and Aqdim, S. (2019) Relationship between Chemical Durability, Structure and the Ionic-Covalent Character of Me-O-P Bond (Me = Cr, Fe), in the Vitreous Part of the System 60P2O5-2Cr2O3-(38-x)Na2O-xFe2O3 (with 3 ≤ x ≤ 33 mol%). Advances in Materials Physics and Chemistry, 9, 199-209.
