The aim of the study is to comparatively assess the concentrations of lead, zinc and iron in Rivers Ase, Warri and Ethiope, in Nigeria. Monthly water samples were collected from six randomly selected sites along the rivers course. 72 water samples were collected from each river at 0 - 15 cm depths. Samples were analysed based on the standard methods recommended by the WHO for testing lead, zinc and iron. The assessment of the water quality was done using the Water Quality Index (WQI) of the Canadian Council of Ministers of the Environment (CCME-WQI). While hypotheses were tested using ANOVA. Findings indicated that CCME-WQI values were 47.3, 66.52 and 78.7. This meant that the water quality of River Ase is impaired and departed from desirable levels, while that of Warri and Ethiope were considered to occasionally be impaired and depart from desirable levels. The ANOVA model showed that there is a significant variation in heavy metal load in the selected rivers at P < 0.05. River water was put to domestic uses such as drinking (20.5%) preparing food (17.8%), bathing (19.8%), washing clothes and dishes (21.3%), brushing teeth (13.3%), and catering for domestic animals (7.5%). Poverty (49.5%) was the major reason for the use of river water for domestic purposes. The locals highlighted that they usually suffer from cholera (26.8%), diarrhoea (25.8%), dysentery (24%) and typhoid (23.5%) as a result of using the river water. The study recommended routine monitoring of anthropogenic and geologic activities, testing of the water regularly amongst others.
References
[1]
Utami, R.R., Geerling, G.W., Salami, I.R.S., Notodarmojo, S. and Ragas, A.M. (2023) Mapping Domestic Water Use to Quantify Water-Demand and Water-Related Contaminant Exposure in a Peri-Urban Community, Indonesia. International Journal of Environmental Health Research. https://doi.org/10.1080/09603123.2022.2163986
[2]
Yan, T., Shen, S.L. and Zhou, A. (2022) Indices and Models of Surface Water Quality Assessment: Review and Perspectives. Environmental Pollution, 308, Article ID: 119611. https://doi.org/10.1016/j.envpol.2022.119611
[3]
Mishra, R.K. (2023) Fresh Water Availability and Its Global Challenge. British Journal of Multidisciplinary and Advanced Studies, 4, 1-78. https://doi.org/10.37745/bjmas.2022.0208
[4]
Balogun, M.A., Anumah, A.O., Adegoke, K.A. and Maxakato, N.W. (2022) Environmental Health Impacts and Controlling Measures of Anthropogenic Activities on Groundwater Quality in Southwestern Nigeria. Environmental Monitoring and Assessment, 194, Article No. 384. https://doi.org/10.1007/s10661-022-09805-z
[5]
Okumagba, P.O. and Ozabor, F. (2014) The Effects of Socio-Economic Activities on River Ethiope. Journal of Sustainable Society, 3, 1-6. https://doi.org/10.11634/216825851403528
[6]
Mukhopadhyay, A., Duttagupta, S. and Mukherjee, A. (2022) Emerging Organic Contaminants in Global Community Drinking Water Sources and Supply: A Review of Occurrence, Processes and Remediation. Journal of Environmental Chemical Engineering, 10, Article ID: 107560. https://doi.org/10.1016/j.jece.2022.107560
[7]
Chen, S.S., Kimirei, I.A., Yu, C., Shen, Q. and Gao, Q. (2022) Assessment of Urban River Water Pollution with Urbanization in East Africa. Environmental Science and Pollution Research, 29, 40812-40825. https://doi.org/10.1007/s11356-021-18082-1
[8]
Khan, W.A., Ali, S. and Shah, S.A. (2022) Water Pollution: Sources and Its Impact on Human Health, Control and Managing. Journal of International Cooperation and Development, 5, 69. https://doi.org/10.36941/jicd-2022-0005
[9]
