Natural gas (NG) is one of the most important
sources of energy for industrial and domestic consumption in the present era
because it is cheap and free from sulfur impurities. Therefore, accurate and
precise measurement of its composition is of fundamental importance for trade
reasons. To improve the quality of NG gas measurements, certified reference
materials (CRMs) should be used for calibration of measuring equipment in order
to ensure the traceability of the measurement results to the SI units. For the
traceability purpose, a multicomponent natural gas mixture was prepared
gravimetrically as a reference material according to ISO 6142 from pure helium,
hydrogen, n-pentane, i-pentane, n-butane, i-butane, propane, ethane, hexane,
methane and nitrogen. The preparation was done in two dilution steps in 5L aluminum cylinders. The calculated mole fractions and associated
uncertainties of natural gas components were verified by a dual GC-FID/TCD
system in accordance with ISO 6143 calibrated by a series of primary gas
mixtures (CRMs) produced by an NMI. The results obtained by gravimetry and by
GC measurements have been checked for compatibility as required by ISO 6142 and
were found in very good agreement. Details of the preparation and calculation
of the mole fractions and uncertainties of all gas components are explained in this
article.
References
[1]
Wardzinski, J., et al. (2004) Interstate Natural Gas—Quality Specifications & Interchangeability. Center for Energy Economics, Bureau of Economic Geology, The University of Texas, Austin. https://www.beg.utexas.edu/files/energyecon/global-gas-and-lng/CEE_Interstate_Natural_Gas_Quality_Specifications_and_Interchangeability.pdf
[2]
Andrew, S.B., Martin, J.T.M., Chris, J.C., Gavin, D.S., Wolfram, B. and Richard, W.B. (2004) Analysis of Natural Gas by Gas Chromatography Reduction of Correlated Uncertainties by Normalization. Journal of Chromatography A, 1040, 215-225. https://doi.org/10.1016/j.chroma.2004.04.007
[3]
Greorge, C.R. (2003) Analysis of Natural Gas: The Necessity of Multiple Standards for Calibration. Journal of Chromatography A, 1017, 131-139. https://doi.org/10.1016/j.chroma.2003.08.002
[4]
Cowper, C.J. (1995) The Analysis of Hydrocarbon Gases. Journal of Chromatography Library, 56, 1-40. https://doi.org/10.1016/S0301-4770(08)61280-4
[5]
Brown, A.S., Milton, M.J., Cowper, C.J., Squire, G.D., Bremser, W. and Branch, R.W. (2004) Analysis of Natural Gas by Gas Chromatography. Journal of Chromatography A, 1040, 215-225. https://doi.org/10.1016/j.chroma.2004.04.007
[6]
Skrbic, B.D. and Zlatkovic, M.J. (1983) Simple Method for the Rapid Analysis of Natural Gas by Gas Chromatography. Chromatographia, 17, 44–46. https://doi.org/10.1007/BF02265109
[7]
ASTM Standard D1945-03 (2003) Standard Test Method for Analysis of Natural Gas by Gas Chromatography. https://webstore.ansi.org/standards/astm/astmd194503
[8]
ASTM Standard D1946-90 (2000) Standard Practice for Analysis of Reformed Gas by Gas Chromatography. https://standards.globalspec.com/std/3818515/ASTM%20D1946-90(2000)
[9]
International Standard ISO 6974-3 (2001) Natural Gas-Determination of Composition with Defined Uncertainty by Gas Chromatography-Part 3: Determination of Hydrogen, Helium, Oxygen, Nitrogen, Carbon Dioxide and Hydrocarbons up to C8 Using Two Packed Columns. https://www.iso.org/standard/25854.html
[10]
Lechner-Fish, T.J. (1999) Enhanced Performance of an Integrated Gas Chromatograph for On-Line Natural Gas Analysis. 4th International Symposium on Fluid Flow Measurement, Denver, 27-30 June 1999. https://es.studenta.com/content/111273256/14-02-gas-cromatographs-cesar-delgado
[11]
Stufkens, J.S. and Bogaard, H.J. (1975) Rapid Method for the Determination of the Composition of Natural Gas by Gas Chromatography. Analytical Chemistry, 47, 383-386. https://doi.org/10.1021/ac60353a060
[12]
