Polyvinyl alcohol (PVA) stabilized Polyvinyl acetate (PVAc) dispersions-based
wood adhesive has poor water and heat resistance. Recently, the addition of fillers in the wood adhesive is one of the most effective
ways to enhance the performance of PVAc wood adhesive. Inorganic fillers have
unique characteristics to improve the
performance of adhesive, such as small size, high surface energy and
surface hardness. Hence, the present work investigates the applicability of
calcium carbonate and clay incorporated 3% in situ emulsion polymerization PVAc wood adhesive. Effect on
physical, thermal and mechanical properties was studied by viscosity, pH,
contact angle measurement, differential scanning calorimetry (DSC) and pencil
hardness test of films.Emulsions
with 3% calcium carbonate and 3% clay were prepared and the shear
strength of the applied adhesive on wood was measured. The viscosity of the
adhesives was reduced in thecase of
the addition of calcium carbonate and
increased in the case of clay. The mechanical properties like tensile strength of adhesives with calcium carbonate and clay were measured by a universal
tensile machine (UTM). Thermal stability was studied by differential scanning
calorimetry (DSC). The tensile shear strength demonstrates that clay can
improve bonding strength as compared to
calcium carbonate of PVAc adhesive in wet
conditions. The hardness of PVAc films was also changed posi
References
[1]
Mori, A., Kitayama, T., Takatani, M. and Okamoto, T. (2004) A Honeymoon-Type Adhesive for Wood Products Based on Acetoacetylated Poly(vinyl alcohol) and Diamines: Effect of Diamines and Degree of Acetoacetylation. Journal of Applied Polymer Science, 91, 2966-2972. https://doi.org/10.1002/app.13491
[2]
Mori, A., Tashiro, K., Makita, K., Takatani, M. and Okamoto, T. (2005) Development of Room-Temperature Curing Aqueous Emulsion-Type Acrylic Adhesive II: Effect of Monomer Composition on the Final Adhesive Strength. Journal of Wood Science, 51, 38-41. https://doi.org/10.1007/s10086-003-0611-1
[3]
Gadhave, R. (2022) Starch Grafted Water Resistant Polyvinyl Acetate-Based Wood Adhesive: A Review. Open Journal of Organic Polymer Materials, 12, 17-30. https://doi.org/10.4236/ojopm.2022.122002
[4]
Kim, S. and Kim, H.-J. (2005) Effect of Addition of Polyvinyl Acetate to Melamine-Formaldehyde Resin on the Adhesion and Formaldehyde Emission in Engineered Flooring. International Journal of Adhesion and Adhesives, 25, 456-461. https://doi.org/10.1016/j.ijadhadh.2005.01.001
[5]
Liu, X., Zhang, X., Long, K., et al. (2012) PVA Wood Adhesive Modified with Sodium Silicate Cross-Linked Copolymer. Proceedings of 2012 International Conference on Biobase Material Science and Engineering, Changsha, 21-23 October 2012, 108-111. https://doi.org/10.1109/BMSE.2012.6466192
[6]
Dhawale, P.V., Vineeth, S.K., Gadhave, R.V., et al. (2022) Tannin as a Renewable Raw Material for Adhesive Applications: A Review. Materials Advances, 3, 3365-3388. https://doi.org/10.1039/D1MA00841B
[7]
Stoeckel, F., Konnerth, J. and Gindl-Altmutter, W. (2013) Mechanical Properties of Adhesives for Bonding Wood—A Review. International Journal of Adhesion and Adhesives, 45, 32-41. https://doi.org/10.1016/j.ijadhadh.2013.03.013