Bakare, B.F. and Adeyinka, G.C. (2022) Evaluating the Potential Health Risks of Selected Heavy Metals across Four Wastewater Treatment Water Works in Durban, South Africa. Toxics, 10, Article 340. https://doi.org/10.3390/toxics10060340
[10]
WHO (1987) Guidelines for Drinking-Water Quality, Volume 3: Drinking-Water Quality Control in Small-Community Supplieswho, Geneva, 1985, VIII + 121 pp. Price: Sw. fr. 17.00. Science of the Total Environment, 61, 274-275. https://doi.org/10.1016/0048-9697(87)90389-5
[11]
Solhi, L., et al. (2023) Understanding Nanocellulose—Water Interactions: Turning a Detriment into an Asset. Chemical Reviews, 123, 1925-2015. https://doi.org/10.1021/acs.chemrev.2c00611
[12]
Shi, X., Du, Y., Lam, P.K., Wu, R.S. and Zhou, B. (2023) Developmental Toxicity and Alteration of Gene Expression in Zebrafish Embryos Exposed to PFOS. Toxicology and Applied Pharmacology, 230, 23-32. https://pubmed.ncbi.nlm.nih.gov/18407306/
[13]
Kumar, V., Dwivedi, S.K. and Oh, S. (2022) A Critical Review on Lead Removal from Industrial Wastewater: Recent Advances and Future Outlook. Journal of Water Process Engineering, 45, Article ID: 102518. https://doi.org/10.1016/j.jwpe.2021.102518
[14]
Bradham, K.D., et al. (2022) A National Survey of Lead and Other Metal (Loids) in Residential Drinking Water in the United States. Journal of Exposure Science and Environmental Epidemiology, 33, 160-167. https://doi.org/10.1038/s41370-022-00461-6
[15]
Wong, C., Roberts, S.M. and Saab, I.N. (2022) Review of Regulatory Reference Values and Background Levels for Heavy Metals in the Human Diet. Regulatory Toxicology and Pharmacology, 130, Article ID: 105122. https://doi.org/10.1016/j.yrtph.2022.105122
[16]
Hatakeyama, S. (1989) Effect of Copper and Zinc on the Growth and Emergence of Epeorus latifolium (Ephemeroptera) in an Indoor Model Stream. Hydrobiologia, 174, 17-27. https://doi.org/10.1007/BF00006054
[17]
Jensen, J., Larsen, M.M. and Bak, J. (2016) National Monitoring Study in Denmark Finds Increased and Critical Levels of Copper and Zinc in Arable Soils Fertilized with Pig Slurry. Environmental Pollution, 214, 334-340. https://doi.org/10.1016/j.envpol.2016.03.034
[18]
Wada, S. and Suzuki, S. (2011) Inhibitory Effect of Zinc on the Remineralisation of Dissolved Organic Matter in the Coastal Environment. Aquatic Microbial Ecology, 63, 47-59. https://doi.org/10.3354/ame01481
[19]
Naito, W., Kamo, M., Tsushima, K. and Iwasaki, Y. (2010) Exposure and Risk Assessment of Zinc in Japanese Surface Waters. Science of the Total Environment, 408, 4271-4284. https://doi.org/10.1016/j.scitotenv.2010.06.018
[20]
Gozzard, E., Mayes, W.M., Potter, H. and Jarvis, A.P. (2011) Seasonal and Spatial Variation of Diffuse (Non-Point) Source Zinc Pollution in a Historically Metal Mined River Catchment, UK. Environmental Pollution, 159, 3113-3122. https://doi.org/10.1016/j.envpol.2011.02.010
[21]
Chen, M., et al. (2019) Zinc Pollution in Zones Dominated by Algae and Submerged Macrophytes in Lake Taihu. Science of the Total Environment, 670, 361-368. https://doi.org/10.1016/j.scitotenv.2019.03.167
[22]
Wang, X., Zhao, L., Xu, H. and Zhang, X. (2018) Spatial and Seasonal Characteristics of Dissolved Heavy Metals in the Surface Seawater of the Yellow River Estuary, China. Marine Pollution Bulletin, 137, 465-473. https://doi.org/10.1016/j.marpolbul.2018.10.052
[23]
Liu, H., et al. (2022) Navigating Fast and Uniform Zinc Deposition via a Versatile Metal-Organic Complex Interphase. Energy and Environmental Science, 15, 1872-1881. https://doi.org/10.1039/D2EE00209D
[24]
Usman, M., et al. (2023) Effect of Soil Texture and Zinc Oxide Nanoparticles on Growth and Accumulation of Cadmium by Wheat: A Life Cycle Study. Environmental Research, 216, Article ID: 114397. https://doi.org/10.1016/j.envres.2022.114397
