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MOFs复合材料及在锂离子电池中应用研究进展
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Abstract:
锂离子电池是目前纯电动汽车和混动汽车的主流动力电源，因其循环寿命长、能量密度高以及自放电率低等优点备受青睐。金属–有机框架材料(Metal-Organic Frameworks，简称MOFs，下同)作为新型功能分子晶体材料，在锂离子电池中有着潜在的应用前景，成为新型功能材料研究的热点。本文通过综合国内外相关文献报道，调研了MOFs材料及其衍生材料的合成方法和结构调控方面的最新研究进展。着重对于MOFs以及其衍生物在锂离子电池负极和正极方面的应用进行全面综合。同时，对目前MOFs在锂离子电池应用领域所面临的挑战进行了深入分析，同时也对其未来的发展前景进行了展望。进一步研究MOFs在锂离子电池中电荷负载能力和多孔结构特点等性能优势，以期为锂离子电池电极材料进一步开发与应用提供参考。
Lithium-ion batteries are the mainstream power supply for pure electric vehicles and hybrid vehicles at present, because of their long cycle life, high energy density and low self-discharge rate. Metal-organic frameworks (MOFs), as a new functional molecular crystal material, have potential application prospects in lithium-ion batteries and become a hot spot in the research of new functional materials. This article comprehensively reviews the latest research progress in synthesis methods and structural regulation of MOFs materials and their derivatives based on an integration of relevant literature reports from domestic and international sources. The application of MOFs and its derivatives in the negative and positive electrodes of lithium-ion batteries is reviewed, and the challenges and prospects of the application of MOFs in lithium-ion batteries are analyzed. Further research on the performance advantages of MOFs, such as their charge loading capacity and porous structural characteristics, in lithium-ion batteries is aimed at providing references for further development and application of electrode materials for lithium-ion batteries.
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