Harry, B., Nuryatini and Oman, Z. (2015) Comparison between GC-TCD and GC-FID for the Determination of Propane in Gas Mixture. Procedia Chemistry, 16, 465-472. https://doi.org/10.1016/j.proche.2015.12.080
[13]
Mayara, F.B., Jainny, R.B.S., Alexandre, N.S., Sófacles, F.C.S. and Mario, C.U.A. (2021) A Cheap Handheld NIR Spectrometric System for Automatic Determination of Methane, Ethane, and Propane in Natural Gas and Biogas. Microchemical Journal, 170, Article ID: 106752. https://doi.org/10.1016/j.microc.2021.106752
[14]
Oman, Z. and Harry, B. (2015) Estimating Precision and Accuracy of GC-TCD Method for Carbon Dioxide, Propane and Carbon Monoxide Determination at Different Flow Rate of Carrier Gas. Hemijska Industrija, 70, 451-459. http://www.ache.org.rs/HI/ https://doi.org/10.2298/HEMIND150315051Z
[15]
Barrabin, J.S., Garrido, B.C., Machado, G.A., Wollinger, W., Freitas, R.F.M., Feliciano, A.C.S. and de la Cruz, M.N.S. (2015) Comparison of Exact Matching and Calibration Curve Quantification Methods for Glucose in Human Serum GC-IDMS Analysis and Their Application for the Development of Certified Reference Materials. Accreditation and Quality Assurance, 20, 483-493. https://sci-hub.hkvisa.net/10.1007/s00769-015-1168-6 https://doi.org/10.1007/s00769-015-1168-6
[16]
JCGM 200 (2012) International Vocabulary of Metrology-Basic and General Concepts and associated Terms (VIM), BIPM, IEC, IFCC, ILAC, ISO, IUPAC, IUPAP, OIML. 3rd Edition. https://www.bipm.org/documents/20126/2071204/JCGM_200_2012.pdf/f0e1ad45-d337-bbeb-53a6-15fe649d0ff1
[17]
International Standard ISO 6142 (2001) Gas Analysis-Preparation of Calibration Gas Mixtures-Gravimetric Method. https://cdn.standards.iteh.ai/samples/24663/a3cbfcc95cd9463aab1c82f113862eb9/ISO-6142-2001.pdf
[18]
International Standard ISO 6143 (2001) Gas Analysis-Comparison Methods for Determining and Checking the Composition of Calibration Gas Mixtures. https://www.iso.org/standard/24665.html
[19]
Shehata, A.B., Alaskar, A.R., AlYami, N.H. and Alowaysi, A.S. (2021) Preparation and Certification of Carbon Monoxide Gas Reference Material for the Quality of CO Emission Measurements. Journal of Chemical Metrology, 15, 11-24. https://doi.org/10.25135/jcm.58.21.04.2055
[20]
Shehata, A.B., Alaskar, A.R., AlYami, N.H. and Alowaysi, A.S. (2022) Development of CO2 in N2 Primary Gas Mixtures as Certified Reference Materials for Supporting the Climate Change Monitoring Measurements. Science Journal of Chemistry, 10, 133-143.
[21]
McNair, H.M. and Miller, J.M. (1998) Basic Gas Chromatography. John Wiley and Sons, Inc., New York. https://library.samdu.uz/download/1004
[22]
Grob, R.L. and Barry, E.F. (2004) Modern Practice of Gas Chromatography. 4th Edition, John Wiley and Sons, Inc., Hoboken. https://doi.org/10.1002/0471651141 http://ead2.ctgas.com.br/a_rquivos/inspecao_sistemas_de_gas/Cromatografia/Biblioteca/Modern_Practice_of_Gas_Chromatography_Handbook.pdf
[23]
ISO (2017) ISO Guide 35: Reference Materials-Guidance for Characterization and Assessment of Homogeneity and Stability. ISO, Geneva. https://www.iso.org/standard/60281.html
[24]
Shehata, A.B., AlAskar, A.R., AlRasheed, M.A., AlZahrany, A.M., AlKharraa, F.A. and AlSowailem, A.S. (2023) Development of a Certified Reference Material from Caffeine Solution for Assuring the Quality of Food and Drug Measurements. Green and Sustainable Chemistry, 13, 216-236. https://doi.org/10.4236/gsc.2023.133012
[25]
Shehata, A.B., Alaskar, A.R., Alrasheed, M.A., Alkharraa, F.A. and Alzahrani, A.M. (2020) Certification of Sodium Benzoate Solution Reference Material by HPLC-UV, LC-MS/MS and UVVIS-NIR Spectrophotometry for Food and Drug Analysis. Journal of Chemical Metrology, 14, 88-105. https://doi.org/10.25135/jcm.48.20.08.1780
[26]
ISO (2016) ISO 17034: General Requirements for the Competence of Reference Material Producers. ISO, Geneva. https://standards.iteh.ai/catalog/standards/sist/6e9395ff-15a5-4667-abc4-31db9dc5a911/iso-17034-2016