[25]
Frost, D.J., Liebske, C., Langenhorst, F., McCammon, C., Tronnes, R.G. and Rubie, D.C. (2004) Experimental Evidence for the Existence of Iron-Rich Metal in the Earth’s Lower Mantle. Nature, 428, 409-412. https://doi.org/10.1038/nature02413
[26]
An Introduction to Iron and Manganese Biofiltration—ProQuest. https://www.proquest.com/openview/28d3fa06343c4ce9e1d637721a5ca1a9/1?pq-origsite=gscholar&cbl=106031
[27]
Mohan, D. and Haripavan, N. (2022) Applications of Plants Leaf-Based Biosorbents for Removal of Iron and Phosphorus from Contaminated Water: A Review. Biomedical Materials & Devices, 1, 122-145. https://doi.org/10.1007/s44174-022-00029-w
[28]
Alladin, E.A., Omoruyi, D.I. and Odia-Oseghale, O.O. (2022) Impact of Heavy Metals on the Soil and Groundwater of Ariaria Waste Dumpsite, Aba, South-Eastern Nigeria. International Journal of Earth Sciences Knowledge and Applications, 4, 365-374. http://www.ijeska.com/index.php/ijeska
[29]
Das, S., Mishra, S. and Sahu, H. (2023) A Review of Activated Carbon to Counteract the Effect of Iron Toxicity on the Environment. Environmental Chemistry and Ecotoxicology, 5, 86-97. https://doi.org/10.1016/j.enceco.2023.02.002
[30]
Xu, P., Wang, L., Liu, X., Xie, S., Yang, Z. and Zhu, P. (2022) Ascorbic Acid Enhanced the Zero-Valent Iron/Peroxymonosulfate Oxidation: Simultaneous Chelating and Reducing. Separation and Purification Technology, 298, Article ID: 121599. https://doi.org/10.1016/j.seppur.2022.121599
[31]
Obisesan, A. and Famous, O. (2016) Factors Affecting Water Supply in Owah-Abbi, Delta State. Open Journal of Social Sciences, 4, 137-146. https://doi.org/10.4236/jss.2016.47023
[32]
Rigueto, V.T., et al. (2022) Toxic Metals an Overview of Main Sources, Exposure Routes, Adverse Effects and Treatment Approaches. CRC Press, Boca Raton. https://doi.org/10.1201/9781003138907-1
[33]
Corsita, L., Arwin, A., Muntalif, B.S. and Salami, I.R. (2014) Assessment of the Water Quality of Jatiluhur Reservoir, the Downstream of Citarum Cascade River, Using Selected Physico-Chemical Parameters. Jurnal Rekayasa Kimia & Lingkungan, 10, 40-48. https://doi.org/10.23955/rkl.v10i1.2171
[34]
Tyagi, M. (2017) Ground Water Quality Assessment in and around Bhagwanpur Industrial Area (UK), India. MOJ Ecology & Environmental Sciences, 2, 42-44. https://doi.org/10.15406/mojes.2017.02.00016
[35]
Brar, K.K., Raza, H., Magdouli, S. and Brar, S.K. (2022) Role and Importance of Filtration System in Modular Drinking Water Treatment System. In: Brar, S.K., Kumar, P. and Cuprys, A., Eds., Modular Treatment Approach for Drinking Water and Wastewater, Elsevier, Amsterdam, 239-265. https://doi.org/10.1016/B978-0-323-85421-4.00013-9
[36]
Babuji, P., Thirumalaisamy, S., Duraisamy, K. and Periyasamy, G. (2023) Human Health Risks Due to Exposure to Water Pollution: A Review. Water, 15, Article 2532. https://doi.org/10.3390/w15142532
[37]
Omo-Irabor, O. and Olobaniyi, S. (2010) Investigation of the Hydrological Quality of Ethiope River Watershed, Southern Nigeria. Journal of Applied Sciences and Environmental Management, 11, 13-19. https://doi.org/10.4314/jasem.v11i2.54978
[38]
Ushurhe, O., Ozabor, F. and Origho, T. (2023) A Comparative Study of Upstream and Downstream Water Quality of Warri River, in Delta State, Southern Nigeria. African Journal of Environmental Research, 4, 42-53.
[39]
Egedegbe, A.O., et al. (2023) Molecular Characterization and Potentiality of Anopheles coluzzii in Disease Transmission in Different Communities in Ughelli North lga, Delta State, Nigeria. Animal Research International, 20, 4988-5006.