[8]
Kaboorani, A., Riedl, B. and Blanchet, P. (2013) Ultrasonication Technique: A Method for Dispersing Nanoclay in Wood Adhesives. Journal of Nanomaterials, 2013, Article ID: 341897. https://doi.org/10.1155/2013/341897
[9]
Moya, R., Rodríguez-Zúniga, A., Vega-Baudrit, J. and álvarez, V. (2015) Effects of Adding Nano-Clay (Montmorillonite) on Performance of Polyvinyl Acetate (PVAc) and Urea-Formaldehyde (UF) Adhesives in Carapa guianensis, a Tropical Species. International Journal of Adhesion and Adhesives, 59, 62-70. https://doi.org/10.1016/j.ijadhadh.2015.02.004
[10]
Gadhave, R.V.I. and Dhawale, P.V. (2022) State of Research and Trends in the Development of Polyvinyl Acetate-Based Wood Adhesive. Open Journal of Polymer Chemistry, 12, 13-42. https://doi.org/10.4236/ojpchem.2022.121002
[11]
Mohsen, R.M. (1992) Effect of Calcium Carbonate Filler on Polyvinyl Acetate Emulsion as Wood Adhesive. Pigment & Resin Technology, 21, 10-11. https://doi.org/10.1108/eb042981
[12]
Kaboorani, A. and Riedl, B. (2011) Effects of Adding Nano-Clay on Performance of Polyvinyl Acetate (PVA) as a Wood Adhesive. Composites Part A: Applied Science and Manufacturing, 42, 1031-1039. https://doi.org/10.1016/j.compositesa.2011.04.007
[13]
Dhawale, P.V., Vineeth, S.K., Gadhave, R.V. and Mahanwar, P.A. (2021) Cellulose Stabilized Polyvinyl Acetate Emulsion: Review. Open Journal of Organic Polymer Materials, 11, 51-66. https://doi.org/10.4236/ojopm.2021.112002
[14]
Gadhave, R. and Dhawale, P. (2022) State of Research and Trends in the Development of Polyvinyl Acetate-Based Wood Adhesive. Open Journal of Polymer Chemistry, 12, 13-42. https://doi.org/10.4236/ojpchem.2022.121002
[15]
Lu, T., Du, J. and Samulyak, R. (2008) A Numerical Algorithm for Magnetohydrodynamics of Ablated Materials. Journal of Nanoscience and Nanotechnology, 8, 3674-3685. https://doi.org/10.1166/jnn.2008.18333
[16]
Zhang, Y., Ding, L., Gu, J., Tan, H. and Zhu, L. (2015) Preparation and Properties of a Starch-Based Wood Adhesive with High Bonding Strength and Water Resistance. Carbohydrate Polymers, 115, 32-37. https://doi.org/10.1016/j.carbpol.2014.08.063
[17]
Baldan, A. (2004) Adhesively-Bonded Joints and Repairs in Metallic Alloys, Polymers and Composite Materials: Adhesives, Adhesion Theories and Surface Pretreatment. Journal of Materials Science, 39, 1-49. https://doi.org/10.1023/B:JMSC.0000007726.58758.e4
[18]
Shaffei, K.A., Moustafa, A.B. and Hamed, A.I. (2009) The Emulsion Polymerization of Each of Vinyl Acetate and Butyl Acrylate Monomers Using Bis(2-ethylhexyl) Maleate for Improving the Physicomechanical Properties of Paints and Adhesive Films. International Journal of Polymer Science, 2009, Article ID: 731971. https://doi.org/10.1155/2009/731971
[19]
Gadhave, R. (2022) Importance of Dynamic Mechanical Analysis to Predict Performance of the Polyvinyl Acetate Wood Adhesives in Summer Season. Open Journal of Polymer Chemistry, 12, 93-100. https://doi.org/10.4236/ojpchem.2022.123006
[20]
López-Suevos, F. and Frazier, C.E. (2006) Fracture Cleavage Analysis of PVAc Latex Adhesives: Influence of Phenolic Additives. Holzforschung, 60, 313-317. https://doi.org/10.1515/HF.2006.050