[40]
Ayoola, E.O., et al. (2023) Determination of Polychlorinated Biphenyls (PCBS) Levels in the Soil and Water from Electronic Waste Dumpsite at Alaba, Lagos State, Nigeria. Fudma Journal of Sciences, 7, 133-145. https://doi.org/10.33003/fjs-2023-0703-1857
[41]
Davidson, J., Redman, N., Crouse, C. and Vinci, B. (2022) Water Quality, Waste Production, and Off-Flavor Characterization in a Depuration System Stocked with Market-Size Atlantic Salmon salmo salar. Journal of the World Aquaculture Society, 54, 96-112. https://doi.org/10.1111/jwas.12920
[42]
Sharma, D. and Kansal, A. (2011) Water Quality Analysis of River Yamuna Using Water Quality Index in the National Capital Territory, India (2000-2009). Applied Water Science, 1, 147-157. https://doi.org/10.1007/s13201-011-0011-4
[43]
Bora, M. and Goswami, D.C. (2016) Water Quality Assessment in Terms of Water Quality Index (WQI): Case Study of the Kolong River, Assam, India. Applied Water Science, 7, 3125-3135. https://doi.org/10.1007/s13201-016-0451-y
[44]
Abba, S.I., Saini, G. and Abdulkadir, R.A. (2017) Evaluation of Yearly Water Quality Index and Seasonal Variation of Yamuna River at Hathikund Station Using Canadian Council of Ministers of Environment Water Quality Index (CCME) Model. IOSR Journal of Engineering, 7, 12-17. https://doi.org/10.9790/30210-701011217
[45]
Khan, A.A., Paterson, R. and Khan, H. (2004) Modification and Application of the Canadian Council of Ministers of the Environment Water Quality Index (CCME WQI) for the Communication of Drinking Water Quality Data in Newfoundland and Labrador. Water Quality Research Journal, 39, 285-293. https://doi.org/10.2166/wqrj.2004.039
[46]
Kiptum, C. (2022) Commonly Used Methods to Calculate Water Quality Indices. In: Vaseashta, A., Duca, G. and Travin, S., Eds., Handbook of Research on Water Sciences and Society, Engineering Science Reference, Hershey, 271-292. https://doi.org/10.4018/978-1-7998-7356-3.ch012
[47]
Goswami, A.P. and Kalamdhad, A.S. (2022) Trend of Water Quality of a River Flowing through Densely Populated Area of Assam, India Using Water Quality Index (WQI). In: Haq, I., Kalamdhad, A.S. and Dash, S., Eds., Environmental Degradation: Monitoring, Assessment and Treatment Technologies, Springer, Cham 215-224. https://doi.org/10.1007/978-3-030-94148-2_19
[48]
Hui, T., et al. (2020) Evaluation of Drinking Water Quality Using the Water Quality Index (WQI), the Synthetic Pollution Index (SPI) and Geospatial Tools in Lianhuashan District, China. Polish Journal of Environmental Studies, 30, 141-153.
[49]
https://doi.org/10.15244/pjoes/120765
[50]
Famous, O. and Adekunle, O. (2020) The Role of Government and Private Partnership in Eradicating Street Waste Dumps in Port Harcourt. International Journal of Environmental Protection and Policy, 8, 31-35. https://doi.org/10.11648/j.ijepp.20200801.14
[51]
Aisien, F.A., Chiadikobi, J.C. and Aisien, E.T. (2009) Toxicity Assessment of Some Crude Oil Contaminated Soils in the Niger Delta. Advanced Materials Research, 62-64, 451-455. https://doi.org/10.4028/www.scientific.net/AMR.62-64.451
[52]
Egbore, A.B.M. (1994) Water Pollution in Nigeria. Ben Miller Books Ltd., Warri.
[53]
Parker, B. (1996) Monitoring and Modeling of Coastal Waters in Support of Environmental Preservation. Journal of Marine Science and Technology, 1, 75-84. https://link.springer.com/article/10.1007/BF02391163
[54]
Wutich, A. (2008) Estimating Household Water Use: A Comparison of Diary, Prompted Recall, and Free Recall Methods. Field Methods, 21, 49-68. https://doi.org/10.1177/1525822X08325673
[55]
Bates, W.B., et al. (2023) A Tale of Two Rivers—Baaka and Martuwarra, Australia: Shared Voices and Art towards Water Justice. The Anthropocene Review. https://doi.org/10.1177/20530196231186962
[56]
Okumagba, P.O. and Ozabor, F. (2016) Environmental and Social Implication of Urban Solid Waste in Abraka, Ethiope-East Local Government Area of Delta State, Nigeria. Journal of Social and Management Sciences, 11, 124-131.
[57]
Gyawali, K., Acharya, P. and Poudel, D. (2023) Environmental Pollution and Its Effects on Human Health. Interdisciplinary Research in Education, 8, 84-94. https://doi.org/10.3126/ire.v8i1.56729
[58]
Parida, L. and Patel, T.N. (2023) Systemic Impact of Heavy Metals and Their Role in Cancer Development: A Review. Environmental Monitoring and Assessment, 195, Article No. 766. https://doi.org/10.1007/s10661-023-11399-z