[21]
Kim, S. and Kim, H.-J. (2006) Thermal Stability and Viscoelastic Properties of MF/PVAc Hybrid Resins on the Adhesion for Engineered Flooring in Underheating System; ONDOL. Thermochimica Acta, 444, 134-140. https://doi.org/10.1016/j.tca.2006.03.009
[22]
Ferrándiz-Gómez, T.P., Fernández-García, J.C., Orgilés-Barceló, A.C. and Martín-Martínez, J.M. (1996) Effects of Hydrocarbon Tackifiers on the Adhesive Properties of Contact Adhesives Based on Polychloroprene. I. Influence of the Amount of Hydrocarbon Tackifier. Journal of Adhesion Science and Technology, 10, 833-845. https://doi.org/10.1163/156856196X00887
[23]
Gadhave, R., Mahanwar, P. and Gadekar, P. (2019) Study of Cross-Linking between Boric Acid and Different Types of Polyvinyl Alcohol Adhesive. Open Journal of Polymer Chemistry, 9, 16-26. https://doi.org/10.4236/ojpchem.2019.91002
[24]
Poh, B.T. and Firdaus, S.Z. (2010) Effect of Hybrid Tackifiers on Adhesion Properties of Epoxidized Natural Rubber-Based Pressure-Sensitive Adhesives. Journal of Polymers and the Environment, 18, 335-338. https://doi.org/10.1007/s10924-010-0197-9
[25]
Bomba, J., Cvach, J., Sedivka, P. and Kvietková, M. (2014) Strength Increase Pattern in Joints Bonded with PVAc Adhesives. BioResearch, 9, 1027-1037. https://doi.org/10.15376/biores.9.1.1027-1037
[26]
Kaboorani, A., Riedl, B., Blanchet, P., et al. (2012) Nanocrystalline Cellulose (NCC): A Renewable Nano-Material for Polyvinyl Acetate (PVA) Adhesive. European Polymer Journal, 48, 1829-1837. https://doi.org/10.1016/j.eurpolymj.2012.08.008
[27]
Kaboorani, A. and Riedl, B. (2012) Nano-Aluminum Oxide as a Reinforcing Material for Thermoplastic Adhesives. Journal of Industrial and Engineering Chemistry, 18, 1076-1081. https://doi.org/10.1016/j.jiec.2011.12.001
[28]
Mohan, P. (2013) A Critical Review: The Modification, Properties, and Applications of Epoxy Resins. Polymer—Plastics Technology and Engineering, 52, 107-125. https://doi.org/10.1080/03602559.2012.727057
[29]
Pique, T.M., Pérez, C.J., Alvarez, V.A. and Vázquez, A. (2014) Water Soluble Nanocomposite Films Based on Poly(vinyl alcohol) and Chemically Modified Montmorillonites. Journal of Composite Materials, 48, 545-553. https://doi.org/10.1177/0021998313476322
[30]
Lei, H., Du, G., Pizzi, A. and Celzard, A. (2008) Influence of Nanoclay on Urea-Formaldehyde Resins for Wood Adhesives and Its Model. Journal of Applied Polymer Science, 109, 2442-2451. https://doi.org/10.1002/app.28359
[31]
Pirayesh, H., Khanjanzadeh, H. and Salari, A. (2013) Effect of Using Walnut/Almond Shells on the Physical, Mechanical Properties and Formaldehyde Emission of Particleboard. Composites Part B: Engineering, 45, 858-863. https://doi.org/10.1016/j.compositesb.2012.05.008
[32]
Esin Ates, N.K. and Uyanik, N. (2013) Preparation of Urea Formaldehyde Resin/Layered Silicate Nanocomposites. Pigment & Resin Technology, 42, 283-287. https://doi.org/10.1108/PRT-07-2012-0043
[33]
Vera Kovacevic, I.S., Lucic, S., Hace, D. and Packham, D. (1999) Composites of Poly(vinyl acetate) Filled with Calcium Carbonate: Microscopy, Diffractometry and Thermophysical Properties. Polymer Engineering & Science, 39, 1433-1443. https://doi.org/10.1002/pen.11534